Green synthesis of nanocrystalline faujasite zeolite

Autores
Reinoso, Deborath Mariana; Adrover, María Esperanza; Pedernera, Marisa Noemi
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, the synthesis of 28 and 38 nm Na-Y zeolite nanocrystals is reported. The process was performed via green synthesis without any organic structure directing agents (SDAs), at low temperature and applying ultrasound-assisted aging. The zeolite nanoparticles obtained were characterized by X ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and N2 adsorption – desorption isotherm at 77 K. A simple, fast, efficient and environmentally friendly procedure to synthetize nanocrystalline FAU zeolite is described in the present study. The sonochemical pretreatment was found to directly affect the Na-Y zeolite properties. The final product obtained via ultrasound pretreatment shows high phase purity and crystallinity degree with crystal size smaller than 38 nm and elevated surface area (SBET ∼ 950 m2 g−1). The hierarchical micro- and mesoporous FAU zeolites exhibit a pore volume of ∼0.4 cm3 g−1.
Fil: Reinoso, Deborath Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
Fil: Adrover, María Esperanza. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
Fil: Pedernera, Marisa Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
Materia
FREE ORGANIC TEMPLATE
GREEN SYNTHESIS
NA-Y FAUJASITE
ULTRASOUND PRETREATMENT
ZEOLITE NANOCRYSTALLINE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/87949
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/87949
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Green synthesis of nanocrystalline faujasite zeoliteReinoso, Deborath MarianaAdrover, María EsperanzaPedernera, Marisa NoemiFREE ORGANIC TEMPLATEGREEN SYNTHESISNA-Y FAUJASITEULTRASOUND PRETREATMENTZEOLITE NANOCRYSTALLINEhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2In this work, the synthesis of 28 and 38 nm Na-Y zeolite nanocrystals is reported. The process was performed via green synthesis without any organic structure directing agents (SDAs), at low temperature and applying ultrasound-assisted aging. The zeolite nanoparticles obtained were characterized by X ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and N2 adsorption – desorption isotherm at 77 K. A simple, fast, efficient and environmentally friendly procedure to synthetize nanocrystalline FAU zeolite is described in the present study. The sonochemical pretreatment was found to directly affect the Na-Y zeolite properties. The final product obtained via ultrasound pretreatment shows high phase purity and crystallinity degree with crystal size smaller than 38 nm and elevated surface area (SBET ∼ 950 m2 g−1). The hierarchical micro- and mesoporous FAU zeolites exhibit a pore volume of ∼0.4 cm3 g−1.Fil: Reinoso, Deborath Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; ArgentinaFil: Adrover, María Esperanza. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; ArgentinaFil: Pedernera, Marisa Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; ArgentinaElsevier Science2018-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/87949Reinoso, Deborath Mariana; Adrover, María Esperanza; Pedernera, Marisa Noemi; Green synthesis of nanocrystalline faujasite zeolite; Elsevier Science; Ultrasonics Sonochemistry; 42; 4-2018; 303-3091350-4177CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1350417717305503info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ultsonch.2017.11.034info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:52:18Zoai:ri.conicet.gov.ar:11336/87949instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:52:19.224CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Green synthesis of nanocrystalline faujasite zeolite
title Green synthesis of nanocrystalline faujasite zeolite
spellingShingle Green synthesis of nanocrystalline faujasite zeolite
Reinoso, Deborath Mariana
FREE ORGANIC TEMPLATE
GREEN SYNTHESIS
NA-Y FAUJASITE
ULTRASOUND PRETREATMENT
ZEOLITE NANOCRYSTALLINE
title_short Green synthesis of nanocrystalline faujasite zeolite
title_full Green synthesis of nanocrystalline faujasite zeolite
title_fullStr Green synthesis of nanocrystalline faujasite zeolite
title_full_unstemmed Green synthesis of nanocrystalline faujasite zeolite
title_sort Green synthesis of nanocrystalline faujasite zeolite
dc.creator.none.fl_str_mv Reinoso, Deborath Mariana
Adrover, María Esperanza
Pedernera, Marisa Noemi
author Reinoso, Deborath Mariana
author_facet Reinoso, Deborath Mariana
Adrover, María Esperanza
Pedernera, Marisa Noemi
author_role author
author2 Adrover, María Esperanza
Pedernera, Marisa Noemi
author2_role author
author
dc.subject.none.fl_str_mv FREE ORGANIC TEMPLATE
GREEN SYNTHESIS
NA-Y FAUJASITE
ULTRASOUND PRETREATMENT
ZEOLITE NANOCRYSTALLINE
topic FREE ORGANIC TEMPLATE
GREEN SYNTHESIS
NA-Y FAUJASITE
ULTRASOUND PRETREATMENT
ZEOLITE NANOCRYSTALLINE
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In this work, the synthesis of 28 and 38 nm Na-Y zeolite nanocrystals is reported. The process was performed via green synthesis without any organic structure directing agents (SDAs), at low temperature and applying ultrasound-assisted aging. The zeolite nanoparticles obtained were characterized by X ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and N2 adsorption – desorption isotherm at 77 K. A simple, fast, efficient and environmentally friendly procedure to synthetize nanocrystalline FAU zeolite is described in the present study. The sonochemical pretreatment was found to directly affect the Na-Y zeolite properties. The final product obtained via ultrasound pretreatment shows high phase purity and crystallinity degree with crystal size smaller than 38 nm and elevated surface area (SBET ∼ 950 m2 g−1). The hierarchical micro- and mesoporous FAU zeolites exhibit a pore volume of ∼0.4 cm3 g−1.
Fil: Reinoso, Deborath Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
Fil: Adrover, María Esperanza. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
Fil: Pedernera, Marisa Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
description In this work, the synthesis of 28 and 38 nm Na-Y zeolite nanocrystals is reported. The process was performed via green synthesis without any organic structure directing agents (SDAs), at low temperature and applying ultrasound-assisted aging. The zeolite nanoparticles obtained were characterized by X ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and N2 adsorption – desorption isotherm at 77 K. A simple, fast, efficient and environmentally friendly procedure to synthetize nanocrystalline FAU zeolite is described in the present study. The sonochemical pretreatment was found to directly affect the Na-Y zeolite properties. The final product obtained via ultrasound pretreatment shows high phase purity and crystallinity degree with crystal size smaller than 38 nm and elevated surface area (SBET ∼ 950 m2 g−1). The hierarchical micro- and mesoporous FAU zeolites exhibit a pore volume of ∼0.4 cm3 g−1.
publishDate 2018
dc.date.none.fl_str_mv 2018-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/87949
Reinoso, Deborath Mariana; Adrover, María Esperanza; Pedernera, Marisa Noemi; Green synthesis of nanocrystalline faujasite zeolite; Elsevier Science; Ultrasonics Sonochemistry; 42; 4-2018; 303-309
1350-4177
CONICET Digital
CONICET
url http://hdl.handle.net/11336/87949
identifier_str_mv Reinoso, Deborath Mariana; Adrover, María Esperanza; Pedernera, Marisa Noemi; Green synthesis of nanocrystalline faujasite zeolite; Elsevier Science; Ultrasonics Sonochemistry; 42; 4-2018; 303-309
1350-4177
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1350417717305503
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ultsonch.2017.11.034
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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