Micro-Raman spectroscopy of carbon-based black pigments

Autores
Tomasini, Eugenia Paula; Halac, Emilia Beatriz; Reinoso, Maria Elba; Di Liscia, Emiliano Javier; Maier, Marta Silvia
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Carbon-based black pigments are a wide group of dark-colored materials, which are classified according to the starting material used and their method of manufacture. Raman spectroscopy is an ideal technique for the characterization of carbonaceous matter: crystalline carbon materials present well-defined peaks, which can be easily assigned; amorphous carbon materials, on the other hand, show broad bands between 1300 and 1600 cm -1. The aim of this work was the discrimination between carbon-based pigments by micro-Raman spectroscopy. Five carbon-based pigments provided by Zecchi (lampblack, ivory black, bistre, bitumen, and graphite), two humic-earth materials [Van Dyck (Kremer) and Earth of Kassel (Zecchi)], and a commercial wood charcoal were studied. Raman spectra of all the samples showed the characteristic bands at approximately 1580 and 1350 cm -1; however, a clear difference in position, width, and relative intensity could be observed for most of the samples. The resulting analysis showed that micro-Raman spectroscopy allowed the discrimination of most of the reference pigments and allowed the identification of carbon-based black pigments in two South American colonial paintings dated from the early 18th century. Copyright © 2012 John Wiley & Sons, Ltd.
Fil: Tomasini, Eugenia Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos en Química Orgánica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Unidad de Microanálisis y Métodos Físicos en Química Orgánica; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina
Fil: Halac, Emilia Beatriz. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina
Fil: Reinoso, Maria Elba. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina
Fil: Di Liscia, Emiliano Javier. Comisión Nacional de Energía Atómica; Argentina
Fil: Maier, Marta Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos en Química Orgánica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Unidad de Microanálisis y Métodos Físicos en Química Orgánica; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina
Materia
Art And Archaeology
Carbon-Based Pigments
Colonial Art
Micro-Raman Spectroscopy
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/69535
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/69535
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Micro-Raman spectroscopy of carbon-based black pigmentsTomasini, Eugenia PaulaHalac, Emilia BeatrizReinoso, Maria ElbaDi Liscia, Emiliano JavierMaier, Marta SilviaArt And ArchaeologyCarbon-Based PigmentsColonial ArtMicro-Raman Spectroscopyhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Carbon-based black pigments are a wide group of dark-colored materials, which are classified according to the starting material used and their method of manufacture. Raman spectroscopy is an ideal technique for the characterization of carbonaceous matter: crystalline carbon materials present well-defined peaks, which can be easily assigned; amorphous carbon materials, on the other hand, show broad bands between 1300 and 1600 cm -1. The aim of this work was the discrimination between carbon-based pigments by micro-Raman spectroscopy. Five carbon-based pigments provided by Zecchi (lampblack, ivory black, bistre, bitumen, and graphite), two humic-earth materials [Van Dyck (Kremer) and Earth of Kassel (Zecchi)], and a commercial wood charcoal were studied. Raman spectra of all the samples showed the characteristic bands at approximately 1580 and 1350 cm -1; however, a clear difference in position, width, and relative intensity could be observed for most of the samples. The resulting analysis showed that micro-Raman spectroscopy allowed the discrimination of most of the reference pigments and allowed the identification of carbon-based black pigments in two South American colonial paintings dated from the early 18th century. Copyright © 2012 John Wiley & Sons, Ltd.Fil: Tomasini, Eugenia Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos en Química Orgánica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Unidad de Microanálisis y Métodos Físicos en Química Orgánica; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; ArgentinaFil: Halac, Emilia Beatriz. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; ArgentinaFil: Reinoso, Maria Elba. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; ArgentinaFil: Di Liscia, Emiliano Javier. Comisión Nacional de Energía Atómica; ArgentinaFil: Maier, Marta Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos en Química Orgánica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Unidad de Microanálisis y Métodos Físicos en Química Orgánica; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; ArgentinaJohn Wiley & Sons Ltd2012-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/69535Tomasini, Eugenia Paula; Halac, Emilia Beatriz; Reinoso, Maria Elba; Di Liscia, Emiliano Javier; Maier, Marta Silvia; Micro-Raman spectroscopy of carbon-based black pigments; John Wiley & Sons Ltd; Journal Of Raman Spectroscopy; 43; 11; 11-2012; 1671-16750377-0486CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/jrs.4159info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/jrs.4159info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:30:50Zoai:ri.conicet.gov.ar:11336/69535instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:30:51.017CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Micro-Raman spectroscopy of carbon-based black pigments
title Micro-Raman spectroscopy of carbon-based black pigments
spellingShingle Micro-Raman spectroscopy of carbon-based black pigments
Tomasini, Eugenia Paula
Art And Archaeology
Carbon-Based Pigments
Colonial Art
Micro-Raman Spectroscopy
title_short Micro-Raman spectroscopy of carbon-based black pigments
title_full Micro-Raman spectroscopy of carbon-based black pigments
title_fullStr Micro-Raman spectroscopy of carbon-based black pigments
title_full_unstemmed Micro-Raman spectroscopy of carbon-based black pigments
title_sort Micro-Raman spectroscopy of carbon-based black pigments
dc.creator.none.fl_str_mv Tomasini, Eugenia Paula
Halac, Emilia Beatriz
Reinoso, Maria Elba
Di Liscia, Emiliano Javier
Maier, Marta Silvia
author Tomasini, Eugenia Paula
author_facet Tomasini, Eugenia Paula
Halac, Emilia Beatriz
Reinoso, Maria Elba
Di Liscia, Emiliano Javier
Maier, Marta Silvia
author_role author
author2 Halac, Emilia Beatriz
Reinoso, Maria Elba
Di Liscia, Emiliano Javier
Maier, Marta Silvia
author2_role author
author
author
author
dc.subject.none.fl_str_mv Art And Archaeology
Carbon-Based Pigments
Colonial Art
Micro-Raman Spectroscopy
topic Art And Archaeology
Carbon-Based Pigments
Colonial Art
Micro-Raman Spectroscopy
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Carbon-based black pigments are a wide group of dark-colored materials, which are classified according to the starting material used and their method of manufacture. Raman spectroscopy is an ideal technique for the characterization of carbonaceous matter: crystalline carbon materials present well-defined peaks, which can be easily assigned; amorphous carbon materials, on the other hand, show broad bands between 1300 and 1600 cm -1. The aim of this work was the discrimination between carbon-based pigments by micro-Raman spectroscopy. Five carbon-based pigments provided by Zecchi (lampblack, ivory black, bistre, bitumen, and graphite), two humic-earth materials [Van Dyck (Kremer) and Earth of Kassel (Zecchi)], and a commercial wood charcoal were studied. Raman spectra of all the samples showed the characteristic bands at approximately 1580 and 1350 cm -1; however, a clear difference in position, width, and relative intensity could be observed for most of the samples. The resulting analysis showed that micro-Raman spectroscopy allowed the discrimination of most of the reference pigments and allowed the identification of carbon-based black pigments in two South American colonial paintings dated from the early 18th century. Copyright © 2012 John Wiley & Sons, Ltd.
Fil: Tomasini, Eugenia Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos en Química Orgánica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Unidad de Microanálisis y Métodos Físicos en Química Orgánica; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina
Fil: Halac, Emilia Beatriz. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina
Fil: Reinoso, Maria Elba. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina
Fil: Di Liscia, Emiliano Javier. Comisión Nacional de Energía Atómica; Argentina
Fil: Maier, Marta Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos en Química Orgánica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Unidad de Microanálisis y Métodos Físicos en Química Orgánica; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina
description Carbon-based black pigments are a wide group of dark-colored materials, which are classified according to the starting material used and their method of manufacture. Raman spectroscopy is an ideal technique for the characterization of carbonaceous matter: crystalline carbon materials present well-defined peaks, which can be easily assigned; amorphous carbon materials, on the other hand, show broad bands between 1300 and 1600 cm -1. The aim of this work was the discrimination between carbon-based pigments by micro-Raman spectroscopy. Five carbon-based pigments provided by Zecchi (lampblack, ivory black, bistre, bitumen, and graphite), two humic-earth materials [Van Dyck (Kremer) and Earth of Kassel (Zecchi)], and a commercial wood charcoal were studied. Raman spectra of all the samples showed the characteristic bands at approximately 1580 and 1350 cm -1; however, a clear difference in position, width, and relative intensity could be observed for most of the samples. The resulting analysis showed that micro-Raman spectroscopy allowed the discrimination of most of the reference pigments and allowed the identification of carbon-based black pigments in two South American colonial paintings dated from the early 18th century. Copyright © 2012 John Wiley & Sons, Ltd.
publishDate 2012
dc.date.none.fl_str_mv 2012-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/69535
Tomasini, Eugenia Paula; Halac, Emilia Beatriz; Reinoso, Maria Elba; Di Liscia, Emiliano Javier; Maier, Marta Silvia; Micro-Raman spectroscopy of carbon-based black pigments; John Wiley & Sons Ltd; Journal Of Raman Spectroscopy; 43; 11; 11-2012; 1671-1675
0377-0486
CONICET Digital
CONICET
url http://hdl.handle.net/11336/69535
identifier_str_mv Tomasini, Eugenia Paula; Halac, Emilia Beatriz; Reinoso, Maria Elba; Di Liscia, Emiliano Javier; Maier, Marta Silvia; Micro-Raman spectroscopy of carbon-based black pigments; John Wiley & Sons Ltd; Journal Of Raman Spectroscopy; 43; 11; 11-2012; 1671-1675
0377-0486
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/jrs.4159
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/jrs.4159
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Ltd
publisher.none.fl_str_mv John Wiley & Sons Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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