Tuning the Structure, dimensionality and Luminescent properties of Lanthanide Metal-Organic Frameworks under Ancillary Ligand Influence

Autores
D'Vries, Richard Fernando; Gomez, Germán Ernesto; Hodak, Jose Hector; Soler Illia, Galo Juan de Avila Arturo; Ellena, Javier
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This manuscript addresses the synthesis, structural characterization and optical properties of a 1D coordination polymer (CPs) and 2D and 3D Metal–Organic Frameworks (MOFs) obtained from lanthanide metals, 3-hydroxinaftalene-2,7-disulfonic acid (3-OHNDS) and two different phenanthroline derivates as ancillary ligands. The first is a family of 2D compounds with formula [Ln(3-OHNDS)(H2O)2], where Ln = La(1), Pr(2), Nd(3) and Sm(4). The addition of 1,10-phenanthroline (phen) in the reaction produces 1D compounds with general formula [Ln(3-OHNDS)(phen)(H2O)]·3H2O, where Ln = La(5), Pr(6), Nd(7) and Sm(8). Finally, the synthesis with 3,4,7,8-tetramethyl-1,10-phenanthroline (3,4,7,8-TMPhen) as an ancillary ligand results in the formation of the 3D [La(3-OHNDS)(3,4,7,8-TMphen)(H2O)] (9) compound. The photoluminescence (PL) properties of 1D and 2D compounds were fully investigated in comparison with the 3-OHNDS ligand. One of the most important results was the obtaining of a white-light single-emitter without adding dopant atoms in the structure. With all these results in mind it was possible to establish structure–property relationships.
Fil: D'Vries, Richard Fernando. Universidade de Sao Paulo; Brasil
Fil: Gomez, Germán Ernesto. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Hodak, Jose Hector. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Soler Illia, Galo Juan de Avila Arturo. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Ellena, Javier. Universidade de Sao Paulo; Brasil
Materia
LANTHANIDES
MOF
LUMINESCENCE
COORDINATION POLYMERS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/42518
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/42518
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Tuning the Structure, dimensionality and Luminescent properties of Lanthanide Metal-Organic Frameworks under Ancillary Ligand InfluenceD'Vries, Richard FernandoGomez, Germán ErnestoHodak, Jose HectorSoler Illia, Galo Juan de Avila ArturoEllena, JavierLANTHANIDESMOFLUMINESCENCECOORDINATION POLYMERShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1This manuscript addresses the synthesis, structural characterization and optical properties of a 1D coordination polymer (CPs) and 2D and 3D Metal–Organic Frameworks (MOFs) obtained from lanthanide metals, 3-hydroxinaftalene-2,7-disulfonic acid (3-OHNDS) and two different phenanthroline derivates as ancillary ligands. The first is a family of 2D compounds with formula [Ln(3-OHNDS)(H2O)2], where Ln = La(1), Pr(2), Nd(3) and Sm(4). The addition of 1,10-phenanthroline (phen) in the reaction produces 1D compounds with general formula [Ln(3-OHNDS)(phen)(H2O)]·3H2O, where Ln = La(5), Pr(6), Nd(7) and Sm(8). Finally, the synthesis with 3,4,7,8-tetramethyl-1,10-phenanthroline (3,4,7,8-TMPhen) as an ancillary ligand results in the formation of the 3D [La(3-OHNDS)(3,4,7,8-TMphen)(H2O)] (9) compound. The photoluminescence (PL) properties of 1D and 2D compounds were fully investigated in comparison with the 3-OHNDS ligand. One of the most important results was the obtaining of a white-light single-emitter without adding dopant atoms in the structure. With all these results in mind it was possible to establish structure–property relationships.Fil: D'Vries, Richard Fernando. Universidade de Sao Paulo; BrasilFil: Gomez, Germán Ernesto. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Hodak, Jose Hector. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Soler Illia, Galo Juan de Avila Arturo. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Ellena, Javier. Universidade de Sao Paulo; BrasilRoyal Society of Chemistry2016-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/42518D'Vries, Richard Fernando ; Gomez, Germán Ernesto; Hodak, Jose Hector; Soler Illia, Galo Juan de Avila Arturo; Ellena, Javier; Tuning the Structure, dimensionality and Luminescent properties of Lanthanide Metal-Organic Frameworks under Ancillary Ligand Influence; Royal Society of Chemistry; Dalton Transactions; 45; 2; 1-2016; 646-6561477-9226CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1039/C5DT04033Ginfo:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/content/articlelanding/2016/dt/c5dt04033ginfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:07:11Zoai:ri.conicet.gov.ar:11336/42518instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:07:11.806CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Tuning the Structure, dimensionality and Luminescent properties of Lanthanide Metal-Organic Frameworks under Ancillary Ligand Influence
title Tuning the Structure, dimensionality and Luminescent properties of Lanthanide Metal-Organic Frameworks under Ancillary Ligand Influence
spellingShingle Tuning the Structure, dimensionality and Luminescent properties of Lanthanide Metal-Organic Frameworks under Ancillary Ligand Influence
D'Vries, Richard Fernando
LANTHANIDES
MOF
LUMINESCENCE
COORDINATION POLYMERS
title_short Tuning the Structure, dimensionality and Luminescent properties of Lanthanide Metal-Organic Frameworks under Ancillary Ligand Influence
title_full Tuning the Structure, dimensionality and Luminescent properties of Lanthanide Metal-Organic Frameworks under Ancillary Ligand Influence
title_fullStr Tuning the Structure, dimensionality and Luminescent properties of Lanthanide Metal-Organic Frameworks under Ancillary Ligand Influence
title_full_unstemmed Tuning the Structure, dimensionality and Luminescent properties of Lanthanide Metal-Organic Frameworks under Ancillary Ligand Influence
title_sort Tuning the Structure, dimensionality and Luminescent properties of Lanthanide Metal-Organic Frameworks under Ancillary Ligand Influence
dc.creator.none.fl_str_mv D'Vries, Richard Fernando
Gomez, Germán Ernesto
Hodak, Jose Hector
Soler Illia, Galo Juan de Avila Arturo
Ellena, Javier
author D'Vries, Richard Fernando
author_facet D'Vries, Richard Fernando
Gomez, Germán Ernesto
Hodak, Jose Hector
Soler Illia, Galo Juan de Avila Arturo
Ellena, Javier
author_role author
author2 Gomez, Germán Ernesto
Hodak, Jose Hector
Soler Illia, Galo Juan de Avila Arturo
Ellena, Javier
author2_role author
author
author
author
dc.subject.none.fl_str_mv LANTHANIDES
MOF
LUMINESCENCE
COORDINATION POLYMERS
topic LANTHANIDES
MOF
LUMINESCENCE
COORDINATION POLYMERS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv This manuscript addresses the synthesis, structural characterization and optical properties of a 1D coordination polymer (CPs) and 2D and 3D Metal–Organic Frameworks (MOFs) obtained from lanthanide metals, 3-hydroxinaftalene-2,7-disulfonic acid (3-OHNDS) and two different phenanthroline derivates as ancillary ligands. The first is a family of 2D compounds with formula [Ln(3-OHNDS)(H2O)2], where Ln = La(1), Pr(2), Nd(3) and Sm(4). The addition of 1,10-phenanthroline (phen) in the reaction produces 1D compounds with general formula [Ln(3-OHNDS)(phen)(H2O)]·3H2O, where Ln = La(5), Pr(6), Nd(7) and Sm(8). Finally, the synthesis with 3,4,7,8-tetramethyl-1,10-phenanthroline (3,4,7,8-TMPhen) as an ancillary ligand results in the formation of the 3D [La(3-OHNDS)(3,4,7,8-TMphen)(H2O)] (9) compound. The photoluminescence (PL) properties of 1D and 2D compounds were fully investigated in comparison with the 3-OHNDS ligand. One of the most important results was the obtaining of a white-light single-emitter without adding dopant atoms in the structure. With all these results in mind it was possible to establish structure–property relationships.
Fil: D'Vries, Richard Fernando. Universidade de Sao Paulo; Brasil
Fil: Gomez, Germán Ernesto. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Hodak, Jose Hector. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Soler Illia, Galo Juan de Avila Arturo. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Ellena, Javier. Universidade de Sao Paulo; Brasil
description This manuscript addresses the synthesis, structural characterization and optical properties of a 1D coordination polymer (CPs) and 2D and 3D Metal–Organic Frameworks (MOFs) obtained from lanthanide metals, 3-hydroxinaftalene-2,7-disulfonic acid (3-OHNDS) and two different phenanthroline derivates as ancillary ligands. The first is a family of 2D compounds with formula [Ln(3-OHNDS)(H2O)2], where Ln = La(1), Pr(2), Nd(3) and Sm(4). The addition of 1,10-phenanthroline (phen) in the reaction produces 1D compounds with general formula [Ln(3-OHNDS)(phen)(H2O)]·3H2O, where Ln = La(5), Pr(6), Nd(7) and Sm(8). Finally, the synthesis with 3,4,7,8-tetramethyl-1,10-phenanthroline (3,4,7,8-TMPhen) as an ancillary ligand results in the formation of the 3D [La(3-OHNDS)(3,4,7,8-TMphen)(H2O)] (9) compound. The photoluminescence (PL) properties of 1D and 2D compounds were fully investigated in comparison with the 3-OHNDS ligand. One of the most important results was the obtaining of a white-light single-emitter without adding dopant atoms in the structure. With all these results in mind it was possible to establish structure–property relationships.
publishDate 2016
dc.date.none.fl_str_mv 2016-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/42518
D'Vries, Richard Fernando ; Gomez, Germán Ernesto; Hodak, Jose Hector; Soler Illia, Galo Juan de Avila Arturo; Ellena, Javier; Tuning the Structure, dimensionality and Luminescent properties of Lanthanide Metal-Organic Frameworks under Ancillary Ligand Influence; Royal Society of Chemistry; Dalton Transactions; 45; 2; 1-2016; 646-656
1477-9226
CONICET Digital
CONICET
url http://hdl.handle.net/11336/42518
identifier_str_mv D'Vries, Richard Fernando ; Gomez, Germán Ernesto; Hodak, Jose Hector; Soler Illia, Galo Juan de Avila Arturo; Ellena, Javier; Tuning the Structure, dimensionality and Luminescent properties of Lanthanide Metal-Organic Frameworks under Ancillary Ligand Influence; Royal Society of Chemistry; Dalton Transactions; 45; 2; 1-2016; 646-656
1477-9226
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1039/C5DT04033G
info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/content/articlelanding/2016/dt/c5dt04033g
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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