UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city

Autores
Fujiwara, Fabián Guillermo; Guiñez, María Evangelina; Cerutti, Estela Soledad; Smichowski, Patricia Nora
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A study was undertaken to evaluate the content of oxygenated and nitrated polycyclic aromatic hydrocarbons (OPAHs and NPAHs) in airborne particulate matter (PM2.5 and PM10), and tree barks. For PM2.5 and PM10 collection different approaches were followed using different type of filters and sample collectors. Samples of PM2.5 were collected on glass fiber filters during one month with a medium volume sampler. For PM10, glass and quartz fiber filters were used and samples were collected simultaneously for one week using a high volume sampler. In addition, bark samples were collected at the same sites. Ultra high performance liquid chromatography-atmospheric pressure chemical ionization tandem mass spectrometry (UHPLC-APCI-MS/MS) was used for PAHs derivatives quantification. Data acquisition under MS/MS was achieved by applying multiple reaction monitoring to provide a high degree of sensitivity and specificity. Chromatographic separation was performed on a reverse phase rapid resolution column using a gradient mode (total run time: 5.0 min). The study evidenced that in airborne particles matter, four PAHs derivatives were detected at concentrations from 0.01 to 240.62 ng m-3 (or 0.3 µg g-1 to 30 mg g-1). Meanwhile, in tree barks, only OPAHs were detected at concentrations varying from 0.18 to 0.72 µg g-1.
Fil: Fujiwara, Fabián Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Guiñez, María Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Cerutti, Estela Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Smichowski, Patricia Nora. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comision Nacional de Energia Atomica. Gerencia Quimica. CAC; Argentina
Materia
OPAHs
NPAHs
UHPLC-(+)APCI-MS/MS
APM
Tree Barks
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/7373
Acceder
id CONICETDig_a6feb22903f6539812577da62e7b97cd
oai_identifier_str oai:ri.conicet.gov.ar:11336/7373
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires cityFujiwara, Fabián GuillermoGuiñez, María EvangelinaCerutti, Estela SoledadSmichowski, Patricia NoraOPAHsNPAHsUHPLC-(+)APCI-MS/MSAPMTree Barkshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1A study was undertaken to evaluate the content of oxygenated and nitrated polycyclic aromatic hydrocarbons (OPAHs and NPAHs) in airborne particulate matter (PM2.5 and PM10), and tree barks. For PM2.5 and PM10 collection different approaches were followed using different type of filters and sample collectors. Samples of PM2.5 were collected on glass fiber filters during one month with a medium volume sampler. For PM10, glass and quartz fiber filters were used and samples were collected simultaneously for one week using a high volume sampler. In addition, bark samples were collected at the same sites. Ultra high performance liquid chromatography-atmospheric pressure chemical ionization tandem mass spectrometry (UHPLC-APCI-MS/MS) was used for PAHs derivatives quantification. Data acquisition under MS/MS was achieved by applying multiple reaction monitoring to provide a high degree of sensitivity and specificity. Chromatographic separation was performed on a reverse phase rapid resolution column using a gradient mode (total run time: 5.0 min). The study evidenced that in airborne particles matter, four PAHs derivatives were detected at concentrations from 0.01 to 240.62 ng m-3 (or 0.3 µg g-1 to 30 mg g-1). Meanwhile, in tree barks, only OPAHs were detected at concentrations varying from 0.18 to 0.72 µg g-1.Fil: Fujiwara, Fabián Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; ArgentinaFil: Guiñez, María Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; ArgentinaFil: Cerutti, Estela Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; ArgentinaFil: Smichowski, Patricia Nora. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comision Nacional de Energia Atomica. Gerencia Quimica. CAC; ArgentinaElsevier Science2014-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/7373Fujiwara, Fabián Guillermo; Guiñez, María Evangelina; Cerutti, Estela Soledad; Smichowski, Patricia Nora; UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city; Elsevier Science; Microchemical Journal; 116; 5-2014; 118-1240026-265Xenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0026265X14000630info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2014.04.004info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:01:06Zoai:ri.conicet.gov.ar:11336/7373instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:01:06.376CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city
title UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city
spellingShingle UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city
Fujiwara, Fabián Guillermo
OPAHs
NPAHs
UHPLC-(+)APCI-MS/MS
APM
Tree Barks
title_short UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city
title_full UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city
title_fullStr UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city
title_full_unstemmed UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city
title_sort UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city
dc.creator.none.fl_str_mv Fujiwara, Fabián Guillermo
Guiñez, María Evangelina
Cerutti, Estela Soledad
Smichowski, Patricia Nora
author Fujiwara, Fabián Guillermo
author_facet Fujiwara, Fabián Guillermo
Guiñez, María Evangelina
Cerutti, Estela Soledad
Smichowski, Patricia Nora
author_role author
author2 Guiñez, María Evangelina
Cerutti, Estela Soledad
Smichowski, Patricia Nora
author2_role author
author
author
dc.subject.none.fl_str_mv OPAHs
NPAHs
UHPLC-(+)APCI-MS/MS
APM
Tree Barks
topic OPAHs
NPAHs
UHPLC-(+)APCI-MS/MS
APM
Tree Barks
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A study was undertaken to evaluate the content of oxygenated and nitrated polycyclic aromatic hydrocarbons (OPAHs and NPAHs) in airborne particulate matter (PM2.5 and PM10), and tree barks. For PM2.5 and PM10 collection different approaches were followed using different type of filters and sample collectors. Samples of PM2.5 were collected on glass fiber filters during one month with a medium volume sampler. For PM10, glass and quartz fiber filters were used and samples were collected simultaneously for one week using a high volume sampler. In addition, bark samples were collected at the same sites. Ultra high performance liquid chromatography-atmospheric pressure chemical ionization tandem mass spectrometry (UHPLC-APCI-MS/MS) was used for PAHs derivatives quantification. Data acquisition under MS/MS was achieved by applying multiple reaction monitoring to provide a high degree of sensitivity and specificity. Chromatographic separation was performed on a reverse phase rapid resolution column using a gradient mode (total run time: 5.0 min). The study evidenced that in airborne particles matter, four PAHs derivatives were detected at concentrations from 0.01 to 240.62 ng m-3 (or 0.3 µg g-1 to 30 mg g-1). Meanwhile, in tree barks, only OPAHs were detected at concentrations varying from 0.18 to 0.72 µg g-1.
Fil: Fujiwara, Fabián Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Guiñez, María Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Cerutti, Estela Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Smichowski, Patricia Nora. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comision Nacional de Energia Atomica. Gerencia Quimica. CAC; Argentina
description A study was undertaken to evaluate the content of oxygenated and nitrated polycyclic aromatic hydrocarbons (OPAHs and NPAHs) in airborne particulate matter (PM2.5 and PM10), and tree barks. For PM2.5 and PM10 collection different approaches were followed using different type of filters and sample collectors. Samples of PM2.5 were collected on glass fiber filters during one month with a medium volume sampler. For PM10, glass and quartz fiber filters were used and samples were collected simultaneously for one week using a high volume sampler. In addition, bark samples were collected at the same sites. Ultra high performance liquid chromatography-atmospheric pressure chemical ionization tandem mass spectrometry (UHPLC-APCI-MS/MS) was used for PAHs derivatives quantification. Data acquisition under MS/MS was achieved by applying multiple reaction monitoring to provide a high degree of sensitivity and specificity. Chromatographic separation was performed on a reverse phase rapid resolution column using a gradient mode (total run time: 5.0 min). The study evidenced that in airborne particles matter, four PAHs derivatives were detected at concentrations from 0.01 to 240.62 ng m-3 (or 0.3 µg g-1 to 30 mg g-1). Meanwhile, in tree barks, only OPAHs were detected at concentrations varying from 0.18 to 0.72 µg g-1.
publishDate 2014
dc.date.none.fl_str_mv 2014-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/7373
Fujiwara, Fabián Guillermo; Guiñez, María Evangelina; Cerutti, Estela Soledad; Smichowski, Patricia Nora; UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city; Elsevier Science; Microchemical Journal; 116; 5-2014; 118-124
0026-265X
url http://hdl.handle.net/11336/7373
identifier_str_mv Fujiwara, Fabián Guillermo; Guiñez, María Evangelina; Cerutti, Estela Soledad; Smichowski, Patricia Nora; UHPLC-(+)APCI-MS/MS determination of oxygenated and nitrated polycyclic aromatic hydrocarbons in airborne particulate matter and tree barks collected in Buenos Aires city; Elsevier Science; Microchemical Journal; 116; 5-2014; 118-124
0026-265X
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0026265X14000630
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2014.04.004
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.069144

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