Reversible breaking and forming of Metal-Ligand coordination bonds: Temperature-Triggered Single-Crystal to Single-Crystal transformation in a Metal-Organic framework
- Autores
- Bernini, Maria Celeste; Gandara, Felipe; Iglesias, Marta; Snejko, Natalia; Gutierrez Puebla, Enrique; Brusau, Elena Virginia; Narda, Griselda Edith; Monge, M. Angeles
- Año de publicación
- 2009
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- [Yb(C4H4O4)15] undergoes a temperature-triggered single-crystal to single-crystal transformation. Thermal X-ray single-crystal studies showed a reversibly orchestrated rearrangement of the atoms generated by the breaking/formation of coordination bonds, in which the stoichiometry of the compound remains unchanged. The transformation occurs on heating the crystal at «130 °C. This uncommon behavior was also studied by thermal methods, FTIR spectroscopy, and thermodiffrac-tometry. Both polymorphs, a (room-temperature form) and b (high-temperature form), are proven to be active heterogeneous catalysts; the higher catalytic activity of b is owed to a decrease in the Yb coordination number. A mechanism based on spectroscopic evidence and involving formation of the active species Yb-O-OH is proposed for the sulfide oxidation.
Fil: Bernini, Maria Celeste. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Área Química General e Inorgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Gandara, Felipe. Instituto de Ciencia de Materiales de Madrid; España
Fil: Iglesias, Marta. Instituto de Ciencia de Materiales de Madrid; España
Fil: Snejko, Natalia. Instituto de Ciencia de Materiales de Madrid; España
Fil: Gutierrez Puebla, Enrique. Instituto de Ciencia de Materiales de Madrid; España
Fil: Brusau, Elena Virginia. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Área Química General e Inorgánica; Argentina
Fil: Narda, Griselda Edith. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Área Química General e Inorgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Monge, M. Angeles. Instituto de Ciencia de Materiales de Madrid; España - Materia
-
HETEROGENEOUS CATALYSIS
METAL-ORGANIC FRAMEWORKS
POLYMORPHISM
STRUCTURE ELUCIDATION
YTTERBIUM - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/148536
Ver los metadatos del registro completo
id |
CONICETDig_88291dee481af36796dd3a47f0c62fef |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/148536 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
Reversible breaking and forming of Metal-Ligand coordination bonds: Temperature-Triggered Single-Crystal to Single-Crystal transformation in a Metal-Organic frameworkBernini, Maria CelesteGandara, FelipeIglesias, MartaSnejko, NataliaGutierrez Puebla, EnriqueBrusau, Elena VirginiaNarda, Griselda EdithMonge, M. AngelesHETEROGENEOUS CATALYSISMETAL-ORGANIC FRAMEWORKSPOLYMORPHISMSTRUCTURE ELUCIDATIONYTTERBIUMhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1[Yb(C4H4O4)15] undergoes a temperature-triggered single-crystal to single-crystal transformation. Thermal X-ray single-crystal studies showed a reversibly orchestrated rearrangement of the atoms generated by the breaking/formation of coordination bonds, in which the stoichiometry of the compound remains unchanged. The transformation occurs on heating the crystal at «130 °C. This uncommon behavior was also studied by thermal methods, FTIR spectroscopy, and thermodiffrac-tometry. Both polymorphs, a (room-temperature form) and b (high-temperature form), are proven to be active heterogeneous catalysts; the higher catalytic activity of b is owed to a decrease in the Yb coordination number. A mechanism based on spectroscopic evidence and involving formation of the active species Yb-O-OH is proposed for the sulfide oxidation.Fil: Bernini, Maria Celeste. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Área Química General e Inorgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Gandara, Felipe. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Iglesias, Marta. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Snejko, Natalia. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Gutierrez Puebla, Enrique. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Brusau, Elena Virginia. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Área Química General e Inorgánica; ArgentinaFil: Narda, Griselda Edith. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Área Química General e Inorgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Monge, M. Angeles. Instituto de Ciencia de Materiales de Madrid; EspañaWiley VCH Verlag2009-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/148536Bernini, Maria Celeste; Gandara, Felipe; Iglesias, Marta; Snejko, Natalia; Gutierrez Puebla, Enrique; et al.; Reversible breaking and forming of Metal-Ligand coordination bonds: Temperature-Triggered Single-Crystal to Single-Crystal transformation in a Metal-Organic framework; Wiley VCH Verlag; Chemistry- A European Journal; 15; 19; 5-2009; 4896-49050947-6539CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/chem.200802385info:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.200802385info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:47:05Zoai:ri.conicet.gov.ar:11336/148536instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:47:05.318CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Reversible breaking and forming of Metal-Ligand coordination bonds: Temperature-Triggered Single-Crystal to Single-Crystal transformation in a Metal-Organic framework |
title |
Reversible breaking and forming of Metal-Ligand coordination bonds: Temperature-Triggered Single-Crystal to Single-Crystal transformation in a Metal-Organic framework |
spellingShingle |
Reversible breaking and forming of Metal-Ligand coordination bonds: Temperature-Triggered Single-Crystal to Single-Crystal transformation in a Metal-Organic framework Bernini, Maria Celeste HETEROGENEOUS CATALYSIS METAL-ORGANIC FRAMEWORKS POLYMORPHISM STRUCTURE ELUCIDATION YTTERBIUM |
title_short |
Reversible breaking and forming of Metal-Ligand coordination bonds: Temperature-Triggered Single-Crystal to Single-Crystal transformation in a Metal-Organic framework |
title_full |
Reversible breaking and forming of Metal-Ligand coordination bonds: Temperature-Triggered Single-Crystal to Single-Crystal transformation in a Metal-Organic framework |
title_fullStr |
Reversible breaking and forming of Metal-Ligand coordination bonds: Temperature-Triggered Single-Crystal to Single-Crystal transformation in a Metal-Organic framework |
title_full_unstemmed |
Reversible breaking and forming of Metal-Ligand coordination bonds: Temperature-Triggered Single-Crystal to Single-Crystal transformation in a Metal-Organic framework |
title_sort |
Reversible breaking and forming of Metal-Ligand coordination bonds: Temperature-Triggered Single-Crystal to Single-Crystal transformation in a Metal-Organic framework |
dc.creator.none.fl_str_mv |
Bernini, Maria Celeste Gandara, Felipe Iglesias, Marta Snejko, Natalia Gutierrez Puebla, Enrique Brusau, Elena Virginia Narda, Griselda Edith Monge, M. Angeles |
author |
Bernini, Maria Celeste |
author_facet |
Bernini, Maria Celeste Gandara, Felipe Iglesias, Marta Snejko, Natalia Gutierrez Puebla, Enrique Brusau, Elena Virginia Narda, Griselda Edith Monge, M. Angeles |
author_role |
author |
author2 |
Gandara, Felipe Iglesias, Marta Snejko, Natalia Gutierrez Puebla, Enrique Brusau, Elena Virginia Narda, Griselda Edith Monge, M. Angeles |
author2_role |
author author author author author author author |
dc.subject.none.fl_str_mv |
HETEROGENEOUS CATALYSIS METAL-ORGANIC FRAMEWORKS POLYMORPHISM STRUCTURE ELUCIDATION YTTERBIUM |
topic |
HETEROGENEOUS CATALYSIS METAL-ORGANIC FRAMEWORKS POLYMORPHISM STRUCTURE ELUCIDATION YTTERBIUM |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
[Yb(C4H4O4)15] undergoes a temperature-triggered single-crystal to single-crystal transformation. Thermal X-ray single-crystal studies showed a reversibly orchestrated rearrangement of the atoms generated by the breaking/formation of coordination bonds, in which the stoichiometry of the compound remains unchanged. The transformation occurs on heating the crystal at «130 °C. This uncommon behavior was also studied by thermal methods, FTIR spectroscopy, and thermodiffrac-tometry. Both polymorphs, a (room-temperature form) and b (high-temperature form), are proven to be active heterogeneous catalysts; the higher catalytic activity of b is owed to a decrease in the Yb coordination number. A mechanism based on spectroscopic evidence and involving formation of the active species Yb-O-OH is proposed for the sulfide oxidation. Fil: Bernini, Maria Celeste. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Área Química General e Inorgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina Fil: Gandara, Felipe. Instituto de Ciencia de Materiales de Madrid; España Fil: Iglesias, Marta. Instituto de Ciencia de Materiales de Madrid; España Fil: Snejko, Natalia. Instituto de Ciencia de Materiales de Madrid; España Fil: Gutierrez Puebla, Enrique. Instituto de Ciencia de Materiales de Madrid; España Fil: Brusau, Elena Virginia. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Área Química General e Inorgánica; Argentina Fil: Narda, Griselda Edith. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Área Química General e Inorgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina Fil: Monge, M. Angeles. Instituto de Ciencia de Materiales de Madrid; España |
description |
[Yb(C4H4O4)15] undergoes a temperature-triggered single-crystal to single-crystal transformation. Thermal X-ray single-crystal studies showed a reversibly orchestrated rearrangement of the atoms generated by the breaking/formation of coordination bonds, in which the stoichiometry of the compound remains unchanged. The transformation occurs on heating the crystal at «130 °C. This uncommon behavior was also studied by thermal methods, FTIR spectroscopy, and thermodiffrac-tometry. Both polymorphs, a (room-temperature form) and b (high-temperature form), are proven to be active heterogeneous catalysts; the higher catalytic activity of b is owed to a decrease in the Yb coordination number. A mechanism based on spectroscopic evidence and involving formation of the active species Yb-O-OH is proposed for the sulfide oxidation. |
publishDate |
2009 |
dc.date.none.fl_str_mv |
2009-05 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/148536 Bernini, Maria Celeste; Gandara, Felipe; Iglesias, Marta; Snejko, Natalia; Gutierrez Puebla, Enrique; et al.; Reversible breaking and forming of Metal-Ligand coordination bonds: Temperature-Triggered Single-Crystal to Single-Crystal transformation in a Metal-Organic framework; Wiley VCH Verlag; Chemistry- A European Journal; 15; 19; 5-2009; 4896-4905 0947-6539 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/148536 |
identifier_str_mv |
Bernini, Maria Celeste; Gandara, Felipe; Iglesias, Marta; Snejko, Natalia; Gutierrez Puebla, Enrique; et al.; Reversible breaking and forming of Metal-Ligand coordination bonds: Temperature-Triggered Single-Crystal to Single-Crystal transformation in a Metal-Organic framework; Wiley VCH Verlag; Chemistry- A European Journal; 15; 19; 5-2009; 4896-4905 0947-6539 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1002/chem.200802385 info:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.200802385 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Wiley VCH Verlag |
publisher.none.fl_str_mv |
Wiley VCH Verlag |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844613467380645888 |
score |
13.070432 |