Insight into the Metal Content–Structure–Property Relationship in Lanthanide Metal–Organic Frameworks: Optical Studies, Magnetism, and Catalytic Performance

Autores
Gomez, Germán Ernesto; Brusau, Elena Virginia; Sacanell, Joaquin Gonzalo; Soler Illia, Galo Juan de Avila Arturo; Narda, Griselda Edith
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Two series of metal–organic frameworks (MOFs) based on a flexible ligand and trivalent lanthanides were obtained hydrothermally in order to explore their optical properties at low temperature, magnetism, and catalytic activity in relation to their structural features. A multisite analysis was performed according to the 4f–4f transitions. Moreover, the heterogeneous catalytic activity of the series was evaluated in one-pot cyanosilylation with benzaldehyde as substrate. Recyclability, structure conservation, and catalytic efficiency were also evaluated and compared with those of analogous compounds.
Fil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Brusau, Elena Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Sacanell, Joaquin Gonzalo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área Investigaciones y Aplicaciones no Nucleares; Argentina
Fil: Soler Illia, Galo Juan de Avila Arturo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina
Fil: Narda, Griselda Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Materia
HETEROGENEOUS CATALYSIS
HYDROTHERMAL SYNTHESIS
LANTHANIDES
MAGNETIC PROPERTIES
METAL–ORGANIC FRAMEWORKS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/88061
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/88061
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Insight into the Metal Content–Structure–Property Relationship in Lanthanide Metal–Organic Frameworks: Optical Studies, Magnetism, and Catalytic PerformanceGomez, Germán ErnestoBrusau, Elena VirginiaSacanell, Joaquin GonzaloSoler Illia, Galo Juan de Avila ArturoNarda, Griselda EdithHETEROGENEOUS CATALYSISHYDROTHERMAL SYNTHESISLANTHANIDESMAGNETIC PROPERTIESMETAL–ORGANIC FRAMEWORKShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Two series of metal–organic frameworks (MOFs) based on a flexible ligand and trivalent lanthanides were obtained hydrothermally in order to explore their optical properties at low temperature, magnetism, and catalytic activity in relation to their structural features. A multisite analysis was performed according to the 4f–4f transitions. Moreover, the heterogeneous catalytic activity of the series was evaluated in one-pot cyanosilylation with benzaldehyde as substrate. Recyclability, structure conservation, and catalytic efficiency were also evaluated and compared with those of analogous compounds.Fil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Brusau, Elena Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Sacanell, Joaquin Gonzalo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área Investigaciones y Aplicaciones no Nucleares; ArgentinaFil: Soler Illia, Galo Juan de Avila Arturo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; ArgentinaFil: Narda, Griselda Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaWiley VCH Verlag2018-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/88061Gomez, Germán Ernesto; Brusau, Elena Virginia; Sacanell, Joaquin Gonzalo; Soler Illia, Galo Juan de Avila Arturo; Narda, Griselda Edith; Insight into the Metal Content–Structure–Property Relationship in Lanthanide Metal–Organic Frameworks: Optical Studies, Magnetism, and Catalytic Performance; Wiley VCH Verlag; European Journal of Inorganic Chemistry; 2018; 20; 6-2018; 2452-24601434-1948CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/ejic.201701474info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201701474info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:31:27Zoai:ri.conicet.gov.ar:11336/88061instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:31:28.121CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Insight into the Metal Content–Structure–Property Relationship in Lanthanide Metal–Organic Frameworks: Optical Studies, Magnetism, and Catalytic Performance
title Insight into the Metal Content–Structure–Property Relationship in Lanthanide Metal–Organic Frameworks: Optical Studies, Magnetism, and Catalytic Performance
spellingShingle Insight into the Metal Content–Structure–Property Relationship in Lanthanide Metal–Organic Frameworks: Optical Studies, Magnetism, and Catalytic Performance
Gomez, Germán Ernesto
HETEROGENEOUS CATALYSIS
HYDROTHERMAL SYNTHESIS
LANTHANIDES
MAGNETIC PROPERTIES
METAL–ORGANIC FRAMEWORKS
title_short Insight into the Metal Content–Structure–Property Relationship in Lanthanide Metal–Organic Frameworks: Optical Studies, Magnetism, and Catalytic Performance
title_full Insight into the Metal Content–Structure–Property Relationship in Lanthanide Metal–Organic Frameworks: Optical Studies, Magnetism, and Catalytic Performance
title_fullStr Insight into the Metal Content–Structure–Property Relationship in Lanthanide Metal–Organic Frameworks: Optical Studies, Magnetism, and Catalytic Performance
title_full_unstemmed Insight into the Metal Content–Structure–Property Relationship in Lanthanide Metal–Organic Frameworks: Optical Studies, Magnetism, and Catalytic Performance
title_sort Insight into the Metal Content–Structure–Property Relationship in Lanthanide Metal–Organic Frameworks: Optical Studies, Magnetism, and Catalytic Performance
dc.creator.none.fl_str_mv Gomez, Germán Ernesto
Brusau, Elena Virginia
Sacanell, Joaquin Gonzalo
Soler Illia, Galo Juan de Avila Arturo
Narda, Griselda Edith
author Gomez, Germán Ernesto
author_facet Gomez, Germán Ernesto
Brusau, Elena Virginia
Sacanell, Joaquin Gonzalo
Soler Illia, Galo Juan de Avila Arturo
Narda, Griselda Edith
author_role author
author2 Brusau, Elena Virginia
Sacanell, Joaquin Gonzalo
Soler Illia, Galo Juan de Avila Arturo
Narda, Griselda Edith
author2_role author
author
author
author
dc.subject.none.fl_str_mv HETEROGENEOUS CATALYSIS
HYDROTHERMAL SYNTHESIS
LANTHANIDES
MAGNETIC PROPERTIES
METAL–ORGANIC FRAMEWORKS
topic HETEROGENEOUS CATALYSIS
HYDROTHERMAL SYNTHESIS
LANTHANIDES
MAGNETIC PROPERTIES
METAL–ORGANIC FRAMEWORKS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Two series of metal–organic frameworks (MOFs) based on a flexible ligand and trivalent lanthanides were obtained hydrothermally in order to explore their optical properties at low temperature, magnetism, and catalytic activity in relation to their structural features. A multisite analysis was performed according to the 4f–4f transitions. Moreover, the heterogeneous catalytic activity of the series was evaluated in one-pot cyanosilylation with benzaldehyde as substrate. Recyclability, structure conservation, and catalytic efficiency were also evaluated and compared with those of analogous compounds.
Fil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Brusau, Elena Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Sacanell, Joaquin Gonzalo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área Investigaciones y Aplicaciones no Nucleares; Argentina
Fil: Soler Illia, Galo Juan de Avila Arturo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina
Fil: Narda, Griselda Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
description Two series of metal–organic frameworks (MOFs) based on a flexible ligand and trivalent lanthanides were obtained hydrothermally in order to explore their optical properties at low temperature, magnetism, and catalytic activity in relation to their structural features. A multisite analysis was performed according to the 4f–4f transitions. Moreover, the heterogeneous catalytic activity of the series was evaluated in one-pot cyanosilylation with benzaldehyde as substrate. Recyclability, structure conservation, and catalytic efficiency were also evaluated and compared with those of analogous compounds.
publishDate 2018
dc.date.none.fl_str_mv 2018-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/88061
Gomez, Germán Ernesto; Brusau, Elena Virginia; Sacanell, Joaquin Gonzalo; Soler Illia, Galo Juan de Avila Arturo; Narda, Griselda Edith; Insight into the Metal Content–Structure–Property Relationship in Lanthanide Metal–Organic Frameworks: Optical Studies, Magnetism, and Catalytic Performance; Wiley VCH Verlag; European Journal of Inorganic Chemistry; 2018; 20; 6-2018; 2452-2460
1434-1948
CONICET Digital
CONICET
url http://hdl.handle.net/11336/88061
identifier_str_mv Gomez, Germán Ernesto; Brusau, Elena Virginia; Sacanell, Joaquin Gonzalo; Soler Illia, Galo Juan de Avila Arturo; Narda, Griselda Edith; Insight into the Metal Content–Structure–Property Relationship in Lanthanide Metal–Organic Frameworks: Optical Studies, Magnetism, and Catalytic Performance; Wiley VCH Verlag; European Journal of Inorganic Chemistry; 2018; 20; 6-2018; 2452-2460
1434-1948
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/ejic.201701474
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201701474
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846082798612381696
score 13.22299

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