Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa
- Autores
- Castellanos Buitrago, Nicolás Stiven; Villa, Aída Luz
- Año de publicación
- 2022
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The heat capacity of several terpenes ((−)-carveol, (1R)-(−)-nopyl acetate, γ-terpinene, carvacrol, 3 carene, (1R)-(−)-myrtenol, (S)-(−)-perillyl alcohol, α-pinene oxide and (+)-limonene oxide) were estimated at Medellín (Colombia) atmospheric pressure and in the temperature range from 293.15 K to 353.15 K with a heating rate of 0.5 K/min. All measurements were performed by means of a Setaram E/μDSC 7 Evo-1A microcalorimeter. Heat capacities dependence with temperature were fitted to a third order polynomial equation. Furthermore, heat capacities were estimated using group contribution with Dvorkin et al model, the Dadgostar–Shaw universal correlation and a modified correlation of Dadgostar-Shaw and compared with experimental data. The reliability of the results was evaluated using water as a known substance; the experimental uncertainty measured using naphthalene was lower than 1.5 %.
Fil: Castellanos Buitrago, Nicolás Stiven. Universidad de Antioquia; Colombia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Villa, Aída Luz. Universidad de Antioquia; Colombia - Materia
-
HEAT CAPACITY
MICRO DSC
TEMPERATURE EFFECT
TERPENES - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/211588
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CONICET Digital (CONICET) |
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Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPaCastellanos Buitrago, Nicolás StivenVilla, Aída LuzHEAT CAPACITYMICRO DSCTEMPERATURE EFFECTTERPENEShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The heat capacity of several terpenes ((−)-carveol, (1R)-(−)-nopyl acetate, γ-terpinene, carvacrol, 3 carene, (1R)-(−)-myrtenol, (S)-(−)-perillyl alcohol, α-pinene oxide and (+)-limonene oxide) were estimated at Medellín (Colombia) atmospheric pressure and in the temperature range from 293.15 K to 353.15 K with a heating rate of 0.5 K/min. All measurements were performed by means of a Setaram E/μDSC 7 Evo-1A microcalorimeter. Heat capacities dependence with temperature were fitted to a third order polynomial equation. Furthermore, heat capacities were estimated using group contribution with Dvorkin et al model, the Dadgostar–Shaw universal correlation and a modified correlation of Dadgostar-Shaw and compared with experimental data. The reliability of the results was evaluated using water as a known substance; the experimental uncertainty measured using naphthalene was lower than 1.5 %.Fil: Castellanos Buitrago, Nicolás Stiven. Universidad de Antioquia; Colombia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Villa, Aída Luz. Universidad de Antioquia; ColombiaAcademic Press Ltd - Elsevier Science Ltd2022-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/211588Castellanos Buitrago, Nicolás Stiven; Villa, Aída Luz; Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa; Academic Press Ltd - Elsevier Science Ltd; Journal of Chemical Thermodynamics; 179; 12-2022; 1-250021-9614CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0021961422002622info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jct.2022.106983info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:46:22Zoai:ri.conicet.gov.ar:11336/211588instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:46:22.963CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa |
title |
Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa |
spellingShingle |
Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa Castellanos Buitrago, Nicolás Stiven HEAT CAPACITY MICRO DSC TEMPERATURE EFFECT TERPENES |
title_short |
Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa |
title_full |
Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa |
title_fullStr |
Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa |
title_full_unstemmed |
Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa |
title_sort |
Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa |
dc.creator.none.fl_str_mv |
Castellanos Buitrago, Nicolás Stiven Villa, Aída Luz |
author |
Castellanos Buitrago, Nicolás Stiven |
author_facet |
Castellanos Buitrago, Nicolás Stiven Villa, Aída Luz |
author_role |
author |
author2 |
Villa, Aída Luz |
author2_role |
author |
dc.subject.none.fl_str_mv |
HEAT CAPACITY MICRO DSC TEMPERATURE EFFECT TERPENES |
topic |
HEAT CAPACITY MICRO DSC TEMPERATURE EFFECT TERPENES |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The heat capacity of several terpenes ((−)-carveol, (1R)-(−)-nopyl acetate, γ-terpinene, carvacrol, 3 carene, (1R)-(−)-myrtenol, (S)-(−)-perillyl alcohol, α-pinene oxide and (+)-limonene oxide) were estimated at Medellín (Colombia) atmospheric pressure and in the temperature range from 293.15 K to 353.15 K with a heating rate of 0.5 K/min. All measurements were performed by means of a Setaram E/μDSC 7 Evo-1A microcalorimeter. Heat capacities dependence with temperature were fitted to a third order polynomial equation. Furthermore, heat capacities were estimated using group contribution with Dvorkin et al model, the Dadgostar–Shaw universal correlation and a modified correlation of Dadgostar-Shaw and compared with experimental data. The reliability of the results was evaluated using water as a known substance; the experimental uncertainty measured using naphthalene was lower than 1.5 %. Fil: Castellanos Buitrago, Nicolás Stiven. Universidad de Antioquia; Colombia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Villa, Aída Luz. Universidad de Antioquia; Colombia |
description |
The heat capacity of several terpenes ((−)-carveol, (1R)-(−)-nopyl acetate, γ-terpinene, carvacrol, 3 carene, (1R)-(−)-myrtenol, (S)-(−)-perillyl alcohol, α-pinene oxide and (+)-limonene oxide) were estimated at Medellín (Colombia) atmospheric pressure and in the temperature range from 293.15 K to 353.15 K with a heating rate of 0.5 K/min. All measurements were performed by means of a Setaram E/μDSC 7 Evo-1A microcalorimeter. Heat capacities dependence with temperature were fitted to a third order polynomial equation. Furthermore, heat capacities were estimated using group contribution with Dvorkin et al model, the Dadgostar–Shaw universal correlation and a modified correlation of Dadgostar-Shaw and compared with experimental data. The reliability of the results was evaluated using water as a known substance; the experimental uncertainty measured using naphthalene was lower than 1.5 %. |
publishDate |
2022 |
dc.date.none.fl_str_mv |
2022-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/211588 Castellanos Buitrago, Nicolás Stiven; Villa, Aída Luz; Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa; Academic Press Ltd - Elsevier Science Ltd; Journal of Chemical Thermodynamics; 179; 12-2022; 1-25 0021-9614 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/211588 |
identifier_str_mv |
Castellanos Buitrago, Nicolás Stiven; Villa, Aída Luz; Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa; Academic Press Ltd - Elsevier Science Ltd; Journal of Chemical Thermodynamics; 179; 12-2022; 1-25 0021-9614 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0021961422002622 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jct.2022.106983 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Academic Press Ltd - Elsevier Science Ltd |
publisher.none.fl_str_mv |
Academic Press Ltd - Elsevier Science Ltd |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844613449192046592 |
score |
13.070432 |