Spectroscopic, morphological and chemical characterization of historic pigments based on carbon. Paths for the identification of an artistic pigment

Autores
Tomasini, Eugenia Paula; Siracusano, Gabriela Silvana; Maier, Marta Silvia
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Analytical characterization of reference carbon-based black pigments has been performed using Fourier transform infrared spectroscopy (FTIR) with attenuated total reflectance (ATR) and scanning electron microscopy (SEM) coupled to an energy-dispersive X-ray spectrometer (EDS). The unambiguous identification of these pigments, which are found in paintings, rock art and archeological artifacts, still remains a big challenge due to the variety of sources and manufacturing processes used in their preparation. The analytical results achieved in this study allowed us to discriminate between carbon-based pigments from different sources and detect adulterations. The methodological approach was successfully applied to the identification of vegetable charcoal and bone black in two colonial paintings dated from the eighteenth century. Conclusions regarding the pictorial techniques were drawn from FTIR data.
Fil: Tomasini, Eugenia Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos en Química Orgánica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Unidad de Microanálisis y Métodos Físicos en Química Orgánica; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina
Fil: Siracusano, Gabriela Silvana. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín; Argentina
Fil: Maier, Marta Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos en Química Orgánica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Unidad de Microanálisis y Métodos Físicos en Química Orgánica; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina
Materia
ATR
CARBON BLACK
CARBON-BASED PIGMENTS
COLONIAL ART
FTIR
SEM-EDS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/85156
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Spectroscopic, morphological and chemical characterization of historic pigments based on carbon. Paths for the identification of an artistic pigmentTomasini, Eugenia PaulaSiracusano, Gabriela SilvanaMaier, Marta SilviaATRCARBON BLACKCARBON-BASED PIGMENTSCOLONIAL ARTFTIRSEM-EDShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/6.4https://purl.org/becyt/ford/6Analytical characterization of reference carbon-based black pigments has been performed using Fourier transform infrared spectroscopy (FTIR) with attenuated total reflectance (ATR) and scanning electron microscopy (SEM) coupled to an energy-dispersive X-ray spectrometer (EDS). The unambiguous identification of these pigments, which are found in paintings, rock art and archeological artifacts, still remains a big challenge due to the variety of sources and manufacturing processes used in their preparation. The analytical results achieved in this study allowed us to discriminate between carbon-based pigments from different sources and detect adulterations. The methodological approach was successfully applied to the identification of vegetable charcoal and bone black in two colonial paintings dated from the eighteenth century. Conclusions regarding the pictorial techniques were drawn from FTIR data.Fil: Tomasini, Eugenia Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos en Química Orgánica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Unidad de Microanálisis y Métodos Físicos en Química Orgánica; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; ArgentinaFil: Siracusano, Gabriela Silvana. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín; ArgentinaFil: Maier, Marta Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos en Química Orgánica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Unidad de Microanálisis y Métodos Físicos en Química Orgánica; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; ArgentinaElsevier Science2012-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/85156Tomasini, Eugenia Paula; Siracusano, Gabriela Silvana; Maier, Marta Silvia; Spectroscopic, morphological and chemical characterization of historic pigments based on carbon. Paths for the identification of an artistic pigment; Elsevier Science; Microchemical Journal; 102; 5-2012; 28-370026-265XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0026265X11002141info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2011.11.005info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:07:27Zoai:ri.conicet.gov.ar:11336/85156instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:07:27.359CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Spectroscopic, morphological and chemical characterization of historic pigments based on carbon. Paths for the identification of an artistic pigment
title Spectroscopic, morphological and chemical characterization of historic pigments based on carbon. Paths for the identification of an artistic pigment
spellingShingle Spectroscopic, morphological and chemical characterization of historic pigments based on carbon. Paths for the identification of an artistic pigment
Tomasini, Eugenia Paula
ATR
CARBON BLACK
CARBON-BASED PIGMENTS
COLONIAL ART
FTIR
SEM-EDS
title_short Spectroscopic, morphological and chemical characterization of historic pigments based on carbon. Paths for the identification of an artistic pigment
title_full Spectroscopic, morphological and chemical characterization of historic pigments based on carbon. Paths for the identification of an artistic pigment
title_fullStr Spectroscopic, morphological and chemical characterization of historic pigments based on carbon. Paths for the identification of an artistic pigment
title_full_unstemmed Spectroscopic, morphological and chemical characterization of historic pigments based on carbon. Paths for the identification of an artistic pigment
title_sort Spectroscopic, morphological and chemical characterization of historic pigments based on carbon. Paths for the identification of an artistic pigment
dc.creator.none.fl_str_mv Tomasini, Eugenia Paula
Siracusano, Gabriela Silvana
Maier, Marta Silvia
author Tomasini, Eugenia Paula
author_facet Tomasini, Eugenia Paula
Siracusano, Gabriela Silvana
Maier, Marta Silvia
author_role author
author2 Siracusano, Gabriela Silvana
Maier, Marta Silvia
author2_role author
author
dc.subject.none.fl_str_mv ATR
CARBON BLACK
CARBON-BASED PIGMENTS
COLONIAL ART
FTIR
SEM-EDS
topic ATR
CARBON BLACK
CARBON-BASED PIGMENTS
COLONIAL ART
FTIR
SEM-EDS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/6.4
https://purl.org/becyt/ford/6
dc.description.none.fl_txt_mv Analytical characterization of reference carbon-based black pigments has been performed using Fourier transform infrared spectroscopy (FTIR) with attenuated total reflectance (ATR) and scanning electron microscopy (SEM) coupled to an energy-dispersive X-ray spectrometer (EDS). The unambiguous identification of these pigments, which are found in paintings, rock art and archeological artifacts, still remains a big challenge due to the variety of sources and manufacturing processes used in their preparation. The analytical results achieved in this study allowed us to discriminate between carbon-based pigments from different sources and detect adulterations. The methodological approach was successfully applied to the identification of vegetable charcoal and bone black in two colonial paintings dated from the eighteenth century. Conclusions regarding the pictorial techniques were drawn from FTIR data.
Fil: Tomasini, Eugenia Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos en Química Orgánica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Unidad de Microanálisis y Métodos Físicos en Química Orgánica; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina
Fil: Siracusano, Gabriela Silvana. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín; Argentina
Fil: Maier, Marta Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos en Química Orgánica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Unidad de Microanálisis y Métodos Físicos en Química Orgánica; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina
description Analytical characterization of reference carbon-based black pigments has been performed using Fourier transform infrared spectroscopy (FTIR) with attenuated total reflectance (ATR) and scanning electron microscopy (SEM) coupled to an energy-dispersive X-ray spectrometer (EDS). The unambiguous identification of these pigments, which are found in paintings, rock art and archeological artifacts, still remains a big challenge due to the variety of sources and manufacturing processes used in their preparation. The analytical results achieved in this study allowed us to discriminate between carbon-based pigments from different sources and detect adulterations. The methodological approach was successfully applied to the identification of vegetable charcoal and bone black in two colonial paintings dated from the eighteenth century. Conclusions regarding the pictorial techniques were drawn from FTIR data.
publishDate 2012
dc.date.none.fl_str_mv 2012-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/85156
Tomasini, Eugenia Paula; Siracusano, Gabriela Silvana; Maier, Marta Silvia; Spectroscopic, morphological and chemical characterization of historic pigments based on carbon. Paths for the identification of an artistic pigment; Elsevier Science; Microchemical Journal; 102; 5-2012; 28-37
0026-265X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/85156
identifier_str_mv Tomasini, Eugenia Paula; Siracusano, Gabriela Silvana; Maier, Marta Silvia; Spectroscopic, morphological and chemical characterization of historic pigments based on carbon. Paths for the identification of an artistic pigment; Elsevier Science; Microchemical Journal; 102; 5-2012; 28-37
0026-265X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0026265X11002141
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2011.11.005
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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