On-field Raman spectroscopy of Patagonian prehistoric rock art: Pigments, alteration products and substrata

Autores
Rousaki, Anastasia; Vargas, Fernando Emmanuel; Vázquez, Cristina; Aldazabal, Veronica Beatriz; Bellelli, Cristina Teresa; Carballido Calatayud, Mariana; Hajduk, Adam; Palacios, Oscar Martín; Moens, Luc; Vandenabeele, Peter
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
An extensive in situ Raman spectroscopic campaign was performed on archaeological sites in three different provinces in Patagonia, Argentina (Neuquén, Río Negro and Chubut). 16 open air shelters located in different environments (forests, ecotones, steppes) were investigated and interpreted in terms of pigments used and the identification of substrata. Special attention was given to the alteration products and accretions that were found on the rock art paintings of the shelters and on the surface of the rock walls, as they can affect and damage this magnificent works of art. Haematite (α-Fe2O3) was the main chromophore that was found on the red paintings of the most of the shelters studied. The green earth glauconite, was identified only in one case, by using a red (785 nm) and a green laser (532 nm). Other minerals and silicates were found on the coloured areas but also on the rock support. Calcite (CaCO3) and gypsum (CaSO4 • 2H2O) crystallization was identified on the paintings, crusts and rock surfaces, in combination or alone, and are associated with weathering. In some cases the shelters were so severely degraded that no Raman signal of pigments and/or other components could be retrieved. Calcium oxalates were also detected in several figures and motifs in different shelters.
Fil: Rousaki, Anastasia. University of Ghent; Bélgica
Fil: Vargas, Fernando Emmanuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigaciones en Diversidad Cultural y Procesos de Cambio. Universidad Nacional de Río Negro. Instituto de Investigaciones en Diversidad Cultural y Procesos de Cambio; Argentina
Fil: Vázquez, Cristina. Comisión Nacional de Energía Atómica; Argentina. Universidad de Buenos Aires. Facultad de Ingeniería; Argentina
Fil: Aldazabal, Veronica Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Saavedra 15. Instituto Multidisciplinario de Historia y Ciencias Humanas; Argentina
Fil: Bellelli, Cristina Teresa. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Secretaría de Cultura de la Nación. Dirección Nacional de Cultura y Museos. Instituto Nacional de Antropología y Pensamiento Latinoamericano; Argentina
Fil: Carballido Calatayud, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Secretaría de Cultura de la Nación. Dirección Nacional de Cultura y Museos. Instituto Nacional de Antropología y Pensamiento Latinoamericano; Argentina. Universidad de Buenos Aires; Argentina
Fil: Hajduk, Adam. Administración de Parques Nacionales. Museo de la Patagonia "Francisco Perito Moreno"; Argentina
Fil: Palacios, Oscar Martín. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ingeniería; Argentina
Fil: Moens, Luc. University of Ghent; Bélgica
Fil: Vandenabeele, Peter. University of Ghent; Bélgica
Materia
DEGRADATION
IN SITU RAMAN SPECTROSCOPY
PATAGONIA
PIGMENT
ROCK ART
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/87443
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/87443
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling On-field Raman spectroscopy of Patagonian prehistoric rock art: Pigments, alteration products and substrataRousaki, AnastasiaVargas, Fernando EmmanuelVázquez, CristinaAldazabal, Veronica BeatrizBellelli, Cristina TeresaCarballido Calatayud, MarianaHajduk, AdamPalacios, Oscar MartínMoens, LucVandenabeele, PeterDEGRADATIONIN SITU RAMAN SPECTROSCOPYPATAGONIAPIGMENTROCK ARThttps://purl.org/becyt/ford/6.1https://purl.org/becyt/ford/6An extensive in situ Raman spectroscopic campaign was performed on archaeological sites in three different provinces in Patagonia, Argentina (Neuquén, Río Negro and Chubut). 16 open air shelters located in different environments (forests, ecotones, steppes) were investigated and interpreted in terms of pigments used and the identification of substrata. Special attention was given to the alteration products and accretions that were found on the rock art paintings of the shelters and on the surface of the rock walls, as they can affect and damage this magnificent works of art. Haematite (α-Fe2O3) was the main chromophore that was found on the red paintings of the most of the shelters studied. The green earth glauconite, was identified only in one case, by using a red (785 nm) and a green laser (532 nm). Other minerals and silicates were found on the coloured areas but also on the rock support. Calcite (CaCO3) and gypsum (CaSO4 • 2H2O) crystallization was identified on the paintings, crusts and rock surfaces, in combination or alone, and are associated with weathering. In some cases the shelters were so severely degraded that no Raman signal of pigments and/or other components could be retrieved. Calcium oxalates were also detected in several figures and motifs in different shelters.Fil: Rousaki, Anastasia. University of Ghent; BélgicaFil: Vargas, Fernando Emmanuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigaciones en Diversidad Cultural y Procesos de Cambio. Universidad Nacional de Río Negro. Instituto de Investigaciones en Diversidad Cultural y Procesos de Cambio; ArgentinaFil: Vázquez, Cristina. Comisión Nacional de Energía Atómica; Argentina. Universidad de Buenos Aires. Facultad de Ingeniería; ArgentinaFil: Aldazabal, Veronica Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Saavedra 15. Instituto Multidisciplinario de Historia y Ciencias Humanas; ArgentinaFil: Bellelli, Cristina Teresa. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Secretaría de Cultura de la Nación. Dirección Nacional de Cultura y Museos. Instituto Nacional de Antropología y Pensamiento Latinoamericano; ArgentinaFil: Carballido Calatayud, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Secretaría de Cultura de la Nación. Dirección Nacional de Cultura y Museos. Instituto Nacional de Antropología y Pensamiento Latinoamericano; Argentina. Universidad de Buenos Aires; ArgentinaFil: Hajduk, Adam. Administración de Parques Nacionales. Museo de la Patagonia "Francisco Perito Moreno"; ArgentinaFil: Palacios, Oscar Martín. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ingeniería; ArgentinaFil: Moens, Luc. University of Ghent; BélgicaFil: Vandenabeele, Peter. University of Ghent; BélgicaElsevier2018-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/87443Rousaki, Anastasia; Vargas, Fernando Emmanuel; Vázquez, Cristina; Aldazabal, Veronica Beatriz; Bellelli, Cristina Teresa; et al.; On-field Raman spectroscopy of Patagonian prehistoric rock art: Pigments, alteration products and substrata; Elsevier; Trac-Trends In Analytical Chemistry; 105; 8-2018; 338-3510165-9936CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0165993617304569info:eu-repo/semantics/altIdentifier/doi/10.1016/j.trac.2018.05.011info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:37:56Zoai:ri.conicet.gov.ar:11336/87443instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:37:57.184CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv On-field Raman spectroscopy of Patagonian prehistoric rock art: Pigments, alteration products and substrata
title On-field Raman spectroscopy of Patagonian prehistoric rock art: Pigments, alteration products and substrata
spellingShingle On-field Raman spectroscopy of Patagonian prehistoric rock art: Pigments, alteration products and substrata
Rousaki, Anastasia
DEGRADATION
IN SITU RAMAN SPECTROSCOPY
PATAGONIA
PIGMENT
ROCK ART
title_short On-field Raman spectroscopy of Patagonian prehistoric rock art: Pigments, alteration products and substrata
title_full On-field Raman spectroscopy of Patagonian prehistoric rock art: Pigments, alteration products and substrata
title_fullStr On-field Raman spectroscopy of Patagonian prehistoric rock art: Pigments, alteration products and substrata
title_full_unstemmed On-field Raman spectroscopy of Patagonian prehistoric rock art: Pigments, alteration products and substrata
title_sort On-field Raman spectroscopy of Patagonian prehistoric rock art: Pigments, alteration products and substrata
dc.creator.none.fl_str_mv Rousaki, Anastasia
Vargas, Fernando Emmanuel
Vázquez, Cristina
Aldazabal, Veronica Beatriz
Bellelli, Cristina Teresa
Carballido Calatayud, Mariana
Hajduk, Adam
Palacios, Oscar Martín
Moens, Luc
Vandenabeele, Peter
author Rousaki, Anastasia
author_facet Rousaki, Anastasia
Vargas, Fernando Emmanuel
Vázquez, Cristina
Aldazabal, Veronica Beatriz
Bellelli, Cristina Teresa
Carballido Calatayud, Mariana
Hajduk, Adam
Palacios, Oscar Martín
Moens, Luc
Vandenabeele, Peter
author_role author
author2 Vargas, Fernando Emmanuel
Vázquez, Cristina
Aldazabal, Veronica Beatriz
Bellelli, Cristina Teresa
Carballido Calatayud, Mariana
Hajduk, Adam
Palacios, Oscar Martín
Moens, Luc
Vandenabeele, Peter
author2_role author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv DEGRADATION
IN SITU RAMAN SPECTROSCOPY
PATAGONIA
PIGMENT
ROCK ART
topic DEGRADATION
IN SITU RAMAN SPECTROSCOPY
PATAGONIA
PIGMENT
ROCK ART
purl_subject.fl_str_mv https://purl.org/becyt/ford/6.1
https://purl.org/becyt/ford/6
dc.description.none.fl_txt_mv An extensive in situ Raman spectroscopic campaign was performed on archaeological sites in three different provinces in Patagonia, Argentina (Neuquén, Río Negro and Chubut). 16 open air shelters located in different environments (forests, ecotones, steppes) were investigated and interpreted in terms of pigments used and the identification of substrata. Special attention was given to the alteration products and accretions that were found on the rock art paintings of the shelters and on the surface of the rock walls, as they can affect and damage this magnificent works of art. Haematite (α-Fe2O3) was the main chromophore that was found on the red paintings of the most of the shelters studied. The green earth glauconite, was identified only in one case, by using a red (785 nm) and a green laser (532 nm). Other minerals and silicates were found on the coloured areas but also on the rock support. Calcite (CaCO3) and gypsum (CaSO4 • 2H2O) crystallization was identified on the paintings, crusts and rock surfaces, in combination or alone, and are associated with weathering. In some cases the shelters were so severely degraded that no Raman signal of pigments and/or other components could be retrieved. Calcium oxalates were also detected in several figures and motifs in different shelters.
Fil: Rousaki, Anastasia. University of Ghent; Bélgica
Fil: Vargas, Fernando Emmanuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigaciones en Diversidad Cultural y Procesos de Cambio. Universidad Nacional de Río Negro. Instituto de Investigaciones en Diversidad Cultural y Procesos de Cambio; Argentina
Fil: Vázquez, Cristina. Comisión Nacional de Energía Atómica; Argentina. Universidad de Buenos Aires. Facultad de Ingeniería; Argentina
Fil: Aldazabal, Veronica Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Saavedra 15. Instituto Multidisciplinario de Historia y Ciencias Humanas; Argentina
Fil: Bellelli, Cristina Teresa. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Secretaría de Cultura de la Nación. Dirección Nacional de Cultura y Museos. Instituto Nacional de Antropología y Pensamiento Latinoamericano; Argentina
Fil: Carballido Calatayud, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Secretaría de Cultura de la Nación. Dirección Nacional de Cultura y Museos. Instituto Nacional de Antropología y Pensamiento Latinoamericano; Argentina. Universidad de Buenos Aires; Argentina
Fil: Hajduk, Adam. Administración de Parques Nacionales. Museo de la Patagonia "Francisco Perito Moreno"; Argentina
Fil: Palacios, Oscar Martín. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ingeniería; Argentina
Fil: Moens, Luc. University of Ghent; Bélgica
Fil: Vandenabeele, Peter. University of Ghent; Bélgica
description An extensive in situ Raman spectroscopic campaign was performed on archaeological sites in three different provinces in Patagonia, Argentina (Neuquén, Río Negro and Chubut). 16 open air shelters located in different environments (forests, ecotones, steppes) were investigated and interpreted in terms of pigments used and the identification of substrata. Special attention was given to the alteration products and accretions that were found on the rock art paintings of the shelters and on the surface of the rock walls, as they can affect and damage this magnificent works of art. Haematite (α-Fe2O3) was the main chromophore that was found on the red paintings of the most of the shelters studied. The green earth glauconite, was identified only in one case, by using a red (785 nm) and a green laser (532 nm). Other minerals and silicates were found on the coloured areas but also on the rock support. Calcite (CaCO3) and gypsum (CaSO4 • 2H2O) crystallization was identified on the paintings, crusts and rock surfaces, in combination or alone, and are associated with weathering. In some cases the shelters were so severely degraded that no Raman signal of pigments and/or other components could be retrieved. Calcium oxalates were also detected in several figures and motifs in different shelters.
publishDate 2018
dc.date.none.fl_str_mv 2018-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/87443
Rousaki, Anastasia; Vargas, Fernando Emmanuel; Vázquez, Cristina; Aldazabal, Veronica Beatriz; Bellelli, Cristina Teresa; et al.; On-field Raman spectroscopy of Patagonian prehistoric rock art: Pigments, alteration products and substrata; Elsevier; Trac-Trends In Analytical Chemistry; 105; 8-2018; 338-351
0165-9936
CONICET Digital
CONICET
url http://hdl.handle.net/11336/87443
identifier_str_mv Rousaki, Anastasia; Vargas, Fernando Emmanuel; Vázquez, Cristina; Aldazabal, Veronica Beatriz; Bellelli, Cristina Teresa; et al.; On-field Raman spectroscopy of Patagonian prehistoric rock art: Pigments, alteration products and substrata; Elsevier; Trac-Trends In Analytical Chemistry; 105; 8-2018; 338-351
0165-9936
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0165993617304569
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.trac.2018.05.011
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.891075

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