SR μXRF and XRD study of the spatial distribution and mineralogical composition of Pb and Sb species in weathering crust of corroded bullets of hunting fields

Autores
Mera, Maria Fernanda; Rubio, Marcelo; Perez Carlos; Galván Josa, Víctor Martín; Germanier, Alejandro
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The spatial distribution of Pb and Sb in core and crust material and the mineralogical composition of these elements in weathering crust of corroded bullets found in hunting fields were investigated. Lead, antimony and others metals from pellets alloy are disperse in the soil of the shooting fields. As long as the corroding bullets are present in soil, secondary Pb and Sb phases appear in the weathering crusts being an important source of bioavailable Pb and Sb. Powder X-ray diffraction (XRD) patterns of crust material from weathered bullets showed encrustation of relevant Pb and Sb phases like: hydrocerussite (Pb3(CO3)2(OH)2), litharge (PbO-tetragonal), hydroxypyromorphite (Pb5(PO4)3(OH)), gebhardite (Pb8OCl6(As2O5)2, Sb metallic, stibnite (Sb2S3), tripuhyite (FeSbO4) and potassium sodium antimony oxide (KO13Sb5) among others minor compounds. The chemical elemental distribution of corroded bullets was determined by synchrotron radiation-induced micro X-ray fluorescence analysis (SR-μXRF). A positive correlation between Sb and Fe was detected in crust material measured in the outer rim of the weathered bullets due to Sb adsorption to Fe oxyhydroxides of soil. It was also observed a spatial correlation between Sb and Cu and between Sb and Zn in crust. The influence of phosphorus applied as (P)-based fertilizers of soils was observed in the hydroxypyromorphite phase detected in samples collected near agricultural lands.
Fil: Mera, Maria Fernanda. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina
Fil: Rubio, Marcelo. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Perez Carlos. Laboratorio Nacional de Luz Sincrotron; Brasil
Fil: Galván Josa, Víctor Martín. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Germanier, Alejandro. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina
Materia
Micro X-Ray Fluorescence
Synchrotron
X-Ray Diffraction
Lead
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/34971
Acceder
id CONICETDig_96b02175081de0a9325ee96115f0b2ed
oai_identifier_str oai:ri.conicet.gov.ar:11336/34971
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling SR μXRF and XRD study of the spatial distribution and mineralogical composition of Pb and Sb species in weathering crust of corroded bullets of hunting fieldsMera, Maria FernandaRubio, MarceloPerez CarlosGalván Josa, Víctor MartínGermanier, AlejandroMicro X-Ray FluorescenceSynchrotronX-Ray DiffractionLeadhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1The spatial distribution of Pb and Sb in core and crust material and the mineralogical composition of these elements in weathering crust of corroded bullets found in hunting fields were investigated. Lead, antimony and others metals from pellets alloy are disperse in the soil of the shooting fields. As long as the corroding bullets are present in soil, secondary Pb and Sb phases appear in the weathering crusts being an important source of bioavailable Pb and Sb. Powder X-ray diffraction (XRD) patterns of crust material from weathered bullets showed encrustation of relevant Pb and Sb phases like: hydrocerussite (Pb3(CO3)2(OH)2), litharge (PbO-tetragonal), hydroxypyromorphite (Pb5(PO4)3(OH)), gebhardite (Pb8OCl6(As2O5)2, Sb metallic, stibnite (Sb2S3), tripuhyite (FeSbO4) and potassium sodium antimony oxide (KO13Sb5) among others minor compounds. The chemical elemental distribution of corroded bullets was determined by synchrotron radiation-induced micro X-ray fluorescence analysis (SR-μXRF). A positive correlation between Sb and Fe was detected in crust material measured in the outer rim of the weathered bullets due to Sb adsorption to Fe oxyhydroxides of soil. It was also observed a spatial correlation between Sb and Cu and between Sb and Zn in crust. The influence of phosphorus applied as (P)-based fertilizers of soils was observed in the hydroxypyromorphite phase detected in samples collected near agricultural lands.Fil: Mera, Maria Fernanda. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; ArgentinaFil: Rubio, Marcelo. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Perez Carlos. Laboratorio Nacional de Luz Sincrotron; BrasilFil: Galván Josa, Víctor Martín. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Germanier, Alejandro. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; ArgentinaElsevier Science2014-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/34971Mera, Maria Fernanda; Rubio, Marcelo; Perez Carlos; Galván Josa, Víctor Martín; Germanier, Alejandro; SR μXRF and XRD study of the spatial distribution and mineralogical composition of Pb and Sb species in weathering crust of corroded bullets of hunting fields; Elsevier Science; Microchemical Journal; 119; 10-2014; 114-1220026-265XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2014.11.010info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0026265X14002197info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:40:37Zoai:ri.conicet.gov.ar:11336/34971instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:40:37.843CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv SR μXRF and XRD study of the spatial distribution and mineralogical composition of Pb and Sb species in weathering crust of corroded bullets of hunting fields
title SR μXRF and XRD study of the spatial distribution and mineralogical composition of Pb and Sb species in weathering crust of corroded bullets of hunting fields
spellingShingle SR μXRF and XRD study of the spatial distribution and mineralogical composition of Pb and Sb species in weathering crust of corroded bullets of hunting fields
Mera, Maria Fernanda
Micro X-Ray Fluorescence
Synchrotron
X-Ray Diffraction
Lead
title_short SR μXRF and XRD study of the spatial distribution and mineralogical composition of Pb and Sb species in weathering crust of corroded bullets of hunting fields
title_full SR μXRF and XRD study of the spatial distribution and mineralogical composition of Pb and Sb species in weathering crust of corroded bullets of hunting fields
title_fullStr SR μXRF and XRD study of the spatial distribution and mineralogical composition of Pb and Sb species in weathering crust of corroded bullets of hunting fields
title_full_unstemmed SR μXRF and XRD study of the spatial distribution and mineralogical composition of Pb and Sb species in weathering crust of corroded bullets of hunting fields
title_sort SR μXRF and XRD study of the spatial distribution and mineralogical composition of Pb and Sb species in weathering crust of corroded bullets of hunting fields
dc.creator.none.fl_str_mv Mera, Maria Fernanda
Rubio, Marcelo
Perez Carlos
Galván Josa, Víctor Martín
Germanier, Alejandro
author Mera, Maria Fernanda
author_facet Mera, Maria Fernanda
Rubio, Marcelo
Perez Carlos
Galván Josa, Víctor Martín
Germanier, Alejandro
author_role author
author2 Rubio, Marcelo
Perez Carlos
Galván Josa, Víctor Martín
Germanier, Alejandro
author2_role author
author
author
author
dc.subject.none.fl_str_mv Micro X-Ray Fluorescence
Synchrotron
X-Ray Diffraction
Lead
topic Micro X-Ray Fluorescence
Synchrotron
X-Ray Diffraction
Lead
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The spatial distribution of Pb and Sb in core and crust material and the mineralogical composition of these elements in weathering crust of corroded bullets found in hunting fields were investigated. Lead, antimony and others metals from pellets alloy are disperse in the soil of the shooting fields. As long as the corroding bullets are present in soil, secondary Pb and Sb phases appear in the weathering crusts being an important source of bioavailable Pb and Sb. Powder X-ray diffraction (XRD) patterns of crust material from weathered bullets showed encrustation of relevant Pb and Sb phases like: hydrocerussite (Pb3(CO3)2(OH)2), litharge (PbO-tetragonal), hydroxypyromorphite (Pb5(PO4)3(OH)), gebhardite (Pb8OCl6(As2O5)2, Sb metallic, stibnite (Sb2S3), tripuhyite (FeSbO4) and potassium sodium antimony oxide (KO13Sb5) among others minor compounds. The chemical elemental distribution of corroded bullets was determined by synchrotron radiation-induced micro X-ray fluorescence analysis (SR-μXRF). A positive correlation between Sb and Fe was detected in crust material measured in the outer rim of the weathered bullets due to Sb adsorption to Fe oxyhydroxides of soil. It was also observed a spatial correlation between Sb and Cu and between Sb and Zn in crust. The influence of phosphorus applied as (P)-based fertilizers of soils was observed in the hydroxypyromorphite phase detected in samples collected near agricultural lands.
Fil: Mera, Maria Fernanda. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina
Fil: Rubio, Marcelo. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Perez Carlos. Laboratorio Nacional de Luz Sincrotron; Brasil
Fil: Galván Josa, Víctor Martín. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Germanier, Alejandro. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina
description The spatial distribution of Pb and Sb in core and crust material and the mineralogical composition of these elements in weathering crust of corroded bullets found in hunting fields were investigated. Lead, antimony and others metals from pellets alloy are disperse in the soil of the shooting fields. As long as the corroding bullets are present in soil, secondary Pb and Sb phases appear in the weathering crusts being an important source of bioavailable Pb and Sb. Powder X-ray diffraction (XRD) patterns of crust material from weathered bullets showed encrustation of relevant Pb and Sb phases like: hydrocerussite (Pb3(CO3)2(OH)2), litharge (PbO-tetragonal), hydroxypyromorphite (Pb5(PO4)3(OH)), gebhardite (Pb8OCl6(As2O5)2, Sb metallic, stibnite (Sb2S3), tripuhyite (FeSbO4) and potassium sodium antimony oxide (KO13Sb5) among others minor compounds. The chemical elemental distribution of corroded bullets was determined by synchrotron radiation-induced micro X-ray fluorescence analysis (SR-μXRF). A positive correlation between Sb and Fe was detected in crust material measured in the outer rim of the weathered bullets due to Sb adsorption to Fe oxyhydroxides of soil. It was also observed a spatial correlation between Sb and Cu and between Sb and Zn in crust. The influence of phosphorus applied as (P)-based fertilizers of soils was observed in the hydroxypyromorphite phase detected in samples collected near agricultural lands.
publishDate 2014
dc.date.none.fl_str_mv 2014-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/34971
Mera, Maria Fernanda; Rubio, Marcelo; Perez Carlos; Galván Josa, Víctor Martín; Germanier, Alejandro; SR μXRF and XRD study of the spatial distribution and mineralogical composition of Pb and Sb species in weathering crust of corroded bullets of hunting fields; Elsevier Science; Microchemical Journal; 119; 10-2014; 114-122
0026-265X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/34971
identifier_str_mv Mera, Maria Fernanda; Rubio, Marcelo; Perez Carlos; Galván Josa, Víctor Martín; Germanier, Alejandro; SR μXRF and XRD study of the spatial distribution and mineralogical composition of Pb and Sb species in weathering crust of corroded bullets of hunting fields; Elsevier Science; Microchemical Journal; 119; 10-2014; 114-122
0026-265X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2014.11.010
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0026265X14002197
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613285180080128
score 13.070432

Publicaciones similares