A flexible mixing rule satisfying the ideal-solution limit for equations of state

Autores
Zabaloy, Marcelo Santiago; Brignole, Esteban Alberto; Vera, Juan H.
Año de publicación
2002
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
While the ideal solution is an important reference for the thermodynamic modeling of mixtures, the one-fluid approach for equations of state (EOSs) fails to meet this limit. In this work we present additional evidence supporting this fact. A conceptually new treatment previously proposed for EOSs that meets the ideal solution limit at zero values for the interaction parameters is further developed here. A flexible composition dependence is proposed to cover the entire spectrum from symmetrical to highly asymmetrical, highly nonideal, mixtures. The new composition dependence gives the ideal solution limit, and it accounts for the effect of density on the excess properties of nonideal mixtures. The model treats vapor and liquid phases using a single formalism. For vapor-liquid equilibrium calculations, the new mixing rule can be considered as a hybrid between the well-known φ-φ and γ-φ approaches.
Fil: Zabaloy, Marcelo Santiago. McGill University; Canadá. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Brignole, Esteban Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Vera, Juan H.. McGill University; Canadá
Materia
Equation of State
Mixing Rules
Ideal Solution Limit
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/38069
Acceder
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network_name_str CONICET Digital (CONICET)
spelling A flexible mixing rule satisfying the ideal-solution limit for equations of stateZabaloy, Marcelo SantiagoBrignole, Esteban AlbertoVera, Juan H.Equation of StateMixing RulesIdeal Solution Limithttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2While the ideal solution is an important reference for the thermodynamic modeling of mixtures, the one-fluid approach for equations of state (EOSs) fails to meet this limit. In this work we present additional evidence supporting this fact. A conceptually new treatment previously proposed for EOSs that meets the ideal solution limit at zero values for the interaction parameters is further developed here. A flexible composition dependence is proposed to cover the entire spectrum from symmetrical to highly asymmetrical, highly nonideal, mixtures. The new composition dependence gives the ideal solution limit, and it accounts for the effect of density on the excess properties of nonideal mixtures. The model treats vapor and liquid phases using a single formalism. For vapor-liquid equilibrium calculations, the new mixing rule can be considered as a hybrid between the well-known φ-φ and γ-φ approaches.Fil: Zabaloy, Marcelo Santiago. McGill University; Canadá. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Brignole, Esteban Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Vera, Juan H.. McGill University; CanadáAmerican Chemical Society2002-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/38069Zabaloy, Marcelo Santiago; Brignole, Esteban Alberto; Vera, Juan H.; A flexible mixing rule satisfying the ideal-solution limit for equations of state; American Chemical Society; Industrial & Engineering Chemical Research; 41; 5; 3-2002; 922-9300888-5885CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ie0101184info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/ie0101184info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:45:50Zoai:ri.conicet.gov.ar:11336/38069instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:45:51.054CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A flexible mixing rule satisfying the ideal-solution limit for equations of state
title A flexible mixing rule satisfying the ideal-solution limit for equations of state
spellingShingle A flexible mixing rule satisfying the ideal-solution limit for equations of state
Zabaloy, Marcelo Santiago
Equation of State
Mixing Rules
Ideal Solution Limit
title_short A flexible mixing rule satisfying the ideal-solution limit for equations of state
title_full A flexible mixing rule satisfying the ideal-solution limit for equations of state
title_fullStr A flexible mixing rule satisfying the ideal-solution limit for equations of state
title_full_unstemmed A flexible mixing rule satisfying the ideal-solution limit for equations of state
title_sort A flexible mixing rule satisfying the ideal-solution limit for equations of state
dc.creator.none.fl_str_mv Zabaloy, Marcelo Santiago
Brignole, Esteban Alberto
Vera, Juan H.
author Zabaloy, Marcelo Santiago
author_facet Zabaloy, Marcelo Santiago
Brignole, Esteban Alberto
Vera, Juan H.
author_role author
author2 Brignole, Esteban Alberto
Vera, Juan H.
author2_role author
author
dc.subject.none.fl_str_mv Equation of State
Mixing Rules
Ideal Solution Limit
topic Equation of State
Mixing Rules
Ideal Solution Limit
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv While the ideal solution is an important reference for the thermodynamic modeling of mixtures, the one-fluid approach for equations of state (EOSs) fails to meet this limit. In this work we present additional evidence supporting this fact. A conceptually new treatment previously proposed for EOSs that meets the ideal solution limit at zero values for the interaction parameters is further developed here. A flexible composition dependence is proposed to cover the entire spectrum from symmetrical to highly asymmetrical, highly nonideal, mixtures. The new composition dependence gives the ideal solution limit, and it accounts for the effect of density on the excess properties of nonideal mixtures. The model treats vapor and liquid phases using a single formalism. For vapor-liquid equilibrium calculations, the new mixing rule can be considered as a hybrid between the well-known φ-φ and γ-φ approaches.
Fil: Zabaloy, Marcelo Santiago. McGill University; Canadá. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Brignole, Esteban Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Vera, Juan H.. McGill University; Canadá
description While the ideal solution is an important reference for the thermodynamic modeling of mixtures, the one-fluid approach for equations of state (EOSs) fails to meet this limit. In this work we present additional evidence supporting this fact. A conceptually new treatment previously proposed for EOSs that meets the ideal solution limit at zero values for the interaction parameters is further developed here. A flexible composition dependence is proposed to cover the entire spectrum from symmetrical to highly asymmetrical, highly nonideal, mixtures. The new composition dependence gives the ideal solution limit, and it accounts for the effect of density on the excess properties of nonideal mixtures. The model treats vapor and liquid phases using a single formalism. For vapor-liquid equilibrium calculations, the new mixing rule can be considered as a hybrid between the well-known φ-φ and γ-φ approaches.
publishDate 2002
dc.date.none.fl_str_mv 2002-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/38069
Zabaloy, Marcelo Santiago; Brignole, Esteban Alberto; Vera, Juan H.; A flexible mixing rule satisfying the ideal-solution limit for equations of state; American Chemical Society; Industrial & Engineering Chemical Research; 41; 5; 3-2002; 922-930
0888-5885
CONICET Digital
CONICET
url http://hdl.handle.net/11336/38069
identifier_str_mv Zabaloy, Marcelo Santiago; Brignole, Esteban Alberto; Vera, Juan H.; A flexible mixing rule satisfying the ideal-solution limit for equations of state; American Chemical Society; Industrial & Engineering Chemical Research; 41; 5; 3-2002; 922-930
0888-5885
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/ie0101184
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/ie0101184
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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