Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties
- Autores
- Iborra, Agustín; Salvatierra, Lucas Matías; Giussi, Juan M.; Azzaroni, Omar
- Año de publicación
- 2019
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión aceptada
- Descripción
- Fil: Iborra, Agustín. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Iborra, Agustín. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Salvatierra, Lucas Matías. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Salvatierra, Lucas Matías. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Salvatierra, Lucas Matías. Pontificia Universidad Católica Argentina. Facultad de Química e Ingeniería del Rosario; Argentina
Fil: Giussi, Juan M. Universidad Nacional de La Plata. Facultad de Ciencias Exactas.Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Giussi, Juan M. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Azzaroni, Omar. Universidad Nacional de La Plata. Facultad de Ciencias Exactas.Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Azzaroni, Omar. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Abstract: In this work we study the synthesis and properties of copolymers constituted of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate monomers, prepared by atom transfer radical copolymerization in the entire composition range (with low and high monomer conversion). We propose a description of the copolymer microstructure, and evaluate the composition drift effect in the thermal and solution properties of the obtained copolymers. Nuclear magnetic resonance (NMR) was used to determine the chemical composition of the copolymers, while differential scanning calorimetry and themogravimetric analysis was employed to understand the thermal chracteristics. Rheological studies were conducted to obtain the viscosity and viscoelastic properties that were correlated with thermal transitions at different temperatures. Finally, dynamic light scattering (DLS) and surface tension measurements were used to evaluate the copolymer solution properties. The incorporation of an oil phase in the self-assembled aggregates was evaluated by DLS and characterized by atomic force microscopy, diffusion-ordered spectroscopy NMR and nuclear Overhauser effect NMR spectroscopy.. Our results suggest a longer sequence of LMA units in the copolymer chain and a drift effect in the case of high monomer conversions. A clear dependence on copolymer composition and microstructure to disperse an oil phase in water was observed. We believe that these results bring valuable knowledge that advances the field of macrosurfactants as well as their potential applications in oil recovery and other industrial processes. - Fuente
- Postprint del artículo publicado en European Polymer Journal, 2019
- Materia
-
POLIMEROS
PROPIEDADES TERMODINAMICAS
COMPOSICION QUIMICA
QUIMICA
MICROESTRUCTURA - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/4.0/
- Repositorio
- Institución
- Pontificia Universidad Católica Argentina
- OAI Identificador
- oai:ucacris:123456789/9020
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spelling |
Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying propertiesIborra, AgustínSalvatierra, Lucas MatíasGiussi, Juan M.Azzaroni, OmarPOLIMEROSPROPIEDADES TERMODINAMICASCOMPOSICION QUIMICAQUIMICAMICROESTRUCTURAFil: Iborra, Agustín. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Iborra, Agustín. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Salvatierra, Lucas Matías. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Salvatierra, Lucas Matías. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Salvatierra, Lucas Matías. Pontificia Universidad Católica Argentina. Facultad de Química e Ingeniería del Rosario; ArgentinaFil: Giussi, Juan M. Universidad Nacional de La Plata. Facultad de Ciencias Exactas.Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Giussi, Juan M. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Azzaroni, Omar. Universidad Nacional de La Plata. Facultad de Ciencias Exactas.Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Azzaroni, Omar. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaAbstract: In this work we study the synthesis and properties of copolymers constituted of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate monomers, prepared by atom transfer radical copolymerization in the entire composition range (with low and high monomer conversion). We propose a description of the copolymer microstructure, and evaluate the composition drift effect in the thermal and solution properties of the obtained copolymers. Nuclear magnetic resonance (NMR) was used to determine the chemical composition of the copolymers, while differential scanning calorimetry and themogravimetric analysis was employed to understand the thermal chracteristics. Rheological studies were conducted to obtain the viscosity and viscoelastic properties that were correlated with thermal transitions at different temperatures. Finally, dynamic light scattering (DLS) and surface tension measurements were used to evaluate the copolymer solution properties. The incorporation of an oil phase in the self-assembled aggregates was evaluated by DLS and characterized by atomic force microscopy, diffusion-ordered spectroscopy NMR and nuclear Overhauser effect NMR spectroscopy.. Our results suggest a longer sequence of LMA units in the copolymer chain and a drift effect in the case of high monomer conversions. A clear dependence on copolymer composition and microstructure to disperse an oil phase in water was observed. We believe that these results bring valuable knowledge that advances the field of macrosurfactants as well as their potential applications in oil recovery and other industrial processes.Elsevier2019info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttps://repositorio.uca.edu.ar/handle/123456789/90200014-305710.1016/j.eurpolymj.2019.04.010Iborra, A. et al. Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties. [en línea]. Postprint del artículo publicado en European Polymer Journal. 2019. doi 10.1016/j.eurpolymj.2019.04.010. Disponible en: https://repositorio.uca.edu.ar/handle/123456789/9020Postprint del artículo publicado en European Polymer Journal, 2019reponame:Repositorio Institucional (UCA)instname:Pontificia Universidad Católica Argentinaenginfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/4.0/2025-07-03T10:57:00Zoai:ucacris:123456789/9020instacron:UCAInstitucionalhttps://repositorio.uca.edu.ar/Universidad privadaNo correspondehttps://repositorio.uca.edu.ar/oaiclaudia_fernandez@uca.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:25852025-07-03 10:57:00.757Repositorio Institucional (UCA) - Pontificia Universidad Católica Argentinafalse |
dc.title.none.fl_str_mv |
Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties |
title |
Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties |
spellingShingle |
Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties Iborra, Agustín POLIMEROS PROPIEDADES TERMODINAMICAS COMPOSICION QUIMICA QUIMICA MICROESTRUCTURA |
title_short |
Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties |
title_full |
Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties |
title_fullStr |
Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties |
title_full_unstemmed |
Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties |
title_sort |
Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties |
dc.creator.none.fl_str_mv |
Iborra, Agustín Salvatierra, Lucas Matías Giussi, Juan M. Azzaroni, Omar |
author |
Iborra, Agustín |
author_facet |
Iborra, Agustín Salvatierra, Lucas Matías Giussi, Juan M. Azzaroni, Omar |
author_role |
author |
author2 |
Salvatierra, Lucas Matías Giussi, Juan M. Azzaroni, Omar |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
POLIMEROS PROPIEDADES TERMODINAMICAS COMPOSICION QUIMICA QUIMICA MICROESTRUCTURA |
topic |
POLIMEROS PROPIEDADES TERMODINAMICAS COMPOSICION QUIMICA QUIMICA MICROESTRUCTURA |
dc.description.none.fl_txt_mv |
Fil: Iborra, Agustín. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina Fil: Iborra, Agustín. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Salvatierra, Lucas Matías. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina Fil: Salvatierra, Lucas Matías. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Salvatierra, Lucas Matías. Pontificia Universidad Católica Argentina. Facultad de Química e Ingeniería del Rosario; Argentina Fil: Giussi, Juan M. Universidad Nacional de La Plata. Facultad de Ciencias Exactas.Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina Fil: Giussi, Juan M. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Azzaroni, Omar. Universidad Nacional de La Plata. Facultad de Ciencias Exactas.Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina Fil: Azzaroni, Omar. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Abstract: In this work we study the synthesis and properties of copolymers constituted of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate monomers, prepared by atom transfer radical copolymerization in the entire composition range (with low and high monomer conversion). We propose a description of the copolymer microstructure, and evaluate the composition drift effect in the thermal and solution properties of the obtained copolymers. Nuclear magnetic resonance (NMR) was used to determine the chemical composition of the copolymers, while differential scanning calorimetry and themogravimetric analysis was employed to understand the thermal chracteristics. Rheological studies were conducted to obtain the viscosity and viscoelastic properties that were correlated with thermal transitions at different temperatures. Finally, dynamic light scattering (DLS) and surface tension measurements were used to evaluate the copolymer solution properties. The incorporation of an oil phase in the self-assembled aggregates was evaluated by DLS and characterized by atomic force microscopy, diffusion-ordered spectroscopy NMR and nuclear Overhauser effect NMR spectroscopy.. Our results suggest a longer sequence of LMA units in the copolymer chain and a drift effect in the case of high monomer conversions. A clear dependence on copolymer composition and microstructure to disperse an oil phase in water was observed. We believe that these results bring valuable knowledge that advances the field of macrosurfactants as well as their potential applications in oil recovery and other industrial processes. |
description |
Fil: Iborra, Agustín. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina |
publishDate |
2019 |
dc.date.none.fl_str_mv |
2019 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
acceptedVersion |
dc.identifier.none.fl_str_mv |
https://repositorio.uca.edu.ar/handle/123456789/9020 0014-3057 10.1016/j.eurpolymj.2019.04.010 Iborra, A. et al. Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties. [en línea]. Postprint del artículo publicado en European Polymer Journal. 2019. doi 10.1016/j.eurpolymj.2019.04.010. Disponible en: https://repositorio.uca.edu.ar/handle/123456789/9020 |
url |
https://repositorio.uca.edu.ar/handle/123456789/9020 |
identifier_str_mv |
0014-3057 10.1016/j.eurpolymj.2019.04.010 Iborra, A. et al. Synthesis of lauryl methacrylate and poly(ethylene glycol) methyl ether methacrylate copolymers with tunable microstructure and emulsifying properties. [en línea]. Postprint del artículo publicado en European Polymer Journal. 2019. doi 10.1016/j.eurpolymj.2019.04.010. Disponible en: https://repositorio.uca.edu.ar/handle/123456789/9020 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/4.0/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/4.0/ |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
Postprint del artículo publicado en European Polymer Journal, 2019 reponame:Repositorio Institucional (UCA) instname:Pontificia Universidad Católica Argentina |
reponame_str |
Repositorio Institucional (UCA) |
collection |
Repositorio Institucional (UCA) |
instname_str |
Pontificia Universidad Católica Argentina |
repository.name.fl_str_mv |
Repositorio Institucional (UCA) - Pontificia Universidad Católica Argentina |
repository.mail.fl_str_mv |
claudia_fernandez@uca.edu.ar |
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1836638348484018176 |
score |
13.070432 |