The Sibyls from the church of San Pedro Telmo: a micro-Raman spectroscopic investigation

Autores
Marte, Fernando Daniel; Careaga Quiroga, Valeria Pilar; Mastrangelo, Noemi Elisa; Faria, Dalva L. A. de; Maier, Marta Silvia
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The series of the Sibyls from the church of San Pedro Telmo is one of the most important groups of paintings of Argentine colonial art. Ten of the paintings were performed in the 18th century, while those corresponding to the Delphic and Tiburtine Sibyls were painted in 1864 during the first restoration of the series in Buenos Aires. There is a controversy regarding the origin of this remarkable group of paintings pointing to an Andean workshop or a Spanish source. In this study, Raman microscopy in combination with scanning electron microscope energy-dispersive X-ray spectrometer analysis and HPLC has successfully identified the materials employed in the manufacture of the paintings. The Raman analysis revealed the presence of a mixture of barium sulfate, lead white, and calcite in the preparation layers of the 19th century Sibyls in contrast to the clayish ground layer in the 18th century paintings. Traditional pigments such as vermilion, lead white, orpiment, indigo, ultramarine blue, and Prussian blue were readily identified by Raman microscopy. The presence of a madder lake in one of the 18th century Sibyls strongly suggests their Spanish origin in accordance with historical data. The identification of synthetic ultramarine blue in the Tiburtine painting is the first report of this blue pigment in Argentine colonial art.
Fil: Marte, Fernando Daniel. Universidad Nacional de San Martín. Instituto de Investigaciones sobre el Patrimonio Cultural; Argentina
Fil: Careaga Quiroga, Valeria Pilar. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos en Química Orgánica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Unidad de Microanálisis y Métodos Físicos en Química Orgánica; Argentina
Fil: Mastrangelo, Noemi Elisa. Universidad Nacional de San Martín. Instituto de Investigaciones sobre el Patrimonio Cultural; Argentina
Fil: Faria, Dalva L. A. de. Universidade de Sao Paulo; Brasil
Fil: Maier, Marta Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos en Química Orgánica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Unidad de Microanálisis y Métodos Físicos en Química Orgánica; Argentina
Materia
Pigments
Micro-Raman Spectroscopy
Colonial Art
Hplc
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/30953
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/30953
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling The Sibyls from the church of San Pedro Telmo: a micro-Raman spectroscopic investigationMarte, Fernando DanielCareaga Quiroga, Valeria PilarMastrangelo, Noemi ElisaFaria, Dalva L. A. deMaier, Marta SilviaPigmentsMicro-Raman SpectroscopyColonial ArtHplchttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The series of the Sibyls from the church of San Pedro Telmo is one of the most important groups of paintings of Argentine colonial art. Ten of the paintings were performed in the 18th century, while those corresponding to the Delphic and Tiburtine Sibyls were painted in 1864 during the first restoration of the series in Buenos Aires. There is a controversy regarding the origin of this remarkable group of paintings pointing to an Andean workshop or a Spanish source. In this study, Raman microscopy in combination with scanning electron microscope energy-dispersive X-ray spectrometer analysis and HPLC has successfully identified the materials employed in the manufacture of the paintings. The Raman analysis revealed the presence of a mixture of barium sulfate, lead white, and calcite in the preparation layers of the 19th century Sibyls in contrast to the clayish ground layer in the 18th century paintings. Traditional pigments such as vermilion, lead white, orpiment, indigo, ultramarine blue, and Prussian blue were readily identified by Raman microscopy. The presence of a madder lake in one of the 18th century Sibyls strongly suggests their Spanish origin in accordance with historical data. The identification of synthetic ultramarine blue in the Tiburtine painting is the first report of this blue pigment in Argentine colonial art.Fil: Marte, Fernando Daniel. Universidad Nacional de San Martín. Instituto de Investigaciones sobre el Patrimonio Cultural; ArgentinaFil: Careaga Quiroga, Valeria Pilar. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos en Química Orgánica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Unidad de Microanálisis y Métodos Físicos en Química Orgánica; ArgentinaFil: Mastrangelo, Noemi Elisa. Universidad Nacional de San Martín. Instituto de Investigaciones sobre el Patrimonio Cultural; ArgentinaFil: Faria, Dalva L. A. de. Universidade de Sao Paulo; BrasilFil: Maier, Marta Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos en Química Orgánica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Unidad de Microanálisis y Métodos Físicos en Química Orgánica; ArgentinaWiley2014-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/30953Maier, Marta Silvia; Faria, Dalva L. A. de; Mastrangelo, Noemi Elisa; Careaga Quiroga, Valeria Pilar; Marte, Fernando Daniel; The Sibyls from the church of San Pedro Telmo: a micro-Raman spectroscopic investigation; Wiley; Journal Of Raman Spectroscopy; 45; 11-12; 11-2014; 1046-10510377-0486CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/jrs.4616info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/jrs.4616/abstractinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:51:44Zoai:ri.conicet.gov.ar:11336/30953instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:51:44.733CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv The Sibyls from the church of San Pedro Telmo: a micro-Raman spectroscopic investigation
title The Sibyls from the church of San Pedro Telmo: a micro-Raman spectroscopic investigation
spellingShingle The Sibyls from the church of San Pedro Telmo: a micro-Raman spectroscopic investigation
Marte, Fernando Daniel
Pigments
Micro-Raman Spectroscopy
Colonial Art
Hplc
title_short The Sibyls from the church of San Pedro Telmo: a micro-Raman spectroscopic investigation
title_full The Sibyls from the church of San Pedro Telmo: a micro-Raman spectroscopic investigation
title_fullStr The Sibyls from the church of San Pedro Telmo: a micro-Raman spectroscopic investigation
title_full_unstemmed The Sibyls from the church of San Pedro Telmo: a micro-Raman spectroscopic investigation
title_sort The Sibyls from the church of San Pedro Telmo: a micro-Raman spectroscopic investigation
dc.creator.none.fl_str_mv Marte, Fernando Daniel
Careaga Quiroga, Valeria Pilar
Mastrangelo, Noemi Elisa
Faria, Dalva L. A. de
Maier, Marta Silvia
author Marte, Fernando Daniel
author_facet Marte, Fernando Daniel
Careaga Quiroga, Valeria Pilar
Mastrangelo, Noemi Elisa
Faria, Dalva L. A. de
Maier, Marta Silvia
author_role author
author2 Careaga Quiroga, Valeria Pilar
Mastrangelo, Noemi Elisa
Faria, Dalva L. A. de
Maier, Marta Silvia
author2_role author
author
author
author
dc.subject.none.fl_str_mv Pigments
Micro-Raman Spectroscopy
Colonial Art
Hplc
topic Pigments
Micro-Raman Spectroscopy
Colonial Art
Hplc
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The series of the Sibyls from the church of San Pedro Telmo is one of the most important groups of paintings of Argentine colonial art. Ten of the paintings were performed in the 18th century, while those corresponding to the Delphic and Tiburtine Sibyls were painted in 1864 during the first restoration of the series in Buenos Aires. There is a controversy regarding the origin of this remarkable group of paintings pointing to an Andean workshop or a Spanish source. In this study, Raman microscopy in combination with scanning electron microscope energy-dispersive X-ray spectrometer analysis and HPLC has successfully identified the materials employed in the manufacture of the paintings. The Raman analysis revealed the presence of a mixture of barium sulfate, lead white, and calcite in the preparation layers of the 19th century Sibyls in contrast to the clayish ground layer in the 18th century paintings. Traditional pigments such as vermilion, lead white, orpiment, indigo, ultramarine blue, and Prussian blue were readily identified by Raman microscopy. The presence of a madder lake in one of the 18th century Sibyls strongly suggests their Spanish origin in accordance with historical data. The identification of synthetic ultramarine blue in the Tiburtine painting is the first report of this blue pigment in Argentine colonial art.
Fil: Marte, Fernando Daniel. Universidad Nacional de San Martín. Instituto de Investigaciones sobre el Patrimonio Cultural; Argentina
Fil: Careaga Quiroga, Valeria Pilar. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos en Química Orgánica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Unidad de Microanálisis y Métodos Físicos en Química Orgánica; Argentina
Fil: Mastrangelo, Noemi Elisa. Universidad Nacional de San Martín. Instituto de Investigaciones sobre el Patrimonio Cultural; Argentina
Fil: Faria, Dalva L. A. de. Universidade de Sao Paulo; Brasil
Fil: Maier, Marta Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos en Química Orgánica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Unidad de Microanálisis y Métodos Físicos en Química Orgánica; Argentina
description The series of the Sibyls from the church of San Pedro Telmo is one of the most important groups of paintings of Argentine colonial art. Ten of the paintings were performed in the 18th century, while those corresponding to the Delphic and Tiburtine Sibyls were painted in 1864 during the first restoration of the series in Buenos Aires. There is a controversy regarding the origin of this remarkable group of paintings pointing to an Andean workshop or a Spanish source. In this study, Raman microscopy in combination with scanning electron microscope energy-dispersive X-ray spectrometer analysis and HPLC has successfully identified the materials employed in the manufacture of the paintings. The Raman analysis revealed the presence of a mixture of barium sulfate, lead white, and calcite in the preparation layers of the 19th century Sibyls in contrast to the clayish ground layer in the 18th century paintings. Traditional pigments such as vermilion, lead white, orpiment, indigo, ultramarine blue, and Prussian blue were readily identified by Raman microscopy. The presence of a madder lake in one of the 18th century Sibyls strongly suggests their Spanish origin in accordance with historical data. The identification of synthetic ultramarine blue in the Tiburtine painting is the first report of this blue pigment in Argentine colonial art.
publishDate 2014
dc.date.none.fl_str_mv 2014-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/30953
Maier, Marta Silvia; Faria, Dalva L. A. de; Mastrangelo, Noemi Elisa; Careaga Quiroga, Valeria Pilar; Marte, Fernando Daniel; The Sibyls from the church of San Pedro Telmo: a micro-Raman spectroscopic investigation; Wiley; Journal Of Raman Spectroscopy; 45; 11-12; 11-2014; 1046-1051
0377-0486
CONICET Digital
CONICET
url http://hdl.handle.net/11336/30953
identifier_str_mv Maier, Marta Silvia; Faria, Dalva L. A. de; Mastrangelo, Noemi Elisa; Careaga Quiroga, Valeria Pilar; Marte, Fernando Daniel; The Sibyls from the church of San Pedro Telmo: a micro-Raman spectroscopic investigation; Wiley; Journal Of Raman Spectroscopy; 45; 11-12; 11-2014; 1046-1051
0377-0486
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/jrs.4616
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/jrs.4616/abstract
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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