Two Sets of Metal Organic Frameworks along the Lanthanide Series Constructed by 2,3-Dimethylsuccinate: Structures, Topologies, and Strong Emission without Ligand Sensitization

Autores
Gomez, Germán Ernesto; Bernini, Maria Celeste; Brusau, Elena Virginia; Narda, Griselda Edith; Massad, Walter Alfredo; Labrador, Ana
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Reactions in aqueous solution under hydrothermal conditions between (±)-2,3-dimethylsuccinic acid and lanthanide chlorides lead to two different isostructural types with chemical formulas [Ln2(C6H8O4)3(H2O)2] Ln(III) = Pr−Eu (except Pm) (Type I, compounds 1−4) and [Ln2(C6H8O4)3] Ln(III) = Tb−Yb (except Tm) (Type II, compounds 5−9). The crystal structure has been solved for the Pr (1)-, Sm (3)-, and Ho (7)-containing compounds by means of single-crystal XRD methods, whereas powder XRD Rietveld refinement was used for the rest of the MOFs. Compounds 1−4 crystallize in the triclinic space group P1̅, whereas compounds 5−9 belong to the tetragonal space group P43212. Type I and II compounds are 3D frameworks consisting of chains of [LnO8(H2O)] or [LnO8] polyhedra, respectively, linked by dimethylsuccinate anions, giving rise to I1 O2 connectivity. All the compounds were characterized by X-ray diffraction, variable-temperature Fourier transform infrared spectroscopy, and thermal analysis. An exhaustive topological study was performed in comparison with other related compounds. The photoluminescent (PL) properties for compounds 3, 4, and 5 have been also explored, indicating that a metal-centered luminescent process takes place.
Fil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Area Química General e Inorgánica; Argentina
Fil: Bernini, Maria Celeste. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Area Química General e Inorgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Brusau, Elena Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Area Química General e Inorgánica; Argentina
Fil: Narda, Griselda Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Area Química General e Inorgánica; Argentina
Fil: Massad, Walter Alfredo. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Labrador, Ana. No especifíca;
Materia
Lanthanide
Mofs
Luminiscence
Topology
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
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Consejo Nacional de Investigaciones Científicas y Técnicas
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oai:ri.conicet.gov.ar:11336/2276
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/2276
network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Two Sets of Metal Organic Frameworks along the Lanthanide Series Constructed by 2,3-Dimethylsuccinate: Structures, Topologies, and Strong Emission without Ligand SensitizationGomez, Germán ErnestoBernini, Maria CelesteBrusau, Elena VirginiaNarda, Griselda EdithMassad, Walter AlfredoLabrador, AnaLanthanideMofsLuminiscenceTopologyhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Reactions in aqueous solution under hydrothermal conditions between (±)-2,3-dimethylsuccinic acid and lanthanide chlorides lead to two different isostructural types with chemical formulas [Ln2(C6H8O4)3(H2O)2] Ln(III) = Pr−Eu (except Pm) (Type I, compounds 1−4) and [Ln2(C6H8O4)3] Ln(III) = Tb−Yb (except Tm) (Type II, compounds 5−9). The crystal structure has been solved for the Pr (1)-, Sm (3)-, and Ho (7)-containing compounds by means of single-crystal XRD methods, whereas powder XRD Rietveld refinement was used for the rest of the MOFs. Compounds 1−4 crystallize in the triclinic space group P1̅, whereas compounds 5−9 belong to the tetragonal space group P43212. Type I and II compounds are 3D frameworks consisting of chains of [LnO8(H2O)] or [LnO8] polyhedra, respectively, linked by dimethylsuccinate anions, giving rise to I1 O2 connectivity. All the compounds were characterized by X-ray diffraction, variable-temperature Fourier transform infrared spectroscopy, and thermal analysis. An exhaustive topological study was performed in comparison with other related compounds. The photoluminescent (PL) properties for compounds 3, 4, and 5 have been also explored, indicating that a metal-centered luminescent process takes place.Fil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Area Química General e Inorgánica; ArgentinaFil: Bernini, Maria Celeste. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Area Química General e Inorgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Brusau, Elena Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Area Química General e Inorgánica; ArgentinaFil: Narda, Griselda Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Area Química General e Inorgánica; ArgentinaFil: Massad, Walter Alfredo. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; ArgentinaFil: Labrador, Ana. No especifíca;American Chemical Society2013-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/2276Gomez, Germán Ernesto; Bernini, Maria Celeste; Brusau, Elena Virginia; Narda, Griselda Edith; Massad, Walter Alfredo; et al.; Two Sets of Metal Organic Frameworks along the Lanthanide Series Constructed by 2,3-Dimethylsuccinate: Structures, Topologies, and Strong Emission without Ligand Sensitization; American Chemical Society; Crystal Growth & Design; 13; 12; 10-2013; 5249-52601528-7483enginfo:eu-repo/semantics/altIdentifier/doi/10.1021/cg401006dinfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/cg401006dinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:39:28Zoai:ri.conicet.gov.ar:11336/2276instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:39:28.421CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Two Sets of Metal Organic Frameworks along the Lanthanide Series Constructed by 2,3-Dimethylsuccinate: Structures, Topologies, and Strong Emission without Ligand Sensitization
title Two Sets of Metal Organic Frameworks along the Lanthanide Series Constructed by 2,3-Dimethylsuccinate: Structures, Topologies, and Strong Emission without Ligand Sensitization
spellingShingle Two Sets of Metal Organic Frameworks along the Lanthanide Series Constructed by 2,3-Dimethylsuccinate: Structures, Topologies, and Strong Emission without Ligand Sensitization
Gomez, Germán Ernesto
Lanthanide
Mofs
Luminiscence
Topology
title_short Two Sets of Metal Organic Frameworks along the Lanthanide Series Constructed by 2,3-Dimethylsuccinate: Structures, Topologies, and Strong Emission without Ligand Sensitization
title_full Two Sets of Metal Organic Frameworks along the Lanthanide Series Constructed by 2,3-Dimethylsuccinate: Structures, Topologies, and Strong Emission without Ligand Sensitization
title_fullStr Two Sets of Metal Organic Frameworks along the Lanthanide Series Constructed by 2,3-Dimethylsuccinate: Structures, Topologies, and Strong Emission without Ligand Sensitization
title_full_unstemmed Two Sets of Metal Organic Frameworks along the Lanthanide Series Constructed by 2,3-Dimethylsuccinate: Structures, Topologies, and Strong Emission without Ligand Sensitization
title_sort Two Sets of Metal Organic Frameworks along the Lanthanide Series Constructed by 2,3-Dimethylsuccinate: Structures, Topologies, and Strong Emission without Ligand Sensitization
dc.creator.none.fl_str_mv Gomez, Germán Ernesto
Bernini, Maria Celeste
Brusau, Elena Virginia
Narda, Griselda Edith
Massad, Walter Alfredo
Labrador, Ana
author Gomez, Germán Ernesto
author_facet Gomez, Germán Ernesto
Bernini, Maria Celeste
Brusau, Elena Virginia
Narda, Griselda Edith
Massad, Walter Alfredo
Labrador, Ana
author_role author
author2 Bernini, Maria Celeste
Brusau, Elena Virginia
Narda, Griselda Edith
Massad, Walter Alfredo
Labrador, Ana
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Lanthanide
Mofs
Luminiscence
Topology
topic Lanthanide
Mofs
Luminiscence
Topology
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Reactions in aqueous solution under hydrothermal conditions between (±)-2,3-dimethylsuccinic acid and lanthanide chlorides lead to two different isostructural types with chemical formulas [Ln2(C6H8O4)3(H2O)2] Ln(III) = Pr−Eu (except Pm) (Type I, compounds 1−4) and [Ln2(C6H8O4)3] Ln(III) = Tb−Yb (except Tm) (Type II, compounds 5−9). The crystal structure has been solved for the Pr (1)-, Sm (3)-, and Ho (7)-containing compounds by means of single-crystal XRD methods, whereas powder XRD Rietveld refinement was used for the rest of the MOFs. Compounds 1−4 crystallize in the triclinic space group P1̅, whereas compounds 5−9 belong to the tetragonal space group P43212. Type I and II compounds are 3D frameworks consisting of chains of [LnO8(H2O)] or [LnO8] polyhedra, respectively, linked by dimethylsuccinate anions, giving rise to I1 O2 connectivity. All the compounds were characterized by X-ray diffraction, variable-temperature Fourier transform infrared spectroscopy, and thermal analysis. An exhaustive topological study was performed in comparison with other related compounds. The photoluminescent (PL) properties for compounds 3, 4, and 5 have been also explored, indicating that a metal-centered luminescent process takes place.
Fil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Area Química General e Inorgánica; Argentina
Fil: Bernini, Maria Celeste. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Area Química General e Inorgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Brusau, Elena Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Area Química General e Inorgánica; Argentina
Fil: Narda, Griselda Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Area Química General e Inorgánica; Argentina
Fil: Massad, Walter Alfredo. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Labrador, Ana. No especifíca;
description Reactions in aqueous solution under hydrothermal conditions between (±)-2,3-dimethylsuccinic acid and lanthanide chlorides lead to two different isostructural types with chemical formulas [Ln2(C6H8O4)3(H2O)2] Ln(III) = Pr−Eu (except Pm) (Type I, compounds 1−4) and [Ln2(C6H8O4)3] Ln(III) = Tb−Yb (except Tm) (Type II, compounds 5−9). The crystal structure has been solved for the Pr (1)-, Sm (3)-, and Ho (7)-containing compounds by means of single-crystal XRD methods, whereas powder XRD Rietveld refinement was used for the rest of the MOFs. Compounds 1−4 crystallize in the triclinic space group P1̅, whereas compounds 5−9 belong to the tetragonal space group P43212. Type I and II compounds are 3D frameworks consisting of chains of [LnO8(H2O)] or [LnO8] polyhedra, respectively, linked by dimethylsuccinate anions, giving rise to I1 O2 connectivity. All the compounds were characterized by X-ray diffraction, variable-temperature Fourier transform infrared spectroscopy, and thermal analysis. An exhaustive topological study was performed in comparison with other related compounds. The photoluminescent (PL) properties for compounds 3, 4, and 5 have been also explored, indicating that a metal-centered luminescent process takes place.
publishDate 2013
dc.date.none.fl_str_mv 2013-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/2276
Gomez, Germán Ernesto; Bernini, Maria Celeste; Brusau, Elena Virginia; Narda, Griselda Edith; Massad, Walter Alfredo; et al.; Two Sets of Metal Organic Frameworks along the Lanthanide Series Constructed by 2,3-Dimethylsuccinate: Structures, Topologies, and Strong Emission without Ligand Sensitization; American Chemical Society; Crystal Growth & Design; 13; 12; 10-2013; 5249-5260
1528-7483
url http://hdl.handle.net/11336/2276
identifier_str_mv Gomez, Germán Ernesto; Bernini, Maria Celeste; Brusau, Elena Virginia; Narda, Griselda Edith; Massad, Walter Alfredo; et al.; Two Sets of Metal Organic Frameworks along the Lanthanide Series Constructed by 2,3-Dimethylsuccinate: Structures, Topologies, and Strong Emission without Ligand Sensitization; American Chemical Society; Crystal Growth & Design; 13; 12; 10-2013; 5249-5260
1528-7483
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/cg401006d
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/cg401006d
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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