Phase transformations during the zeolitization of fly ashes

Autores
Monzón, Jorge Daniel; Pereyra, Andrea Marisa; Conconi, María Susana; Basaldella, Elena Isabel
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The reactivity of a fly ash discarded from a thermoelectric power station was evaluated in terms of its hydrothermal conversion into NaA-containing products. The influence of ash pretreatments and the effect of changes in the synthesis mixture composition on the evolution of the solid phase toward its conversion into zeolitic materials were studied. Activation by milling was not as effective as alkaline fusion. The highest levels of fly ash reactivity were obtained by applying an alkaline fusion treatment using sodium carbonate at 800 °C. It was observed that this particular ash activation induces a solid reordering that generates crystalline materials identified as NaAlSiO2 polymorphs that in turn are easily transformed into zeolite structures. Synthesis conditions for ash zeolitization as high as 60% were established.
Fil: Monzón, Jorge Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
Fil: Pereyra, Andrea Marisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
Fil: Conconi, María Susana. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Basaldella, Elena Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
Materia
Fly Ashes
Hydrothermal Synthesis
Pretreatment
Zeolites
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/63658
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Phase transformations during the zeolitization of fly ashesMonzón, Jorge DanielPereyra, Andrea MarisaConconi, María SusanaBasaldella, Elena IsabelFly AshesHydrothermal SynthesisPretreatmentZeolitesThe reactivity of a fly ash discarded from a thermoelectric power station was evaluated in terms of its hydrothermal conversion into NaA-containing products. The influence of ash pretreatments and the effect of changes in the synthesis mixture composition on the evolution of the solid phase toward its conversion into zeolitic materials were studied. Activation by milling was not as effective as alkaline fusion. The highest levels of fly ash reactivity were obtained by applying an alkaline fusion treatment using sodium carbonate at 800 °C. It was observed that this particular ash activation induces a solid reordering that generates crystalline materials identified as NaAlSiO2 polymorphs that in turn are easily transformed into zeolite structures. Synthesis conditions for ash zeolitization as high as 60% were established.Fil: Monzón, Jorge Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; ArgentinaFil: Pereyra, Andrea Marisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; ArgentinaFil: Conconi, María Susana. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaFil: Basaldella, Elena Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; ArgentinaElsevier2017-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/63658Monzón, Jorge Daniel; Pereyra, Andrea Marisa; Conconi, María Susana; Basaldella, Elena Isabel; Phase transformations during the zeolitization of fly ashes; Elsevier; Journal of Environmental Chemical Engineering; 5; 2; 4-2017; 1548-15532213-3437CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jece.2017.02.022info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2213343717300738info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:16:41Zoai:ri.conicet.gov.ar:11336/63658instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:16:41.733CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Phase transformations during the zeolitization of fly ashes
title Phase transformations during the zeolitization of fly ashes
spellingShingle Phase transformations during the zeolitization of fly ashes
Monzón, Jorge Daniel
Fly Ashes
Hydrothermal Synthesis
Pretreatment
Zeolites
title_short Phase transformations during the zeolitization of fly ashes
title_full Phase transformations during the zeolitization of fly ashes
title_fullStr Phase transformations during the zeolitization of fly ashes
title_full_unstemmed Phase transformations during the zeolitization of fly ashes
title_sort Phase transformations during the zeolitization of fly ashes
dc.creator.none.fl_str_mv Monzón, Jorge Daniel
Pereyra, Andrea Marisa
Conconi, María Susana
Basaldella, Elena Isabel
author Monzón, Jorge Daniel
author_facet Monzón, Jorge Daniel
Pereyra, Andrea Marisa
Conconi, María Susana
Basaldella, Elena Isabel
author_role author
author2 Pereyra, Andrea Marisa
Conconi, María Susana
Basaldella, Elena Isabel
author2_role author
author
author
dc.subject.none.fl_str_mv Fly Ashes
Hydrothermal Synthesis
Pretreatment
Zeolites
topic Fly Ashes
Hydrothermal Synthesis
Pretreatment
Zeolites
dc.description.none.fl_txt_mv The reactivity of a fly ash discarded from a thermoelectric power station was evaluated in terms of its hydrothermal conversion into NaA-containing products. The influence of ash pretreatments and the effect of changes in the synthesis mixture composition on the evolution of the solid phase toward its conversion into zeolitic materials were studied. Activation by milling was not as effective as alkaline fusion. The highest levels of fly ash reactivity were obtained by applying an alkaline fusion treatment using sodium carbonate at 800 °C. It was observed that this particular ash activation induces a solid reordering that generates crystalline materials identified as NaAlSiO2 polymorphs that in turn are easily transformed into zeolite structures. Synthesis conditions for ash zeolitization as high as 60% were established.
Fil: Monzón, Jorge Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
Fil: Pereyra, Andrea Marisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
Fil: Conconi, María Susana. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Basaldella, Elena Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
description The reactivity of a fly ash discarded from a thermoelectric power station was evaluated in terms of its hydrothermal conversion into NaA-containing products. The influence of ash pretreatments and the effect of changes in the synthesis mixture composition on the evolution of the solid phase toward its conversion into zeolitic materials were studied. Activation by milling was not as effective as alkaline fusion. The highest levels of fly ash reactivity were obtained by applying an alkaline fusion treatment using sodium carbonate at 800 °C. It was observed that this particular ash activation induces a solid reordering that generates crystalline materials identified as NaAlSiO2 polymorphs that in turn are easily transformed into zeolite structures. Synthesis conditions for ash zeolitization as high as 60% were established.
publishDate 2017
dc.date.none.fl_str_mv 2017-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/63658
Monzón, Jorge Daniel; Pereyra, Andrea Marisa; Conconi, María Susana; Basaldella, Elena Isabel; Phase transformations during the zeolitization of fly ashes; Elsevier; Journal of Environmental Chemical Engineering; 5; 2; 4-2017; 1548-1553
2213-3437
CONICET Digital
CONICET
url http://hdl.handle.net/11336/63658
identifier_str_mv Monzón, Jorge Daniel; Pereyra, Andrea Marisa; Conconi, María Susana; Basaldella, Elena Isabel; Phase transformations during the zeolitization of fly ashes; Elsevier; Journal of Environmental Chemical Engineering; 5; 2; 4-2017; 1548-1553
2213-3437
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jece.2017.02.022
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2213343717300738
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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