Engineering Photoluminescence of Lanthanide Doped Yttrium-MOF-76 for Volatile Organic Compound Sensing

Autores
Rosas Rivas, Oswaldo; Hamer, Mariana; Baldoni, Hector Armando; Boone, Maya; Van Deun, Rik; Gomez, Germán Ernesto
Año de publicación
2025
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A set of three-dimensional metal-organic frameworks, named MOF-76, belonging to the tetragonal P4322 space group, based on [Y(BTC)(H2O)](DMF)1.1 (1,3,5-benzenetricarboxylate) doped with Eu3+, Tb3+, and Eu3+/Tb3+ were obtained under solvothermal conditions and fully characterized by powder X-ray diffraction, thermal, and vibrational analyses. In addition, upon UV light excitation (280 nm), all the powdered samples exhibited fine 4f-4f transitions, of which the 5D0 → 7F2 (Eu3+) and 5D4 → 7F5 (Tb3+) were the most intense ones. All samples were photophysically analyzed by determining the luminescence lifetimes, and their emission colors were quantified by calculating their chromaticities and color purities. Moreover, the intrinsic quantum yield, radiative, and non-radiative constants were calculated and compared to establish a structure–property relationship. Specifically, the Eu/Tb co-doped sample was employed to monitor its hypersensitive emissions in the presence of small volatile organic compounds (VOCs), showing quenching or enhancement of emission in protic and non-protic solvents. Furthermore, DFT calculations were carried out to understand the energy transfer processes between the sensor and the respective analytes. These results are promising for the development of solid-state lighting devices and colorimetric chemical sensors for specific compounds.
Fil: Rosas Rivas, Oswaldo. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia; Argentina
Fil: Hamer, Mariana. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Baldoni, Hector Armando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto Multidisciplinario de Investigaciones Biológicas de San Luis. Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto Multidisciplinario de Investigaciones Biológicas de San Luis; Argentina
Fil: Boone, Maya. University of Ghent; Bélgica
Fil: Van Deun, Rik. University of Ghent; Bélgica
Fil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Materia
MOF
LANTHANIDES
LUMINISENSE
VOCs
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/265577
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/265577
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Engineering Photoluminescence of Lanthanide Doped Yttrium-MOF-76 for Volatile Organic Compound SensingRosas Rivas, OswaldoHamer, MarianaBaldoni, Hector ArmandoBoone, MayaVan Deun, RikGomez, Germán ErnestoMOFLANTHANIDESLUMINISENSEVOCshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A set of three-dimensional metal-organic frameworks, named MOF-76, belonging to the tetragonal P4322 space group, based on [Y(BTC)(H2O)](DMF)1.1 (1,3,5-benzenetricarboxylate) doped with Eu3+, Tb3+, and Eu3+/Tb3+ were obtained under solvothermal conditions and fully characterized by powder X-ray diffraction, thermal, and vibrational analyses. In addition, upon UV light excitation (280 nm), all the powdered samples exhibited fine 4f-4f transitions, of which the 5D0 → 7F2 (Eu3+) and 5D4 → 7F5 (Tb3+) were the most intense ones. All samples were photophysically analyzed by determining the luminescence lifetimes, and their emission colors were quantified by calculating their chromaticities and color purities. Moreover, the intrinsic quantum yield, radiative, and non-radiative constants were calculated and compared to establish a structure–property relationship. Specifically, the Eu/Tb co-doped sample was employed to monitor its hypersensitive emissions in the presence of small volatile organic compounds (VOCs), showing quenching or enhancement of emission in protic and non-protic solvents. Furthermore, DFT calculations were carried out to understand the energy transfer processes between the sensor and the respective analytes. These results are promising for the development of solid-state lighting devices and colorimetric chemical sensors for specific compounds.Fil: Rosas Rivas, Oswaldo. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia; ArgentinaFil: Hamer, Mariana. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Baldoni, Hector Armando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto Multidisciplinario de Investigaciones Biológicas de San Luis. Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto Multidisciplinario de Investigaciones Biológicas de San Luis; ArgentinaFil: Boone, Maya. University of Ghent; BélgicaFil: Van Deun, Rik. University of Ghent; BélgicaFil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaMDPI2025-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/265577Rosas Rivas, Oswaldo; Hamer, Mariana; Baldoni, Hector Armando; Boone, Maya; Van Deun, Rik; et al.; Engineering Photoluminescence of Lanthanide Doped Yttrium-MOF-76 for Volatile Organic Compound Sensing; MDPI; Polymers; 17; 9; 4-2025; 1-172073-4360CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4360/17/9/1135info:eu-repo/semantics/altIdentifier/doi/10.3390/polym17091135info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:34:00Zoai:ri.conicet.gov.ar:11336/265577instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:34:00.494CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Engineering Photoluminescence of Lanthanide Doped Yttrium-MOF-76 for Volatile Organic Compound Sensing
title Engineering Photoluminescence of Lanthanide Doped Yttrium-MOF-76 for Volatile Organic Compound Sensing
spellingShingle Engineering Photoluminescence of Lanthanide Doped Yttrium-MOF-76 for Volatile Organic Compound Sensing
Rosas Rivas, Oswaldo
MOF
LANTHANIDES
LUMINISENSE
VOCs
title_short Engineering Photoluminescence of Lanthanide Doped Yttrium-MOF-76 for Volatile Organic Compound Sensing
title_full Engineering Photoluminescence of Lanthanide Doped Yttrium-MOF-76 for Volatile Organic Compound Sensing
title_fullStr Engineering Photoluminescence of Lanthanide Doped Yttrium-MOF-76 for Volatile Organic Compound Sensing
title_full_unstemmed Engineering Photoluminescence of Lanthanide Doped Yttrium-MOF-76 for Volatile Organic Compound Sensing
title_sort Engineering Photoluminescence of Lanthanide Doped Yttrium-MOF-76 for Volatile Organic Compound Sensing
dc.creator.none.fl_str_mv Rosas Rivas, Oswaldo
Hamer, Mariana
Baldoni, Hector Armando
Boone, Maya
Van Deun, Rik
Gomez, Germán Ernesto
author Rosas Rivas, Oswaldo
author_facet Rosas Rivas, Oswaldo
Hamer, Mariana
Baldoni, Hector Armando
Boone, Maya
Van Deun, Rik
Gomez, Germán Ernesto
author_role author
author2 Hamer, Mariana
Baldoni, Hector Armando
Boone, Maya
Van Deun, Rik
Gomez, Germán Ernesto
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv MOF
LANTHANIDES
LUMINISENSE
VOCs
topic MOF
LANTHANIDES
LUMINISENSE
VOCs
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A set of three-dimensional metal-organic frameworks, named MOF-76, belonging to the tetragonal P4322 space group, based on [Y(BTC)(H2O)](DMF)1.1 (1,3,5-benzenetricarboxylate) doped with Eu3+, Tb3+, and Eu3+/Tb3+ were obtained under solvothermal conditions and fully characterized by powder X-ray diffraction, thermal, and vibrational analyses. In addition, upon UV light excitation (280 nm), all the powdered samples exhibited fine 4f-4f transitions, of which the 5D0 → 7F2 (Eu3+) and 5D4 → 7F5 (Tb3+) were the most intense ones. All samples were photophysically analyzed by determining the luminescence lifetimes, and their emission colors were quantified by calculating their chromaticities and color purities. Moreover, the intrinsic quantum yield, radiative, and non-radiative constants were calculated and compared to establish a structure–property relationship. Specifically, the Eu/Tb co-doped sample was employed to monitor its hypersensitive emissions in the presence of small volatile organic compounds (VOCs), showing quenching or enhancement of emission in protic and non-protic solvents. Furthermore, DFT calculations were carried out to understand the energy transfer processes between the sensor and the respective analytes. These results are promising for the development of solid-state lighting devices and colorimetric chemical sensors for specific compounds.
Fil: Rosas Rivas, Oswaldo. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia; Argentina
Fil: Hamer, Mariana. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Baldoni, Hector Armando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto Multidisciplinario de Investigaciones Biológicas de San Luis. Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto Multidisciplinario de Investigaciones Biológicas de San Luis; Argentina
Fil: Boone, Maya. University of Ghent; Bélgica
Fil: Van Deun, Rik. University of Ghent; Bélgica
Fil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
description A set of three-dimensional metal-organic frameworks, named MOF-76, belonging to the tetragonal P4322 space group, based on [Y(BTC)(H2O)](DMF)1.1 (1,3,5-benzenetricarboxylate) doped with Eu3+, Tb3+, and Eu3+/Tb3+ were obtained under solvothermal conditions and fully characterized by powder X-ray diffraction, thermal, and vibrational analyses. In addition, upon UV light excitation (280 nm), all the powdered samples exhibited fine 4f-4f transitions, of which the 5D0 → 7F2 (Eu3+) and 5D4 → 7F5 (Tb3+) were the most intense ones. All samples were photophysically analyzed by determining the luminescence lifetimes, and their emission colors were quantified by calculating their chromaticities and color purities. Moreover, the intrinsic quantum yield, radiative, and non-radiative constants were calculated and compared to establish a structure–property relationship. Specifically, the Eu/Tb co-doped sample was employed to monitor its hypersensitive emissions in the presence of small volatile organic compounds (VOCs), showing quenching or enhancement of emission in protic and non-protic solvents. Furthermore, DFT calculations were carried out to understand the energy transfer processes between the sensor and the respective analytes. These results are promising for the development of solid-state lighting devices and colorimetric chemical sensors for specific compounds.
publishDate 2025
dc.date.none.fl_str_mv 2025-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/265577
Rosas Rivas, Oswaldo; Hamer, Mariana; Baldoni, Hector Armando; Boone, Maya; Van Deun, Rik; et al.; Engineering Photoluminescence of Lanthanide Doped Yttrium-MOF-76 for Volatile Organic Compound Sensing; MDPI; Polymers; 17; 9; 4-2025; 1-17
2073-4360
CONICET Digital
CONICET
url http://hdl.handle.net/11336/265577
identifier_str_mv Rosas Rivas, Oswaldo; Hamer, Mariana; Baldoni, Hector Armando; Boone, Maya; Van Deun, Rik; et al.; Engineering Photoluminescence of Lanthanide Doped Yttrium-MOF-76 for Volatile Organic Compound Sensing; MDPI; Polymers; 17; 9; 4-2025; 1-17
2073-4360
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4360/17/9/1135
info:eu-repo/semantics/altIdentifier/doi/10.3390/polym17091135
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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