Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States
- Autores
- Minari, Roque Javier; Gugliotta, Luis Marcelino; Vega, Jorge Ruben; Meira, Gregorio Raul
- Año de publicación
- 2006
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The industrial production of two styrene-butadiene rubber (SBR) grades is optimized by means of arepresentative mathematical model. The emulsion process involves a train of seven continuously stirred-tankreactors. In the simulations, intermediate feeds of comonomers and chain transfer agent (CTA) are admitted.The steady-state (SS) productions can be increased by aprox 8%, while maintaining the required final values ofconversion, particle diameter, and molecular characteristics (Mh n, Mh w, and the average number of branchesper molecule). For the same rubber grade, the polymer production can be changed with negligible generationof intermediate off-specs, by regulating the global calorimetric conversion. For changes of grade at a fixedpolymer production, transient profiles of the intermediate CTA feeds are proposed. For changes of productionand grade, a sequential (rather than a simultaneous) transition seems preferable.
Fil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/20890
Ver los metadatos del registro completo
id |
CONICETDig_8f724d63767e4605ed74bc8e94e27e9c |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/20890 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady StatesMinari, Roque JavierGugliotta, Luis MarcelinoVega, Jorge RubenMeira, Gregorio Raulhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The industrial production of two styrene-butadiene rubber (SBR) grades is optimized by means of arepresentative mathematical model. The emulsion process involves a train of seven continuously stirred-tankreactors. In the simulations, intermediate feeds of comonomers and chain transfer agent (CTA) are admitted.The steady-state (SS) productions can be increased by aprox 8%, while maintaining the required final values ofconversion, particle diameter, and molecular characteristics (Mh n, Mh w, and the average number of branchesper molecule). For the same rubber grade, the polymer production can be changed with negligible generationof intermediate off-specs, by regulating the global calorimetric conversion. For changes of grade at a fixedpolymer production, transient profiles of the intermediate CTA feeds are proposed. For changes of productionand grade, a sequential (rather than a simultaneous) transition seems preferable.Fil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaAmerican Chemical Society2006-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/20890Minari, Roque Javier; Gugliotta, Luis Marcelino; Vega, Jorge Ruben; Meira, Gregorio Raul; Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States; American Chemical Society; Industrial & Engineering Chemical Research; 45; 1; 12-2006; 245-2570888-5885CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ie0504755info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/ie0504755info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:34:32Zoai:ri.conicet.gov.ar:11336/20890instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:34:32.519CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States |
title |
Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States |
spellingShingle |
Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States Minari, Roque Javier |
title_short |
Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States |
title_full |
Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States |
title_fullStr |
Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States |
title_full_unstemmed |
Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States |
title_sort |
Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States |
dc.creator.none.fl_str_mv |
Minari, Roque Javier Gugliotta, Luis Marcelino Vega, Jorge Ruben Meira, Gregorio Raul |
author |
Minari, Roque Javier |
author_facet |
Minari, Roque Javier Gugliotta, Luis Marcelino Vega, Jorge Ruben Meira, Gregorio Raul |
author_role |
author |
author2 |
Gugliotta, Luis Marcelino Vega, Jorge Ruben Meira, Gregorio Raul |
author2_role |
author author author |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The industrial production of two styrene-butadiene rubber (SBR) grades is optimized by means of arepresentative mathematical model. The emulsion process involves a train of seven continuously stirred-tankreactors. In the simulations, intermediate feeds of comonomers and chain transfer agent (CTA) are admitted.The steady-state (SS) productions can be increased by aprox 8%, while maintaining the required final values ofconversion, particle diameter, and molecular characteristics (Mh n, Mh w, and the average number of branchesper molecule). For the same rubber grade, the polymer production can be changed with negligible generationof intermediate off-specs, by regulating the global calorimetric conversion. For changes of grade at a fixedpolymer production, transient profiles of the intermediate CTA feeds are proposed. For changes of productionand grade, a sequential (rather than a simultaneous) transition seems preferable. Fil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina Fil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina Fil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina Fil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina |
description |
The industrial production of two styrene-butadiene rubber (SBR) grades is optimized by means of arepresentative mathematical model. The emulsion process involves a train of seven continuously stirred-tankreactors. In the simulations, intermediate feeds of comonomers and chain transfer agent (CTA) are admitted.The steady-state (SS) productions can be increased by aprox 8%, while maintaining the required final values ofconversion, particle diameter, and molecular characteristics (Mh n, Mh w, and the average number of branchesper molecule). For the same rubber grade, the polymer production can be changed with negligible generationof intermediate off-specs, by regulating the global calorimetric conversion. For changes of grade at a fixedpolymer production, transient profiles of the intermediate CTA feeds are proposed. For changes of productionand grade, a sequential (rather than a simultaneous) transition seems preferable. |
publishDate |
2006 |
dc.date.none.fl_str_mv |
2006-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/20890 Minari, Roque Javier; Gugliotta, Luis Marcelino; Vega, Jorge Ruben; Meira, Gregorio Raul; Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States; American Chemical Society; Industrial & Engineering Chemical Research; 45; 1; 12-2006; 245-257 0888-5885 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/20890 |
identifier_str_mv |
Minari, Roque Javier; Gugliotta, Luis Marcelino; Vega, Jorge Ruben; Meira, Gregorio Raul; Continuous Emulsion Process for the Production of SBR: Computer Simulation Study for Increasing the Steady Production and for Reducing the Transients between Steady States; American Chemical Society; Industrial & Engineering Chemical Research; 45; 1; 12-2006; 245-257 0888-5885 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1021/ie0504755 info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/ie0504755 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844614362714603520 |
score |
13.070432 |