Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa

Autores
Castellanos Buitrago, Nicolás Stiven; Villa, Aída Luz
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The heat capacity of several terpenes ((−)-carveol, (1R)-(−)-nopyl acetate, γ-terpinene, carvacrol, 3 carene, (1R)-(−)-myrtenol, (S)-(−)-perillyl alcohol, α-pinene oxide and (+)-limonene oxide) were estimated at Medellín (Colombia) atmospheric pressure and in the temperature range from 293.15 K to 353.15 K with a heating rate of 0.5 K/min. All measurements were performed by means of a Setaram E/μDSC 7 Evo-1A microcalorimeter. Heat capacities dependence with temperature were fitted to a third order polynomial equation. Furthermore, heat capacities were estimated using group contribution with Dvorkin et al model, the Dadgostar–Shaw universal correlation and a modified correlation of Dadgostar-Shaw and compared with experimental data. The reliability of the results was evaluated using water as a known substance; the experimental uncertainty measured using naphthalene was lower than 1.5 %.
Fil: Castellanos Buitrago, Nicolás Stiven. Universidad de Antioquia; Colombia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Villa, Aída Luz. Universidad de Antioquia; Colombia
Materia
HEAT CAPACITY
MICRO DSC
TEMPERATURE EFFECT
TERPENES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/211588
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/211588
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPaCastellanos Buitrago, Nicolás StivenVilla, Aída LuzHEAT CAPACITYMICRO DSCTEMPERATURE EFFECTTERPENEShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The heat capacity of several terpenes ((−)-carveol, (1R)-(−)-nopyl acetate, γ-terpinene, carvacrol, 3 carene, (1R)-(−)-myrtenol, (S)-(−)-perillyl alcohol, α-pinene oxide and (+)-limonene oxide) were estimated at Medellín (Colombia) atmospheric pressure and in the temperature range from 293.15 K to 353.15 K with a heating rate of 0.5 K/min. All measurements were performed by means of a Setaram E/μDSC 7 Evo-1A microcalorimeter. Heat capacities dependence with temperature were fitted to a third order polynomial equation. Furthermore, heat capacities were estimated using group contribution with Dvorkin et al model, the Dadgostar–Shaw universal correlation and a modified correlation of Dadgostar-Shaw and compared with experimental data. The reliability of the results was evaluated using water as a known substance; the experimental uncertainty measured using naphthalene was lower than 1.5 %.Fil: Castellanos Buitrago, Nicolás Stiven. Universidad de Antioquia; Colombia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Villa, Aída Luz. Universidad de Antioquia; ColombiaAcademic Press Ltd - Elsevier Science Ltd2022-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/211588Castellanos Buitrago, Nicolás Stiven; Villa, Aída Luz; Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa; Academic Press Ltd - Elsevier Science Ltd; Journal of Chemical Thermodynamics; 179; 12-2022; 1-250021-9614CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0021961422002622info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jct.2022.106983info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:15:13Zoai:ri.conicet.gov.ar:11336/211588instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:15:14.167CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa
title Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa
spellingShingle Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa
Castellanos Buitrago, Nicolás Stiven
HEAT CAPACITY
MICRO DSC
TEMPERATURE EFFECT
TERPENES
title_short Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa
title_full Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa
title_fullStr Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa
title_full_unstemmed Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa
title_sort Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa
dc.creator.none.fl_str_mv Castellanos Buitrago, Nicolás Stiven
Villa, Aída Luz
author Castellanos Buitrago, Nicolás Stiven
author_facet Castellanos Buitrago, Nicolás Stiven
Villa, Aída Luz
author_role author
author2 Villa, Aída Luz
author2_role author
dc.subject.none.fl_str_mv HEAT CAPACITY
MICRO DSC
TEMPERATURE EFFECT
TERPENES
topic HEAT CAPACITY
MICRO DSC
TEMPERATURE EFFECT
TERPENES
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The heat capacity of several terpenes ((−)-carveol, (1R)-(−)-nopyl acetate, γ-terpinene, carvacrol, 3 carene, (1R)-(−)-myrtenol, (S)-(−)-perillyl alcohol, α-pinene oxide and (+)-limonene oxide) were estimated at Medellín (Colombia) atmospheric pressure and in the temperature range from 293.15 K to 353.15 K with a heating rate of 0.5 K/min. All measurements were performed by means of a Setaram E/μDSC 7 Evo-1A microcalorimeter. Heat capacities dependence with temperature were fitted to a third order polynomial equation. Furthermore, heat capacities were estimated using group contribution with Dvorkin et al model, the Dadgostar–Shaw universal correlation and a modified correlation of Dadgostar-Shaw and compared with experimental data. The reliability of the results was evaluated using water as a known substance; the experimental uncertainty measured using naphthalene was lower than 1.5 %.
Fil: Castellanos Buitrago, Nicolás Stiven. Universidad de Antioquia; Colombia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Villa, Aída Luz. Universidad de Antioquia; Colombia
description The heat capacity of several terpenes ((−)-carveol, (1R)-(−)-nopyl acetate, γ-terpinene, carvacrol, 3 carene, (1R)-(−)-myrtenol, (S)-(−)-perillyl alcohol, α-pinene oxide and (+)-limonene oxide) were estimated at Medellín (Colombia) atmospheric pressure and in the temperature range from 293.15 K to 353.15 K with a heating rate of 0.5 K/min. All measurements were performed by means of a Setaram E/μDSC 7 Evo-1A microcalorimeter. Heat capacities dependence with temperature were fitted to a third order polynomial equation. Furthermore, heat capacities were estimated using group contribution with Dvorkin et al model, the Dadgostar–Shaw universal correlation and a modified correlation of Dadgostar-Shaw and compared with experimental data. The reliability of the results was evaluated using water as a known substance; the experimental uncertainty measured using naphthalene was lower than 1.5 %.
publishDate 2022
dc.date.none.fl_str_mv 2022-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/211588
Castellanos Buitrago, Nicolás Stiven; Villa, Aída Luz; Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa; Academic Press Ltd - Elsevier Science Ltd; Journal of Chemical Thermodynamics; 179; 12-2022; 1-25
0021-9614
CONICET Digital
CONICET
url http://hdl.handle.net/11336/211588
identifier_str_mv Castellanos Buitrago, Nicolás Stiven; Villa, Aída Luz; Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa; Academic Press Ltd - Elsevier Science Ltd; Journal of Chemical Thermodynamics; 179; 12-2022; 1-25
0021-9614
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0021961422002622
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jct.2022.106983
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Academic Press Ltd - Elsevier Science Ltd
publisher.none.fl_str_mv Academic Press Ltd - Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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