Phase transformations during the zeolitization of fly ashes
- Autores
- Monzón, Jorge Daniel; Pereyra, Andrea Marisa; Conconi, María Susana; Basaldella, Elena Isabel
- Año de publicación
- 2017
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The reactivity of a fly ash discarded from a thermoelectric power station was evaluated in terms of its hydrothermal conversion into NaA-containing products. The influence of ash pretreatments and the effect of changes in the synthesis mixture composition on the evolution of the solid phase toward its conversion into zeolitic materials were studied. Activation by milling was not as effective as alkaline fusion. The highest levels of fly ash reactivity were obtained by applying an alkaline fusion treatment using sodium carbonate at 800 °C. It was observed that this particular ash activation induces a solid reordering that generates crystalline materials identified as NaAlSiO2 polymorphs that in turn are easily transformed into zeolite structures. Synthesis conditions for ash zeolitization as high as 60% were established.
Fil: Monzón, Jorge Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
Fil: Pereyra, Andrea Marisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
Fil: Conconi, María Susana. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Basaldella, Elena Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina - Materia
-
Fly Ashes
Hydrothermal Synthesis
Pretreatment
Zeolites - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/63658
Ver los metadatos del registro completo
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Phase transformations during the zeolitization of fly ashesMonzón, Jorge DanielPereyra, Andrea MarisaConconi, María SusanaBasaldella, Elena IsabelFly AshesHydrothermal SynthesisPretreatmentZeolitesThe reactivity of a fly ash discarded from a thermoelectric power station was evaluated in terms of its hydrothermal conversion into NaA-containing products. The influence of ash pretreatments and the effect of changes in the synthesis mixture composition on the evolution of the solid phase toward its conversion into zeolitic materials were studied. Activation by milling was not as effective as alkaline fusion. The highest levels of fly ash reactivity were obtained by applying an alkaline fusion treatment using sodium carbonate at 800 °C. It was observed that this particular ash activation induces a solid reordering that generates crystalline materials identified as NaAlSiO2 polymorphs that in turn are easily transformed into zeolite structures. Synthesis conditions for ash zeolitization as high as 60% were established.Fil: Monzón, Jorge Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; ArgentinaFil: Pereyra, Andrea Marisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; ArgentinaFil: Conconi, María Susana. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaFil: Basaldella, Elena Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; ArgentinaElsevier2017-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/63658Monzón, Jorge Daniel; Pereyra, Andrea Marisa; Conconi, María Susana; Basaldella, Elena Isabel; Phase transformations during the zeolitization of fly ashes; Elsevier; Journal of Environmental Chemical Engineering; 5; 2; 4-2017; 1548-15532213-3437CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jece.2017.02.022info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2213343717300738info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:47:49Zoai:ri.conicet.gov.ar:11336/63658instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:47:49.533CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Phase transformations during the zeolitization of fly ashes |
title |
Phase transformations during the zeolitization of fly ashes |
spellingShingle |
Phase transformations during the zeolitization of fly ashes Monzón, Jorge Daniel Fly Ashes Hydrothermal Synthesis Pretreatment Zeolites |
title_short |
Phase transformations during the zeolitization of fly ashes |
title_full |
Phase transformations during the zeolitization of fly ashes |
title_fullStr |
Phase transformations during the zeolitization of fly ashes |
title_full_unstemmed |
Phase transformations during the zeolitization of fly ashes |
title_sort |
Phase transformations during the zeolitization of fly ashes |
dc.creator.none.fl_str_mv |
Monzón, Jorge Daniel Pereyra, Andrea Marisa Conconi, María Susana Basaldella, Elena Isabel |
author |
Monzón, Jorge Daniel |
author_facet |
Monzón, Jorge Daniel Pereyra, Andrea Marisa Conconi, María Susana Basaldella, Elena Isabel |
author_role |
author |
author2 |
Pereyra, Andrea Marisa Conconi, María Susana Basaldella, Elena Isabel |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Fly Ashes Hydrothermal Synthesis Pretreatment Zeolites |
topic |
Fly Ashes Hydrothermal Synthesis Pretreatment Zeolites |
dc.description.none.fl_txt_mv |
The reactivity of a fly ash discarded from a thermoelectric power station was evaluated in terms of its hydrothermal conversion into NaA-containing products. The influence of ash pretreatments and the effect of changes in the synthesis mixture composition on the evolution of the solid phase toward its conversion into zeolitic materials were studied. Activation by milling was not as effective as alkaline fusion. The highest levels of fly ash reactivity were obtained by applying an alkaline fusion treatment using sodium carbonate at 800 °C. It was observed that this particular ash activation induces a solid reordering that generates crystalline materials identified as NaAlSiO2 polymorphs that in turn are easily transformed into zeolite structures. Synthesis conditions for ash zeolitization as high as 60% were established. Fil: Monzón, Jorge Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina Fil: Pereyra, Andrea Marisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina Fil: Conconi, María Susana. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina Fil: Basaldella, Elena Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina |
description |
The reactivity of a fly ash discarded from a thermoelectric power station was evaluated in terms of its hydrothermal conversion into NaA-containing products. The influence of ash pretreatments and the effect of changes in the synthesis mixture composition on the evolution of the solid phase toward its conversion into zeolitic materials were studied. Activation by milling was not as effective as alkaline fusion. The highest levels of fly ash reactivity were obtained by applying an alkaline fusion treatment using sodium carbonate at 800 °C. It was observed that this particular ash activation induces a solid reordering that generates crystalline materials identified as NaAlSiO2 polymorphs that in turn are easily transformed into zeolite structures. Synthesis conditions for ash zeolitization as high as 60% were established. |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017-04 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/63658 Monzón, Jorge Daniel; Pereyra, Andrea Marisa; Conconi, María Susana; Basaldella, Elena Isabel; Phase transformations during the zeolitization of fly ashes; Elsevier; Journal of Environmental Chemical Engineering; 5; 2; 4-2017; 1548-1553 2213-3437 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/63658 |
identifier_str_mv |
Monzón, Jorge Daniel; Pereyra, Andrea Marisa; Conconi, María Susana; Basaldella, Elena Isabel; Phase transformations during the zeolitization of fly ashes; Elsevier; Journal of Environmental Chemical Engineering; 5; 2; 4-2017; 1548-1553 2213-3437 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jece.2017.02.022 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2213343717300738 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613488994942976 |
score |
13.070432 |