Organic-Free Synthesis of Finned Mordenite Zeolite

Autores
Lima, Rafael C.; Lopes, Christian W.; Villarroel Rocha, Jhonny; Bieseki, Lindiane; Sapag, Manuel Karim; Pergher, Sibele B. C.
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Mordenite is a well-known zeolite widely used for industrial processes. However, its pore architecture can be inconvenient due to diffusional issues. A study of the synthesis parameters from an organic-free dense gel was carried out to control the crystal morphology, which resulted in finned mordenite zeolite particles. The obtained materials were characterized by XRD, FTIR, 29Si and 27Al MAS-NMR, elemental analysis, nitrogen physisorption, SEM, and TEM. We found that careful manipulation of the hydrothermal parameters directly affected the sizes and morphologies of the crystallites and particles, as well as the textural properties of the final products. Additionally, it was found that mordenite could exhibit a fin morphology with additional mesoporosity, which is a promising means to reduce the diffusional problems of one-dimensional-channel zeolites.
Fil: Lima, Rafael C.. Universidade Federal do Rio Grande do Norte; Brasil
Fil: Lopes, Christian W.. Universidade Federal do Rio Grande do Sul; Brasil
Fil: Villarroel Rocha, Jhonny. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Bieseki, Lindiane. Universidade Federal do Rio Grande do Norte; Brasil
Fil: Sapag, Manuel Karim. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Pergher, Sibele B. C.. Universidade Federal do Rio Grande do Norte; Brasil
Materia
FINNED PARTICLES
MORDENITE
MORPHOLOGY
ORGANIC-FREE SYNTHESIS
ZEOLITE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/223637
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Organic-Free Synthesis of Finned Mordenite ZeoliteLima, Rafael C.Lopes, Christian W.Villarroel Rocha, JhonnyBieseki, LindianeSapag, Manuel KarimPergher, Sibele B. C.FINNED PARTICLESMORDENITEMORPHOLOGYORGANIC-FREE SYNTHESISZEOLITEhttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1Mordenite is a well-known zeolite widely used for industrial processes. However, its pore architecture can be inconvenient due to diffusional issues. A study of the synthesis parameters from an organic-free dense gel was carried out to control the crystal morphology, which resulted in finned mordenite zeolite particles. The obtained materials were characterized by XRD, FTIR, 29Si and 27Al MAS-NMR, elemental analysis, nitrogen physisorption, SEM, and TEM. We found that careful manipulation of the hydrothermal parameters directly affected the sizes and morphologies of the crystallites and particles, as well as the textural properties of the final products. Additionally, it was found that mordenite could exhibit a fin morphology with additional mesoporosity, which is a promising means to reduce the diffusional problems of one-dimensional-channel zeolites.Fil: Lima, Rafael C.. Universidade Federal do Rio Grande do Norte; BrasilFil: Lopes, Christian W.. Universidade Federal do Rio Grande do Sul; BrasilFil: Villarroel Rocha, Jhonny. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaFil: Bieseki, Lindiane. Universidade Federal do Rio Grande do Norte; BrasilFil: Sapag, Manuel Karim. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaFil: Pergher, Sibele B. C.. Universidade Federal do Rio Grande do Norte; BrasilMDPI2022-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/223637Lima, Rafael C.; Lopes, Christian W.; Villarroel Rocha, Jhonny; Bieseki, Lindiane; Sapag, Manuel Karim; et al.; Organic-Free Synthesis of Finned Mordenite Zeolite; MDPI; Nanomaterials; 12; 15; 8-2022; 1-162079-4991CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.3390/nano12152623info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:02:39Zoai:ri.conicet.gov.ar:11336/223637instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:02:39.737CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Organic-Free Synthesis of Finned Mordenite Zeolite
title Organic-Free Synthesis of Finned Mordenite Zeolite
spellingShingle Organic-Free Synthesis of Finned Mordenite Zeolite
Lima, Rafael C.
FINNED PARTICLES
MORDENITE
MORPHOLOGY
ORGANIC-FREE SYNTHESIS
ZEOLITE
title_short Organic-Free Synthesis of Finned Mordenite Zeolite
title_full Organic-Free Synthesis of Finned Mordenite Zeolite
title_fullStr Organic-Free Synthesis of Finned Mordenite Zeolite
title_full_unstemmed Organic-Free Synthesis of Finned Mordenite Zeolite
title_sort Organic-Free Synthesis of Finned Mordenite Zeolite
dc.creator.none.fl_str_mv Lima, Rafael C.
Lopes, Christian W.
Villarroel Rocha, Jhonny
Bieseki, Lindiane
Sapag, Manuel Karim
Pergher, Sibele B. C.
author Lima, Rafael C.
author_facet Lima, Rafael C.
Lopes, Christian W.
Villarroel Rocha, Jhonny
Bieseki, Lindiane
Sapag, Manuel Karim
Pergher, Sibele B. C.
author_role author
author2 Lopes, Christian W.
Villarroel Rocha, Jhonny
Bieseki, Lindiane
Sapag, Manuel Karim
Pergher, Sibele B. C.
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv FINNED PARTICLES
MORDENITE
MORPHOLOGY
ORGANIC-FREE SYNTHESIS
ZEOLITE
topic FINNED PARTICLES
MORDENITE
MORPHOLOGY
ORGANIC-FREE SYNTHESIS
ZEOLITE
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Mordenite is a well-known zeolite widely used for industrial processes. However, its pore architecture can be inconvenient due to diffusional issues. A study of the synthesis parameters from an organic-free dense gel was carried out to control the crystal morphology, which resulted in finned mordenite zeolite particles. The obtained materials were characterized by XRD, FTIR, 29Si and 27Al MAS-NMR, elemental analysis, nitrogen physisorption, SEM, and TEM. We found that careful manipulation of the hydrothermal parameters directly affected the sizes and morphologies of the crystallites and particles, as well as the textural properties of the final products. Additionally, it was found that mordenite could exhibit a fin morphology with additional mesoporosity, which is a promising means to reduce the diffusional problems of one-dimensional-channel zeolites.
Fil: Lima, Rafael C.. Universidade Federal do Rio Grande do Norte; Brasil
Fil: Lopes, Christian W.. Universidade Federal do Rio Grande do Sul; Brasil
Fil: Villarroel Rocha, Jhonny. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Bieseki, Lindiane. Universidade Federal do Rio Grande do Norte; Brasil
Fil: Sapag, Manuel Karim. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Pergher, Sibele B. C.. Universidade Federal do Rio Grande do Norte; Brasil
description Mordenite is a well-known zeolite widely used for industrial processes. However, its pore architecture can be inconvenient due to diffusional issues. A study of the synthesis parameters from an organic-free dense gel was carried out to control the crystal morphology, which resulted in finned mordenite zeolite particles. The obtained materials were characterized by XRD, FTIR, 29Si and 27Al MAS-NMR, elemental analysis, nitrogen physisorption, SEM, and TEM. We found that careful manipulation of the hydrothermal parameters directly affected the sizes and morphologies of the crystallites and particles, as well as the textural properties of the final products. Additionally, it was found that mordenite could exhibit a fin morphology with additional mesoporosity, which is a promising means to reduce the diffusional problems of one-dimensional-channel zeolites.
publishDate 2022
dc.date.none.fl_str_mv 2022-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/223637
Lima, Rafael C.; Lopes, Christian W.; Villarroel Rocha, Jhonny; Bieseki, Lindiane; Sapag, Manuel Karim; et al.; Organic-Free Synthesis of Finned Mordenite Zeolite; MDPI; Nanomaterials; 12; 15; 8-2022; 1-16
2079-4991
CONICET Digital
CONICET
url http://hdl.handle.net/11336/223637
identifier_str_mv Lima, Rafael C.; Lopes, Christian W.; Villarroel Rocha, Jhonny; Bieseki, Lindiane; Sapag, Manuel Karim; et al.; Organic-Free Synthesis of Finned Mordenite Zeolite; MDPI; Nanomaterials; 12; 15; 8-2022; 1-16
2079-4991
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.3390/nano12152623
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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