Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States

Autores
Minari, Roque Javier; Gugliotta, Luis Marcelino; Vega, Jorge Ruben; Meira, Gregorio Raul
Año de publicación
2006
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The industrial production of two styrene-butadiene rubber (SBR) grades is optimized by means of arepresentative mathematical model. The emulsion process involves a train of seven continuously stirred-tankreactors. In the simulations, intermediate feeds of comonomers and chain transfer agent (CTA) are admitted.The steady-state (SS) productions can be increased by aprox 8%, while maintaining the required final values ofconversion, particle diameter, and molecular characteristics (Mh n, Mh w, and the average number of branchesper molecule). For the same rubber grade, the polymer production can be changed with negligible generationof intermediate off-specs, by regulating the global calorimetric conversion. For changes of grade at a fixedpolymer production, transient profiles of the intermediate CTA feeds are proposed. For changes of productionand grade, a sequential (rather than a simultaneous) transition seems preferable.
Fil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/20890
Acceder
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spelling Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady StatesMinari, Roque JavierGugliotta, Luis MarcelinoVega, Jorge RubenMeira, Gregorio Raulhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The industrial production of two styrene-butadiene rubber (SBR) grades is optimized by means of arepresentative mathematical model. The emulsion process involves a train of seven continuously stirred-tankreactors. In the simulations, intermediate feeds of comonomers and chain transfer agent (CTA) are admitted.The steady-state (SS) productions can be increased by aprox 8%, while maintaining the required final values ofconversion, particle diameter, and molecular characteristics (Mh n, Mh w, and the average number of branchesper molecule). For the same rubber grade, the polymer production can be changed with negligible generationof intermediate off-specs, by regulating the global calorimetric conversion. For changes of grade at a fixedpolymer production, transient profiles of the intermediate CTA feeds are proposed. For changes of productionand grade, a sequential (rather than a simultaneous) transition seems preferable.Fil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaAmerican Chemical Society2006-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/20890Minari, Roque Javier; Gugliotta, Luis Marcelino; Vega, Jorge Ruben; Meira, Gregorio Raul; Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States; American Chemical Society; Industrial & Engineering Chemical Research; 45; 1; 12-2006; 245-2570888-5885CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ie0504755info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/ie0504755info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T12:07:00Zoai:ri.conicet.gov.ar:11336/20890instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 12:07:00.324CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States
title Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States
spellingShingle Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States
Minari, Roque Javier
title_short Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States
title_full Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States
title_fullStr Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States
title_full_unstemmed Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States
title_sort Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States
dc.creator.none.fl_str_mv Minari, Roque Javier
Gugliotta, Luis Marcelino
Vega, Jorge Ruben
Meira, Gregorio Raul
author Minari, Roque Javier
author_facet Minari, Roque Javier
Gugliotta, Luis Marcelino
Vega, Jorge Ruben
Meira, Gregorio Raul
author_role author
author2 Gugliotta, Luis Marcelino
Vega, Jorge Ruben
Meira, Gregorio Raul
author2_role author
author
author
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The industrial production of two styrene-butadiene rubber (SBR) grades is optimized by means of arepresentative mathematical model. The emulsion process involves a train of seven continuously stirred-tankreactors. In the simulations, intermediate feeds of comonomers and chain transfer agent (CTA) are admitted.The steady-state (SS) productions can be increased by aprox 8%, while maintaining the required final values ofconversion, particle diameter, and molecular characteristics (Mh n, Mh w, and the average number of branchesper molecule). For the same rubber grade, the polymer production can be changed with negligible generationof intermediate off-specs, by regulating the global calorimetric conversion. For changes of grade at a fixedpolymer production, transient profiles of the intermediate CTA feeds are proposed. For changes of productionand grade, a sequential (rather than a simultaneous) transition seems preferable.
Fil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
description The industrial production of two styrene-butadiene rubber (SBR) grades is optimized by means of arepresentative mathematical model. The emulsion process involves a train of seven continuously stirred-tankreactors. In the simulations, intermediate feeds of comonomers and chain transfer agent (CTA) are admitted.The steady-state (SS) productions can be increased by aprox 8%, while maintaining the required final values ofconversion, particle diameter, and molecular characteristics (Mh n, Mh w, and the average number of branchesper molecule). For the same rubber grade, the polymer production can be changed with negligible generationof intermediate off-specs, by regulating the global calorimetric conversion. For changes of grade at a fixedpolymer production, transient profiles of the intermediate CTA feeds are proposed. For changes of productionand grade, a sequential (rather than a simultaneous) transition seems preferable.
publishDate 2006
dc.date.none.fl_str_mv 2006-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/20890
Minari, Roque Javier; Gugliotta, Luis Marcelino; Vega, Jorge Ruben; Meira, Gregorio Raul; Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States; American Chemical Society; Industrial & Engineering Chemical Research; 45; 1; 12-2006; 245-257
0888-5885
CONICET Digital
CONICET
url http://hdl.handle.net/11336/20890
identifier_str_mv Minari, Roque Javier; Gugliotta, Luis Marcelino; Vega, Jorge Ruben; Meira, Gregorio Raul; Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States; American Chemical Society; Industrial & Engineering Chemical Research; 45; 1; 12-2006; 245-257
0888-5885
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/ie0504755
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/ie0504755
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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