Optimization of molecular distillation to concentrate ethyl esters of eicosapentaenoic (20:5 ω-3) and docosahexaenoic acids (22:6 ω-3) using simplified phenomenological modeling

Autores
Rossi, Pablo Cesar; Pramparo, Maria del Carmen; Gaich, María C.; Grosso, Nelson; Nepote, Valeria
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Squid oil contains high concentration of eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA). The purpose of this work was to optimize the process of separation by molecular distillation of ω-3 fatty acid ethyl esters obtained from squid oil. The separation process was conducted in two stages in a laboratory-scale molecular distiller. A mathematical model based on the mass transfer phenomena was developed. The Nelder-Mead numerical method was used to optimize the model. RESULTS: The ω-3 content in the output material of the stage II increased with the temperature of stage I (T 1). The amount of distillated material in stage I increased and the distillated material in the stage II decreased with the increment of T 1. That implied a decreasing of the ω-3 recovery in the distillated material in the stage II. In addition, the ω-3 recovery increased with the temperature of stage II (T 2), but the temperatures should be less than 140 °C to avoid chemical changes. The optimization results showed an optimal process at T 1 = 120.5 °C and T 2 = 140 °C. CONCLUSION: The theoretical model and the optimization give decision criteria about the operative conditions for reaching the highest yield during molecular distillation of ω-3 fatty acid ethyl esters. © 2011 Society of Chemical Industry.
Fil: Rossi, Pablo Cesar. Universidad Nacional de Río Cuarto. Facultad de Ingeniería. Departamento de Tecnología Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Pramparo, Maria del Carmen. Universidad Nacional de Río Cuarto. Facultad de Ingeniería. Departamento de Tecnología Química; Argentina
Fil: Gaich, María C.. Universidad Nacional de Río Cuarto. Facultad de Ingeniería. Departamento de Tecnología Química; Argentina
Fil: Grosso, Nelson. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto Multidisciplinario de Biología Vegetal. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Instituto Multidisciplinario de Biología Vegetal; Argentina
Fil: Nepote, Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto Multidisciplinario de Biología Vegetal. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Instituto Multidisciplinario de Biología Vegetal; Argentina
Materia
Ω-3
DHA
EPA
MOLECULAR DISTILLATION
OPTIMIZATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/150442
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Optimization of molecular distillation to concentrate ethyl esters of eicosapentaenoic (20:5 ω-3) and docosahexaenoic acids (22:6 ω-3) using simplified phenomenological modelingRossi, Pablo CesarPramparo, Maria del CarmenGaich, María C.Grosso, NelsonNepote, ValeriaΩ-3DHAEPAMOLECULAR DISTILLATIONOPTIMIZATIONhttps://purl.org/becyt/ford/2.11https://purl.org/becyt/ford/2Squid oil contains high concentration of eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA). The purpose of this work was to optimize the process of separation by molecular distillation of ω-3 fatty acid ethyl esters obtained from squid oil. The separation process was conducted in two stages in a laboratory-scale molecular distiller. A mathematical model based on the mass transfer phenomena was developed. The Nelder-Mead numerical method was used to optimize the model. RESULTS: The ω-3 content in the output material of the stage II increased with the temperature of stage I (T 1). The amount of distillated material in stage I increased and the distillated material in the stage II decreased with the increment of T 1. That implied a decreasing of the ω-3 recovery in the distillated material in the stage II. In addition, the ω-3 recovery increased with the temperature of stage II (T 2), but the temperatures should be less than 140 °C to avoid chemical changes. The optimization results showed an optimal process at T 1 = 120.5 °C and T 2 = 140 °C. CONCLUSION: The theoretical model and the optimization give decision criteria about the operative conditions for reaching the highest yield during molecular distillation of ω-3 fatty acid ethyl esters. © 2011 Society of Chemical Industry.Fil: Rossi, Pablo Cesar. Universidad Nacional de Río Cuarto. Facultad de Ingeniería. Departamento de Tecnología Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Pramparo, Maria del Carmen. Universidad Nacional de Río Cuarto. Facultad de Ingeniería. Departamento de Tecnología Química; ArgentinaFil: Gaich, María C.. Universidad Nacional de Río Cuarto. Facultad de Ingeniería. Departamento de Tecnología Química; ArgentinaFil: Grosso, Nelson. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto Multidisciplinario de Biología Vegetal. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Instituto Multidisciplinario de Biología Vegetal; ArgentinaFil: Nepote, Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto Multidisciplinario de Biología Vegetal. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Instituto Multidisciplinario de Biología Vegetal; ArgentinaJohn Wiley & Sons Ltd2011-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/150442Rossi, Pablo Cesar; Pramparo, Maria del Carmen; Gaich, María C.; Grosso, Nelson; Nepote, Valeria; Optimization of molecular distillation to concentrate ethyl esters of eicosapentaenoic (20:5 ω-3) and docosahexaenoic acids (22:6 ω-3) using simplified phenomenological modeling; John Wiley & Sons Ltd; Journal of the Science of Food and Agriculture; 91; 8; 6-2011; 1452-14580022-51421097-0010CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/jsfa.4332/abstractinfo:eu-repo/semantics/altIdentifier/doi/10.1002/jsfa.4332info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:10:20Zoai:ri.conicet.gov.ar:11336/150442instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:10:20.961CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Optimization of molecular distillation to concentrate ethyl esters of eicosapentaenoic (20:5 ω-3) and docosahexaenoic acids (22:6 ω-3) using simplified phenomenological modeling
title Optimization of molecular distillation to concentrate ethyl esters of eicosapentaenoic (20:5 ω-3) and docosahexaenoic acids (22:6 ω-3) using simplified phenomenological modeling
spellingShingle Optimization of molecular distillation to concentrate ethyl esters of eicosapentaenoic (20:5 ω-3) and docosahexaenoic acids (22:6 ω-3) using simplified phenomenological modeling
Rossi, Pablo Cesar
Ω-3
DHA
EPA
MOLECULAR DISTILLATION
OPTIMIZATION
title_short Optimization of molecular distillation to concentrate ethyl esters of eicosapentaenoic (20:5 ω-3) and docosahexaenoic acids (22:6 ω-3) using simplified phenomenological modeling
title_full Optimization of molecular distillation to concentrate ethyl esters of eicosapentaenoic (20:5 ω-3) and docosahexaenoic acids (22:6 ω-3) using simplified phenomenological modeling
title_fullStr Optimization of molecular distillation to concentrate ethyl esters of eicosapentaenoic (20:5 ω-3) and docosahexaenoic acids (22:6 ω-3) using simplified phenomenological modeling
title_full_unstemmed Optimization of molecular distillation to concentrate ethyl esters of eicosapentaenoic (20:5 ω-3) and docosahexaenoic acids (22:6 ω-3) using simplified phenomenological modeling
title_sort Optimization of molecular distillation to concentrate ethyl esters of eicosapentaenoic (20:5 ω-3) and docosahexaenoic acids (22:6 ω-3) using simplified phenomenological modeling
dc.creator.none.fl_str_mv Rossi, Pablo Cesar
Pramparo, Maria del Carmen
Gaich, María C.
Grosso, Nelson
Nepote, Valeria
author Rossi, Pablo Cesar
author_facet Rossi, Pablo Cesar
Pramparo, Maria del Carmen
Gaich, María C.
Grosso, Nelson
Nepote, Valeria
author_role author
author2 Pramparo, Maria del Carmen
Gaich, María C.
Grosso, Nelson
Nepote, Valeria
author2_role author
author
author
author
dc.subject.none.fl_str_mv Ω-3
DHA
EPA
MOLECULAR DISTILLATION
OPTIMIZATION
topic Ω-3
DHA
EPA
MOLECULAR DISTILLATION
OPTIMIZATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.11
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Squid oil contains high concentration of eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA). The purpose of this work was to optimize the process of separation by molecular distillation of ω-3 fatty acid ethyl esters obtained from squid oil. The separation process was conducted in two stages in a laboratory-scale molecular distiller. A mathematical model based on the mass transfer phenomena was developed. The Nelder-Mead numerical method was used to optimize the model. RESULTS: The ω-3 content in the output material of the stage II increased with the temperature of stage I (T 1). The amount of distillated material in stage I increased and the distillated material in the stage II decreased with the increment of T 1. That implied a decreasing of the ω-3 recovery in the distillated material in the stage II. In addition, the ω-3 recovery increased with the temperature of stage II (T 2), but the temperatures should be less than 140 °C to avoid chemical changes. The optimization results showed an optimal process at T 1 = 120.5 °C and T 2 = 140 °C. CONCLUSION: The theoretical model and the optimization give decision criteria about the operative conditions for reaching the highest yield during molecular distillation of ω-3 fatty acid ethyl esters. © 2011 Society of Chemical Industry.
Fil: Rossi, Pablo Cesar. Universidad Nacional de Río Cuarto. Facultad de Ingeniería. Departamento de Tecnología Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Pramparo, Maria del Carmen. Universidad Nacional de Río Cuarto. Facultad de Ingeniería. Departamento de Tecnología Química; Argentina
Fil: Gaich, María C.. Universidad Nacional de Río Cuarto. Facultad de Ingeniería. Departamento de Tecnología Química; Argentina
Fil: Grosso, Nelson. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto Multidisciplinario de Biología Vegetal. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Instituto Multidisciplinario de Biología Vegetal; Argentina
Fil: Nepote, Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto Multidisciplinario de Biología Vegetal. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Instituto Multidisciplinario de Biología Vegetal; Argentina
description Squid oil contains high concentration of eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA). The purpose of this work was to optimize the process of separation by molecular distillation of ω-3 fatty acid ethyl esters obtained from squid oil. The separation process was conducted in two stages in a laboratory-scale molecular distiller. A mathematical model based on the mass transfer phenomena was developed. The Nelder-Mead numerical method was used to optimize the model. RESULTS: The ω-3 content in the output material of the stage II increased with the temperature of stage I (T 1). The amount of distillated material in stage I increased and the distillated material in the stage II decreased with the increment of T 1. That implied a decreasing of the ω-3 recovery in the distillated material in the stage II. In addition, the ω-3 recovery increased with the temperature of stage II (T 2), but the temperatures should be less than 140 °C to avoid chemical changes. The optimization results showed an optimal process at T 1 = 120.5 °C and T 2 = 140 °C. CONCLUSION: The theoretical model and the optimization give decision criteria about the operative conditions for reaching the highest yield during molecular distillation of ω-3 fatty acid ethyl esters. © 2011 Society of Chemical Industry.
publishDate 2011
dc.date.none.fl_str_mv 2011-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/150442
Rossi, Pablo Cesar; Pramparo, Maria del Carmen; Gaich, María C.; Grosso, Nelson; Nepote, Valeria; Optimization of molecular distillation to concentrate ethyl esters of eicosapentaenoic (20:5 ω-3) and docosahexaenoic acids (22:6 ω-3) using simplified phenomenological modeling; John Wiley & Sons Ltd; Journal of the Science of Food and Agriculture; 91; 8; 6-2011; 1452-1458
0022-5142
1097-0010
CONICET Digital
CONICET
url http://hdl.handle.net/11336/150442
identifier_str_mv Rossi, Pablo Cesar; Pramparo, Maria del Carmen; Gaich, María C.; Grosso, Nelson; Nepote, Valeria; Optimization of molecular distillation to concentrate ethyl esters of eicosapentaenoic (20:5 ω-3) and docosahexaenoic acids (22:6 ω-3) using simplified phenomenological modeling; John Wiley & Sons Ltd; Journal of the Science of Food and Agriculture; 91; 8; 6-2011; 1452-1458
0022-5142
1097-0010
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/jsfa.4332/abstract
info:eu-repo/semantics/altIdentifier/doi/10.1002/jsfa.4332
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Ltd
publisher.none.fl_str_mv John Wiley & Sons Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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