Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties

Autores
Iborra, Agustín; Salvatierra, Lucas Matías; Giussi, Juan M.; Azzaroni, Omar
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión aceptada
Descripción
Fil: Iborra, Agustín. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Iborra, Agustín. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Salvatierra, Lucas Matías. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Salvatierra, Lucas Matías. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Salvatierra, Lucas Matías. Pontificia Universidad Católica Argentina. Facultad de Química e Ingeniería del Rosario; Argentina
Fil: Giussi, Juan M. Universidad Nacional de La Plata. Facultad de Ciencias Exactas.Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Giussi, Juan M. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Azzaroni, Omar. Universidad Nacional de La Plata. Facultad de Ciencias Exactas.Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Azzaroni, Omar. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Abstract: In this work we study the synthesis and properties of copolymers constituted of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate monomers, prepared by atom transfer radical copolymerization in the entire composition range (with low and high monomer conversion). We propose a description of the copolymer microstructure, and evaluate the composition drift effect in the thermal and solution properties of the obtained copolymers. Nuclear magnetic resonance (NMR) was used to determine the chemical composition of the copolymers, while differential scanning calorimetry and themogravimetric analysis was employed to understand the thermal chracteristics. Rheological studies were conducted to obtain the viscosity and viscoelastic properties that were correlated with thermal transitions at different temperatures. Finally, dynamic light scattering (DLS) and surface tension measurements were used to evaluate the copolymer solution properties. The incorporation of an oil phase in the self-assembled aggregates was evaluated by DLS and characterized by atomic force microscopy, diffusion-ordered spectroscopy NMR and nuclear Overhauser effect NMR spectroscopy.. Our results suggest a longer sequence of LMA units in the copolymer chain and a drift effect in the case of high monomer conversions. A clear dependence on copolymer composition and microstructure to disperse an oil phase in water was observed. We believe that these results bring valuable knowledge that advances the field of macrosurfactants as well as their potential applications in oil recovery and other industrial processes.
Fuente
Postprint del artículo publicado en European Polymer Journal, 2019
Materia
POLIMEROS
PROPIEDADES TERMODINAMICAS
COMPOSICION QUIMICA
QUIMICA
MICROESTRUCTURA
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
Repositorio Institucional (UCA)
Institución
Pontificia Universidad Católica Argentina
OAI Identificador
oai:ucacris:123456789/9020

id RIUCA_c4e2eed8c82d2235bfdf6d9107f34ee6
oai_identifier_str oai:ucacris:123456789/9020
network_acronym_str RIUCA
repository_id_str 2585
network_name_str Repositorio Institucional (UCA)
spelling Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying propertiesIborra, AgustínSalvatierra, Lucas MatíasGiussi, Juan M.Azzaroni, OmarPOLIMEROSPROPIEDADES TERMODINAMICASCOMPOSICION QUIMICAQUIMICAMICROESTRUCTURAFil: Iborra, Agustín. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Iborra, Agustín. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Salvatierra, Lucas Matías. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Salvatierra, Lucas Matías. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Salvatierra, Lucas Matías. Pontificia Universidad Católica Argentina. Facultad de Química e Ingeniería del Rosario; ArgentinaFil: Giussi, Juan M. Universidad Nacional de La Plata. Facultad de Ciencias Exactas.Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Giussi, Juan M. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Azzaroni, Omar. Universidad Nacional de La Plata. Facultad de Ciencias Exactas.Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Azzaroni, Omar. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaAbstract: In this work we study the synthesis and properties of copolymers constituted of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate monomers, prepared by atom transfer radical copolymerization in the entire composition range (with low and high monomer conversion). We propose a description of the copolymer microstructure, and evaluate the composition drift effect in the thermal and solution properties of the obtained copolymers. Nuclear magnetic resonance (NMR) was used to determine the chemical composition of the copolymers, while differential scanning calorimetry and themogravimetric analysis was employed to understand the thermal chracteristics. Rheological studies were conducted to obtain the viscosity and viscoelastic properties that were correlated with thermal transitions at different temperatures. Finally, dynamic light scattering (DLS) and surface tension measurements were used to evaluate the copolymer solution properties. The incorporation of an oil phase in the self-assembled aggregates was evaluated by DLS and characterized by atomic force microscopy, diffusion-ordered spectroscopy NMR and nuclear Overhauser effect NMR spectroscopy.. Our results suggest a longer sequence of LMA units in the copolymer chain and a drift effect in the case of high monomer conversions. A clear dependence on copolymer composition and microstructure to disperse an oil phase in water was observed. We believe that these results bring valuable knowledge that advances the field of macrosurfactants as well as their potential applications in oil recovery and other industrial processes.Elsevier2019info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttps://repositorio.uca.edu.ar/handle/123456789/90200014-305710.1016/j.eurpolymj.2019.04.010Iborra, A. et al. Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties. [en línea]. Postprint del artículo publicado en European Polymer Journal. 2019. doi 10.1016/j.eurpolymj.2019.04.010. Disponible en: https://repositorio.uca.edu.ar/handle/123456789/9020Postprint del artículo publicado en European Polymer Journal, 2019reponame:Repositorio Institucional (UCA)instname:Pontificia Universidad Católica Argentinaenginfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/4.0/2025-07-03T10:57:00Zoai:ucacris:123456789/9020instacron:UCAInstitucionalhttps://repositorio.uca.edu.ar/Universidad privadaNo correspondehttps://repositorio.uca.edu.ar/oaiclaudia_fernandez@uca.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:25852025-07-03 10:57:00.757Repositorio Institucional (UCA) - Pontificia Universidad Católica Argentinafalse
dc.title.none.fl_str_mv Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties
title Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties
spellingShingle Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties
Iborra, Agustín
POLIMEROS
PROPIEDADES TERMODINAMICAS
COMPOSICION QUIMICA
QUIMICA
MICROESTRUCTURA
title_short Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties
title_full Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties
title_fullStr Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties
title_full_unstemmed Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties
title_sort Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties
dc.creator.none.fl_str_mv Iborra, Agustín
Salvatierra, Lucas Matías
Giussi, Juan M.
Azzaroni, Omar
author Iborra, Agustín
author_facet Iborra, Agustín
Salvatierra, Lucas Matías
Giussi, Juan M.
Azzaroni, Omar
author_role author
author2 Salvatierra, Lucas Matías
Giussi, Juan M.
Azzaroni, Omar
author2_role author
author
author
dc.subject.none.fl_str_mv POLIMEROS
PROPIEDADES TERMODINAMICAS
COMPOSICION QUIMICA
QUIMICA
MICROESTRUCTURA
topic POLIMEROS
PROPIEDADES TERMODINAMICAS
COMPOSICION QUIMICA
QUIMICA
MICROESTRUCTURA
dc.description.none.fl_txt_mv Fil: Iborra, Agustín. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Iborra, Agustín. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Salvatierra, Lucas Matías. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Salvatierra, Lucas Matías. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Salvatierra, Lucas Matías. Pontificia Universidad Católica Argentina. Facultad de Química e Ingeniería del Rosario; Argentina
Fil: Giussi, Juan M. Universidad Nacional de La Plata. Facultad de Ciencias Exactas.Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Giussi, Juan M. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Azzaroni, Omar. Universidad Nacional de La Plata. Facultad de Ciencias Exactas.Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Azzaroni, Omar. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Abstract: In this work we study the synthesis and properties of copolymers constituted of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate monomers, prepared by atom transfer radical copolymerization in the entire composition range (with low and high monomer conversion). We propose a description of the copolymer microstructure, and evaluate the composition drift effect in the thermal and solution properties of the obtained copolymers. Nuclear magnetic resonance (NMR) was used to determine the chemical composition of the copolymers, while differential scanning calorimetry and themogravimetric analysis was employed to understand the thermal chracteristics. Rheological studies were conducted to obtain the viscosity and viscoelastic properties that were correlated with thermal transitions at different temperatures. Finally, dynamic light scattering (DLS) and surface tension measurements were used to evaluate the copolymer solution properties. The incorporation of an oil phase in the self-assembled aggregates was evaluated by DLS and characterized by atomic force microscopy, diffusion-ordered spectroscopy NMR and nuclear Overhauser effect NMR spectroscopy.. Our results suggest a longer sequence of LMA units in the copolymer chain and a drift effect in the case of high monomer conversions. A clear dependence on copolymer composition and microstructure to disperse an oil phase in water was observed. We believe that these results bring valuable knowledge that advances the field of macrosurfactants as well as their potential applications in oil recovery and other industrial processes.
description Fil: Iborra, Agustín. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
publishDate 2019
dc.date.none.fl_str_mv 2019
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv https://repositorio.uca.edu.ar/handle/123456789/9020
0014-3057
10.1016/j.eurpolymj.2019.04.010
Iborra, A. et al. Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties. [en línea]. Postprint del artículo publicado en European Polymer Journal. 2019. doi 10.1016/j.eurpolymj.2019.04.010. Disponible en: https://repositorio.uca.edu.ar/handle/123456789/9020
url https://repositorio.uca.edu.ar/handle/123456789/9020
identifier_str_mv 0014-3057
10.1016/j.eurpolymj.2019.04.010
Iborra, A. et al. Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties. [en línea]. Postprint del artículo publicado en European Polymer Journal. 2019. doi 10.1016/j.eurpolymj.2019.04.010. Disponible en: https://repositorio.uca.edu.ar/handle/123456789/9020
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/4.0/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/4.0/
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv Postprint del artículo publicado en European Polymer Journal, 2019
reponame:Repositorio Institucional (UCA)
instname:Pontificia Universidad Católica Argentina
reponame_str Repositorio Institucional (UCA)
collection Repositorio Institucional (UCA)
instname_str Pontificia Universidad Católica Argentina
repository.name.fl_str_mv Repositorio Institucional (UCA) - Pontificia Universidad Católica Argentina
repository.mail.fl_str_mv claudia_fernandez@uca.edu.ar
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score 13.070432