Phase transformation during the zeolitization of fly ashes

Autores
Monzón, Jorge; Pereyra, Andrea; Conconi, Susana; Basaldella, Elena
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The reactivity of a fly ash discarded from a thermoelectric power station was evaluated in terms of its hydrothermal conversion into NaA-containing products. The influence of ash pretreatments and the effect of changes in the synthesis mixture composition on the evolution of the solid phase toward its conversion into zeolitic materials were studied. Activation by milling was not as effective as alkaline fusion. The highest levels of fly ash reactivity were obtained by applying an alkaline fusion treatment using sodium carbonate at 800 C. It was observed that this particular ash activatiorn induces a solid reordering that generates crystalline materials identified as NaAlSiO2 polymorphs that in turn are easily transformed into zeolite structures. Synthesis conditions for ash zeolitization as high as 60% were established.
Fil: Monzón, Jorge. UTN (Universidad Tecnológica Nacional). CITEMA (Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales); Argentina
Fil: Pereyra, Andrea. UTN (Universidad Tecnológica Nacional). CITEMA (Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales). UNLP (Universidad Nacional La Plata). CINDECA; Argentina
Fil: Conconi, Susana. Centro de Tecnología de Recursos Minerales y Cerámicos; Argentina
Fil: Basaldella, Elena. UTN (Universidad Tecnológica Nacional). CITEMA (Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales). UNLP (Universidad Nacional La Plata). CINDECA; Argentina
Peer Reviewed
Materia
Fly ashes, Pretreatment, Hydrothermal synthesis, Zeolites
Nivel de accesibilidad
acceso abierto
Condiciones de uso
Atribución (Attribution): En cualquier explotación de la obra autorizada por la licencia será necesario reconocer la autoría (obligatoria en todos los casos). No comercial (Non Commercial): La explotación de la obra queda limitada a usos no comerciales. Sin obras derivadas (No Derivate Works): La autorización para explotar la obra no incluye la posibilidad de crear una obra derivada (traducciones, adaptaciones, etc.).
Repositorio
Repositorio Institucional Abierto (UTN)
Institución
Universidad Tecnológica Nacional
OAI Identificador
oai:ria.utn.edu.ar:20.500.12272/3117
Acceder
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network_acronym_str RIAUTN
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network_name_str Repositorio Institucional Abierto (UTN)
spelling Phase transformation during the zeolitization of fly ashesMonzón, JorgePereyra, AndreaConconi, SusanaBasaldella, ElenaFly ashes, Pretreatment, Hydrothermal synthesis, ZeolitesThe reactivity of a fly ash discarded from a thermoelectric power station was evaluated in terms of its hydrothermal conversion into NaA-containing products. The influence of ash pretreatments and the effect of changes in the synthesis mixture composition on the evolution of the solid phase toward its conversion into zeolitic materials were studied. Activation by milling was not as effective as alkaline fusion. The highest levels of fly ash reactivity were obtained by applying an alkaline fusion treatment using sodium carbonate at 800 C. It was observed that this particular ash activatiorn induces a solid reordering that generates crystalline materials identified as NaAlSiO2 polymorphs that in turn are easily transformed into zeolite structures. Synthesis conditions for ash zeolitization as high as 60% were established.Fil: Monzón, Jorge. UTN (Universidad Tecnológica Nacional). CITEMA (Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales); ArgentinaFil: Pereyra, Andrea. UTN (Universidad Tecnológica Nacional). CITEMA (Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales). UNLP (Universidad Nacional La Plata). CINDECA; ArgentinaFil: Conconi, Susana. Centro de Tecnología de Recursos Minerales y Cerámicos; ArgentinaFil: Basaldella, Elena. UTN (Universidad Tecnológica Nacional). CITEMA (Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales). UNLP (Universidad Nacional La Plata). CINDECA; ArgentinaPeer ReviewedElsevier2018-09-14T15:42:57Z2018-09-14T15:42:57Z2017info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfJournal of Environmental Chemical Engineeringhttp://hdl.handle.net/20.500.12272/311710.1016/j.jece.2017.02.022enghttp://dx.doi.org/10.1016/j.jece.2017.02.022info:eu-repo/semantics/openAccessAtribución (Attribution): En cualquier explotación de la obra autorizada por la licencia será necesario reconocer la autoría (obligatoria en todos los casos). No comercial (Non Commercial): La explotación de la obra queda limitada a usos no comerciales. Sin obras derivadas (No Derivate Works): La autorización para explotar la obra no incluye la posibilidad de crear una obra derivada (traducciones, adaptaciones, etc.).reponame:Repositorio Institucional Abierto (UTN)instname:Universidad Tecnológica Nacional2025-10-23T11:18:44Zoai:ria.utn.edu.ar:20.500.12272/3117instacron:UTNInstitucionalhttp://ria.utn.edu.ar/Universidad públicaNo correspondehttp://ria.utn.edu.ar/oaigestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:a2025-10-23 11:18:44.622Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacionalfalse
dc.title.none.fl_str_mv Phase transformation during the zeolitization of fly ashes
title Phase transformation during the zeolitization of fly ashes
spellingShingle Phase transformation during the zeolitization of fly ashes
Monzón, Jorge
Fly ashes, Pretreatment, Hydrothermal synthesis, Zeolites
title_short Phase transformation during the zeolitization of fly ashes
title_full Phase transformation during the zeolitization of fly ashes
title_fullStr Phase transformation during the zeolitization of fly ashes
title_full_unstemmed Phase transformation during the zeolitization of fly ashes
title_sort Phase transformation during the zeolitization of fly ashes
dc.creator.none.fl_str_mv Monzón, Jorge
Pereyra, Andrea
Conconi, Susana
Basaldella, Elena
author Monzón, Jorge
author_facet Monzón, Jorge
Pereyra, Andrea
Conconi, Susana
Basaldella, Elena
author_role author
author2 Pereyra, Andrea
Conconi, Susana
Basaldella, Elena
author2_role author
author
author
dc.subject.none.fl_str_mv Fly ashes, Pretreatment, Hydrothermal synthesis, Zeolites
topic Fly ashes, Pretreatment, Hydrothermal synthesis, Zeolites
dc.description.none.fl_txt_mv The reactivity of a fly ash discarded from a thermoelectric power station was evaluated in terms of its hydrothermal conversion into NaA-containing products. The influence of ash pretreatments and the effect of changes in the synthesis mixture composition on the evolution of the solid phase toward its conversion into zeolitic materials were studied. Activation by milling was not as effective as alkaline fusion. The highest levels of fly ash reactivity were obtained by applying an alkaline fusion treatment using sodium carbonate at 800 C. It was observed that this particular ash activatiorn induces a solid reordering that generates crystalline materials identified as NaAlSiO2 polymorphs that in turn are easily transformed into zeolite structures. Synthesis conditions for ash zeolitization as high as 60% were established.
Fil: Monzón, Jorge. UTN (Universidad Tecnológica Nacional). CITEMA (Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales); Argentina
Fil: Pereyra, Andrea. UTN (Universidad Tecnológica Nacional). CITEMA (Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales). UNLP (Universidad Nacional La Plata). CINDECA; Argentina
Fil: Conconi, Susana. Centro de Tecnología de Recursos Minerales y Cerámicos; Argentina
Fil: Basaldella, Elena. UTN (Universidad Tecnológica Nacional). CITEMA (Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales). UNLP (Universidad Nacional La Plata). CINDECA; Argentina
Peer Reviewed
description The reactivity of a fly ash discarded from a thermoelectric power station was evaluated in terms of its hydrothermal conversion into NaA-containing products. The influence of ash pretreatments and the effect of changes in the synthesis mixture composition on the evolution of the solid phase toward its conversion into zeolitic materials were studied. Activation by milling was not as effective as alkaline fusion. The highest levels of fly ash reactivity were obtained by applying an alkaline fusion treatment using sodium carbonate at 800 C. It was observed that this particular ash activatiorn induces a solid reordering that generates crystalline materials identified as NaAlSiO2 polymorphs that in turn are easily transformed into zeolite structures. Synthesis conditions for ash zeolitization as high as 60% were established.
publishDate 2017
dc.date.none.fl_str_mv 2017
2018-09-14T15:42:57Z
2018-09-14T15:42:57Z
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv Journal of Environmental Chemical Engineering
http://hdl.handle.net/20.500.12272/3117
10.1016/j.jece.2017.02.022
identifier_str_mv Journal of Environmental Chemical Engineering
10.1016/j.jece.2017.02.022
url http://hdl.handle.net/20.500.12272/3117
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv http://dx.doi.org/10.1016/j.jece.2017.02.022
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
Atribución (Attribution): En cualquier explotación de la obra autorizada por la licencia será necesario reconocer la autoría (obligatoria en todos los casos). No comercial (Non Commercial): La explotación de la obra queda limitada a usos no comerciales. Sin obras derivadas (No Derivate Works): La autorización para explotar la obra no incluye la posibilidad de crear una obra derivada (traducciones, adaptaciones, etc.).
eu_rights_str_mv openAccess
rights_invalid_str_mv Atribución (Attribution): En cualquier explotación de la obra autorizada por la licencia será necesario reconocer la autoría (obligatoria en todos los casos). No comercial (Non Commercial): La explotación de la obra queda limitada a usos no comerciales. Sin obras derivadas (No Derivate Works): La autorización para explotar la obra no incluye la posibilidad de crear una obra derivada (traducciones, adaptaciones, etc.).
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositorio Institucional Abierto (UTN)
instname:Universidad Tecnológica Nacional
reponame_str Repositorio Institucional Abierto (UTN)
collection Repositorio Institucional Abierto (UTN)
instname_str Universidad Tecnológica Nacional
repository.name.fl_str_mv Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacional
repository.mail.fl_str_mv gestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.ar
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score 12.471625

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