UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city
- Autores
- Fujiwara, Fabián Guillermo; Guiñez, María Evangelina; Cerutti, Estela Soledad; Smichowski, Patricia Nora
- Año de publicación
- 2014
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- A study was undertaken to evaluate the content of oxygenated and nitrated polycyclic aromatic hydrocarbons (OPAHs and NPAHs) in airborne particulate matter (PM2.5 and PM10), and tree barks. For PM2.5 and PM10 collection different approaches were followed using different type of filters and sample collectors. Samples of PM2.5 were collected on glass fiber filters during one month with a medium volume sampler. For PM10, glass and quartz fiber filters were used and samples were collected simultaneously for one week using a high volume sampler. In addition, bark samples were collected at the same sites. Ultra high performance liquid chromatography-atmospheric pressure chemical ionization tandem mass spectrometry (UHPLC-APCI-MS/MS) was used for PAHs derivatives quantification. Data acquisition under MS/MS was achieved by applying multiple reaction monitoring to provide a high degree of sensitivity and specificity. Chromatographic separation was performed on a reverse phase rapid resolution column using a gradient mode (total run time: 5.0 min). The study evidenced that in airborne particles matter, four PAHs derivatives were detected at concentrations from 0.01 to 240.62 ng m-3 (or 0.3 µg g-1 to 30 mg g-1). Meanwhile, in tree barks, only OPAHs were detected at concentrations varying from 0.18 to 0.72 µg g-1.
Fil: Fujiwara, Fabián Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Guiñez, María Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Cerutti, Estela Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Smichowski, Patricia Nora. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comision Nacional de Energia Atomica. Gerencia Quimica. CAC; Argentina - Materia
-
OPAHs
NPAHs
UHPLC-(+)APCI-MS/MS
APM
Tree Barks - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/7373
Ver los metadatos del registro completo
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network_name_str |
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spelling |
UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires cityFujiwara, Fabián GuillermoGuiñez, María EvangelinaCerutti, Estela SoledadSmichowski, Patricia NoraOPAHsNPAHsUHPLC-(+)APCI-MS/MSAPMTree Barkshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1A study was undertaken to evaluate the content of oxygenated and nitrated polycyclic aromatic hydrocarbons (OPAHs and NPAHs) in airborne particulate matter (PM2.5 and PM10), and tree barks. For PM2.5 and PM10 collection different approaches were followed using different type of filters and sample collectors. Samples of PM2.5 were collected on glass fiber filters during one month with a medium volume sampler. For PM10, glass and quartz fiber filters were used and samples were collected simultaneously for one week using a high volume sampler. In addition, bark samples were collected at the same sites. Ultra high performance liquid chromatography-atmospheric pressure chemical ionization tandem mass spectrometry (UHPLC-APCI-MS/MS) was used for PAHs derivatives quantification. Data acquisition under MS/MS was achieved by applying multiple reaction monitoring to provide a high degree of sensitivity and specificity. Chromatographic separation was performed on a reverse phase rapid resolution column using a gradient mode (total run time: 5.0 min). The study evidenced that in airborne particles matter, four PAHs derivatives were detected at concentrations from 0.01 to 240.62 ng m-3 (or 0.3 µg g-1 to 30 mg g-1). Meanwhile, in tree barks, only OPAHs were detected at concentrations varying from 0.18 to 0.72 µg g-1.Fil: Fujiwara, Fabián Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; ArgentinaFil: Guiñez, María Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; ArgentinaFil: Cerutti, Estela Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; ArgentinaFil: Smichowski, Patricia Nora. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comision Nacional de Energia Atomica. Gerencia Quimica. CAC; ArgentinaElsevier Science2014-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/7373Fujiwara, Fabián Guillermo; Guiñez, María Evangelina; Cerutti, Estela Soledad; Smichowski, Patricia Nora; UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city; Elsevier Science; Microchemical Journal; 116; 5-2014; 118-1240026-265Xenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0026265X14000630info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2014.04.004info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:56:37Zoai:ri.conicet.gov.ar:11336/7373instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:56:37.296CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city |
title |
UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city |
spellingShingle |
UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city Fujiwara, Fabián Guillermo OPAHs NPAHs UHPLC-(+)APCI-MS/MS APM Tree Barks |
title_short |
UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city |
title_full |
UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city |
title_fullStr |
UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city |
title_full_unstemmed |
UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city |
title_sort |
UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city |
dc.creator.none.fl_str_mv |
Fujiwara, Fabián Guillermo Guiñez, María Evangelina Cerutti, Estela Soledad Smichowski, Patricia Nora |
author |
Fujiwara, Fabián Guillermo |
author_facet |
Fujiwara, Fabián Guillermo Guiñez, María Evangelina Cerutti, Estela Soledad Smichowski, Patricia Nora |
author_role |
author |
author2 |
Guiñez, María Evangelina Cerutti, Estela Soledad Smichowski, Patricia Nora |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
OPAHs NPAHs UHPLC-(+)APCI-MS/MS APM Tree Barks |
topic |
OPAHs NPAHs UHPLC-(+)APCI-MS/MS APM Tree Barks |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 https://purl.org/becyt/ford/1.5 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
A study was undertaken to evaluate the content of oxygenated and nitrated polycyclic aromatic hydrocarbons (OPAHs and NPAHs) in airborne particulate matter (PM2.5 and PM10), and tree barks. For PM2.5 and PM10 collection different approaches were followed using different type of filters and sample collectors. Samples of PM2.5 were collected on glass fiber filters during one month with a medium volume sampler. For PM10, glass and quartz fiber filters were used and samples were collected simultaneously for one week using a high volume sampler. In addition, bark samples were collected at the same sites. Ultra high performance liquid chromatography-atmospheric pressure chemical ionization tandem mass spectrometry (UHPLC-APCI-MS/MS) was used for PAHs derivatives quantification. Data acquisition under MS/MS was achieved by applying multiple reaction monitoring to provide a high degree of sensitivity and specificity. Chromatographic separation was performed on a reverse phase rapid resolution column using a gradient mode (total run time: 5.0 min). The study evidenced that in airborne particles matter, four PAHs derivatives were detected at concentrations from 0.01 to 240.62 ng m-3 (or 0.3 µg g-1 to 30 mg g-1). Meanwhile, in tree barks, only OPAHs were detected at concentrations varying from 0.18 to 0.72 µg g-1. Fil: Fujiwara, Fabián Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina Fil: Guiñez, María Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina Fil: Cerutti, Estela Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina Fil: Smichowski, Patricia Nora. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comision Nacional de Energia Atomica. Gerencia Quimica. CAC; Argentina |
description |
A study was undertaken to evaluate the content of oxygenated and nitrated polycyclic aromatic hydrocarbons (OPAHs and NPAHs) in airborne particulate matter (PM2.5 and PM10), and tree barks. For PM2.5 and PM10 collection different approaches were followed using different type of filters and sample collectors. Samples of PM2.5 were collected on glass fiber filters during one month with a medium volume sampler. For PM10, glass and quartz fiber filters were used and samples were collected simultaneously for one week using a high volume sampler. In addition, bark samples were collected at the same sites. Ultra high performance liquid chromatography-atmospheric pressure chemical ionization tandem mass spectrometry (UHPLC-APCI-MS/MS) was used for PAHs derivatives quantification. Data acquisition under MS/MS was achieved by applying multiple reaction monitoring to provide a high degree of sensitivity and specificity. Chromatographic separation was performed on a reverse phase rapid resolution column using a gradient mode (total run time: 5.0 min). The study evidenced that in airborne particles matter, four PAHs derivatives were detected at concentrations from 0.01 to 240.62 ng m-3 (or 0.3 µg g-1 to 30 mg g-1). Meanwhile, in tree barks, only OPAHs were detected at concentrations varying from 0.18 to 0.72 µg g-1. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-05 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/7373 Fujiwara, Fabián Guillermo; Guiñez, María Evangelina; Cerutti, Estela Soledad; Smichowski, Patricia Nora; UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city; Elsevier Science; Microchemical Journal; 116; 5-2014; 118-124 0026-265X |
url |
http://hdl.handle.net/11336/7373 |
identifier_str_mv |
Fujiwara, Fabián Guillermo; Guiñez, María Evangelina; Cerutti, Estela Soledad; Smichowski, Patricia Nora; UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city; Elsevier Science; Microchemical Journal; 116; 5-2014; 118-124 0026-265X |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0026265X14000630 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2014.04.004 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842269413339824128 |
score |
13.13397 |