Study of lead levels in soils by weathering of metallic Pb bullets used in dove hunting in Córdoba, Argentina

Autores
Rubio, Marcelo; Germanier, A; Mera, Maria Fernanda; Faudone, Sonia Nerina; Sbarato, Ruben Darío; Campos, Jose Manuel; Zampar, Vanesa Paola; Bonzi, Edgardo; Perez, Carlos
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A study of level of Pb in soils of the center-north of the Province of Córdoba, a worldwide recognized tourist region for dove hunting, was performed in this work. The native forest of the region has a great population of doves associated with the grainproductive fields of the surrounding. Contamination of soils due to hunting activities is regulated by national and local norms. The Córdoba Environmental Secretary by resolution no. 1115/2011 approved a new regulation that categorizes this activity as generator of Y31 (Pb) industrial waste. Lead from pellets alloy is deposited on the soil of the shooting fields. Samples were taken at depth of 50mm from 315 pits referenced by GPS in accordance with local environmental authorities as well as the hunting outfitters companies. Sampling sites are distributed between parallels 31 °S (S31) up to 30 °S (S30) and between meridians W64 up to W63. Soils samples were analyzed by X-ray fluorescence spectroscopy while Pb bullets were analyzed by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The average concentration obtained for Pb in dry soil sieved (200 mesh) was 80 ppm. Powder XRD patterns of crust material removed from the corroded surface of weathered bullets were obtained. Three Pb mineral compounds were identified by XRD analysis and also studied by optical microscopy and SEM.
Fil: Rubio, Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
Fil: Germanier, A. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina
Fil: Mera, Maria Fernanda. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina
Fil: Faudone, Sonia Nerina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina
Fil: Sbarato, Ruben Darío. Universidad Tecnológica Nacional; Argentina
Fil: Campos, Jose Manuel. Universidad Tecnológica Nacional; Argentina
Fil: Zampar, Vanesa Paola. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina
Fil: Bonzi, Edgardo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
Fil: Perez, Carlos. Laboratorio Nacional de Luz Sincrotron. Campinas; Brasil
Materia
X-Ray Fluorescence
Lead
Hunting
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/33941
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/33941
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Study of lead levels in soils by weathering of metallic Pb bullets used in dove hunting in Córdoba, ArgentinaRubio, MarceloGermanier, AMera, Maria FernandaFaudone, Sonia NerinaSbarato, Ruben DaríoCampos, Jose ManuelZampar, Vanesa PaolaBonzi, EdgardoPerez, CarlosX-Ray FluorescenceLeadHuntinghttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1A study of level of Pb in soils of the center-north of the Province of Córdoba, a worldwide recognized tourist region for dove hunting, was performed in this work. The native forest of the region has a great population of doves associated with the grainproductive fields of the surrounding. Contamination of soils due to hunting activities is regulated by national and local norms. The Córdoba Environmental Secretary by resolution no. 1115/2011 approved a new regulation that categorizes this activity as generator of Y31 (Pb) industrial waste. Lead from pellets alloy is deposited on the soil of the shooting fields. Samples were taken at depth of 50mm from 315 pits referenced by GPS in accordance with local environmental authorities as well as the hunting outfitters companies. Sampling sites are distributed between parallels 31 °S (S31) up to 30 °S (S30) and between meridians W64 up to W63. Soils samples were analyzed by X-ray fluorescence spectroscopy while Pb bullets were analyzed by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The average concentration obtained for Pb in dry soil sieved (200 mesh) was 80 ppm. Powder XRD patterns of crust material removed from the corroded surface of weathered bullets were obtained. Three Pb mineral compounds were identified by XRD analysis and also studied by optical microscopy and SEM.Fil: Rubio, Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; ArgentinaFil: Germanier, A. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; ArgentinaFil: Mera, Maria Fernanda. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; ArgentinaFil: Faudone, Sonia Nerina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; ArgentinaFil: Sbarato, Ruben Darío. Universidad Tecnológica Nacional; ArgentinaFil: Campos, Jose Manuel. Universidad Tecnológica Nacional; ArgentinaFil: Zampar, Vanesa Paola. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; ArgentinaFil: Bonzi, Edgardo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; ArgentinaFil: Perez, Carlos. Laboratorio Nacional de Luz Sincrotron. Campinas; BrasilJohn Wiley & Sons Ltd2014-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/33941Rubio, Marcelo; Germanier, A; Mera, Maria Fernanda; Faudone, Sonia Nerina; Sbarato, Ruben Darío; et al.; Study of lead levels in soils by weathering of metallic Pb bullets used in dove hunting in Córdoba, Argentina; John Wiley & Sons Ltd; X-ray Spectrometry; 43; 3; 3-2014; 186-1920049-8246CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/xrs.2539/abstractinfo:eu-repo/semantics/altIdentifier/doi/10.1002/xrs.2539info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:00:18Zoai:ri.conicet.gov.ar:11336/33941instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:00:19.014CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Study of lead levels in soils by weathering of metallic Pb bullets used in dove hunting in Córdoba, Argentina
title Study of lead levels in soils by weathering of metallic Pb bullets used in dove hunting in Córdoba, Argentina
spellingShingle Study of lead levels in soils by weathering of metallic Pb bullets used in dove hunting in Córdoba, Argentina
Rubio, Marcelo
X-Ray Fluorescence
Lead
Hunting
title_short Study of lead levels in soils by weathering of metallic Pb bullets used in dove hunting in Córdoba, Argentina
title_full Study of lead levels in soils by weathering of metallic Pb bullets used in dove hunting in Córdoba, Argentina
title_fullStr Study of lead levels in soils by weathering of metallic Pb bullets used in dove hunting in Córdoba, Argentina
title_full_unstemmed Study of lead levels in soils by weathering of metallic Pb bullets used in dove hunting in Córdoba, Argentina
title_sort Study of lead levels in soils by weathering of metallic Pb bullets used in dove hunting in Córdoba, Argentina
dc.creator.none.fl_str_mv Rubio, Marcelo
Germanier, A
Mera, Maria Fernanda
Faudone, Sonia Nerina
Sbarato, Ruben Darío
Campos, Jose Manuel
Zampar, Vanesa Paola
Bonzi, Edgardo
Perez, Carlos
author Rubio, Marcelo
author_facet Rubio, Marcelo
Germanier, A
Mera, Maria Fernanda
Faudone, Sonia Nerina
Sbarato, Ruben Darío
Campos, Jose Manuel
Zampar, Vanesa Paola
Bonzi, Edgardo
Perez, Carlos
author_role author
author2 Germanier, A
Mera, Maria Fernanda
Faudone, Sonia Nerina
Sbarato, Ruben Darío
Campos, Jose Manuel
Zampar, Vanesa Paola
Bonzi, Edgardo
Perez, Carlos
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv X-Ray Fluorescence
Lead
Hunting
topic X-Ray Fluorescence
Lead
Hunting
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A study of level of Pb in soils of the center-north of the Province of Córdoba, a worldwide recognized tourist region for dove hunting, was performed in this work. The native forest of the region has a great population of doves associated with the grainproductive fields of the surrounding. Contamination of soils due to hunting activities is regulated by national and local norms. The Córdoba Environmental Secretary by resolution no. 1115/2011 approved a new regulation that categorizes this activity as generator of Y31 (Pb) industrial waste. Lead from pellets alloy is deposited on the soil of the shooting fields. Samples were taken at depth of 50mm from 315 pits referenced by GPS in accordance with local environmental authorities as well as the hunting outfitters companies. Sampling sites are distributed between parallels 31 °S (S31) up to 30 °S (S30) and between meridians W64 up to W63. Soils samples were analyzed by X-ray fluorescence spectroscopy while Pb bullets were analyzed by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The average concentration obtained for Pb in dry soil sieved (200 mesh) was 80 ppm. Powder XRD patterns of crust material removed from the corroded surface of weathered bullets were obtained. Three Pb mineral compounds were identified by XRD analysis and also studied by optical microscopy and SEM.
Fil: Rubio, Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
Fil: Germanier, A. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina
Fil: Mera, Maria Fernanda. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina
Fil: Faudone, Sonia Nerina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina
Fil: Sbarato, Ruben Darío. Universidad Tecnológica Nacional; Argentina
Fil: Campos, Jose Manuel. Universidad Tecnológica Nacional; Argentina
Fil: Zampar, Vanesa Paola. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina
Fil: Bonzi, Edgardo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
Fil: Perez, Carlos. Laboratorio Nacional de Luz Sincrotron. Campinas; Brasil
description A study of level of Pb in soils of the center-north of the Province of Córdoba, a worldwide recognized tourist region for dove hunting, was performed in this work. The native forest of the region has a great population of doves associated with the grainproductive fields of the surrounding. Contamination of soils due to hunting activities is regulated by national and local norms. The Córdoba Environmental Secretary by resolution no. 1115/2011 approved a new regulation that categorizes this activity as generator of Y31 (Pb) industrial waste. Lead from pellets alloy is deposited on the soil of the shooting fields. Samples were taken at depth of 50mm from 315 pits referenced by GPS in accordance with local environmental authorities as well as the hunting outfitters companies. Sampling sites are distributed between parallels 31 °S (S31) up to 30 °S (S30) and between meridians W64 up to W63. Soils samples were analyzed by X-ray fluorescence spectroscopy while Pb bullets were analyzed by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The average concentration obtained for Pb in dry soil sieved (200 mesh) was 80 ppm. Powder XRD patterns of crust material removed from the corroded surface of weathered bullets were obtained. Three Pb mineral compounds were identified by XRD analysis and also studied by optical microscopy and SEM.
publishDate 2014
dc.date.none.fl_str_mv 2014-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/33941
Rubio, Marcelo; Germanier, A; Mera, Maria Fernanda; Faudone, Sonia Nerina; Sbarato, Ruben Darío; et al.; Study of lead levels in soils by weathering of metallic Pb bullets used in dove hunting in Córdoba, Argentina; John Wiley & Sons Ltd; X-ray Spectrometry; 43; 3; 3-2014; 186-192
0049-8246
CONICET Digital
CONICET
url http://hdl.handle.net/11336/33941
identifier_str_mv Rubio, Marcelo; Germanier, A; Mera, Maria Fernanda; Faudone, Sonia Nerina; Sbarato, Ruben Darío; et al.; Study of lead levels in soils by weathering of metallic Pb bullets used in dove hunting in Córdoba, Argentina; John Wiley & Sons Ltd; X-ray Spectrometry; 43; 3; 3-2014; 186-192
0049-8246
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/xrs.2539/abstract
info:eu-repo/semantics/altIdentifier/doi/10.1002/xrs.2539
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
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eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Ltd
publisher.none.fl_str_mv John Wiley & Sons Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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