Reduction of Transients between Steady States in the Continuous Production of High-Impact Polystyrene

Autores
Luciani, Carla Vanesa; Estenoz, Diana Alejandra; Meira, Gregorio Raul; Oliva, Haydée M.
Año de publicación
2005
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This work theoretically investigates the reduction of transients during changes of grade in a continuous plant for the production of high-impact polystyrene (HIPS). A mathematical model was developed that predicts the global molecular structure and the melt flow index (MFI). The switching times of the off-specs accumulation period were selected on the basis of the admissible MFI ranges. Smoother transitions and reduced off-specs can be produced through a simple readjustment (with respect to the original plant policy) of the two intermediate chain transfer agent (CTA) loads into the batch dissolver. For the transitions that involve a large difference in their MFIs, the off-specs can be reduced by 60%, with respect to the original plant policy, by including a transient feed of CTA into an intermediate stirred reactor.
Fil: Luciani, Carla Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Estenoz, Diana Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Oliva, Haydée M.. Universidad del Zulia; Venezuela
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/26628
Acceder
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spelling Reduction of Transients between Steady States in the Continuous Production of High-Impact PolystyreneLuciani, Carla VanesaEstenoz, Diana AlejandraMeira, Gregorio RaulOliva, Haydée M.https://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2This work theoretically investigates the reduction of transients during changes of grade in a continuous plant for the production of high-impact polystyrene (HIPS). A mathematical model was developed that predicts the global molecular structure and the melt flow index (MFI). The switching times of the off-specs accumulation period were selected on the basis of the admissible MFI ranges. Smoother transitions and reduced off-specs can be produced through a simple readjustment (with respect to the original plant policy) of the two intermediate chain transfer agent (CTA) loads into the batch dissolver. For the transitions that involve a large difference in their MFIs, the off-specs can be reduced by 60%, with respect to the original plant policy, by including a transient feed of CTA into an intermediate stirred reactor.Fil: Luciani, Carla Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Estenoz, Diana Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Oliva, Haydée M.. Universidad del Zulia; VenezuelaAmerican Chemical Society2005-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/26628Luciani, Carla Vanesa; Estenoz, Diana Alejandra; Meira, Gregorio Raul; Oliva, Haydée M.; Reduction of Transients between Steady States in the Continuous Production of High-Impact Polystyrene; American Chemical Society; Industrial & Engineering Chemical Research; 44; 22; 12-2005; 8354-83670888-5885CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ie050657zinfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/ie050657zinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:37:27Zoai:ri.conicet.gov.ar:11336/26628instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:37:28.213CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Reduction of Transients between Steady States in the Continuous Production of High-Impact Polystyrene
title Reduction of Transients between Steady States in the Continuous Production of High-Impact Polystyrene
spellingShingle Reduction of Transients between Steady States in the Continuous Production of High-Impact Polystyrene
Luciani, Carla Vanesa
title_short Reduction of Transients between Steady States in the Continuous Production of High-Impact Polystyrene
title_full Reduction of Transients between Steady States in the Continuous Production of High-Impact Polystyrene
title_fullStr Reduction of Transients between Steady States in the Continuous Production of High-Impact Polystyrene
title_full_unstemmed Reduction of Transients between Steady States in the Continuous Production of High-Impact Polystyrene
title_sort Reduction of Transients between Steady States in the Continuous Production of High-Impact Polystyrene
dc.creator.none.fl_str_mv Luciani, Carla Vanesa
Estenoz, Diana Alejandra
Meira, Gregorio Raul
Oliva, Haydée M.
author Luciani, Carla Vanesa
author_facet Luciani, Carla Vanesa
Estenoz, Diana Alejandra
Meira, Gregorio Raul
Oliva, Haydée M.
author_role author
author2 Estenoz, Diana Alejandra
Meira, Gregorio Raul
Oliva, Haydée M.
author2_role author
author
author
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv This work theoretically investigates the reduction of transients during changes of grade in a continuous plant for the production of high-impact polystyrene (HIPS). A mathematical model was developed that predicts the global molecular structure and the melt flow index (MFI). The switching times of the off-specs accumulation period were selected on the basis of the admissible MFI ranges. Smoother transitions and reduced off-specs can be produced through a simple readjustment (with respect to the original plant policy) of the two intermediate chain transfer agent (CTA) loads into the batch dissolver. For the transitions that involve a large difference in their MFIs, the off-specs can be reduced by 60%, with respect to the original plant policy, by including a transient feed of CTA into an intermediate stirred reactor.
Fil: Luciani, Carla Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Estenoz, Diana Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Oliva, Haydée M.. Universidad del Zulia; Venezuela
description This work theoretically investigates the reduction of transients during changes of grade in a continuous plant for the production of high-impact polystyrene (HIPS). A mathematical model was developed that predicts the global molecular structure and the melt flow index (MFI). The switching times of the off-specs accumulation period were selected on the basis of the admissible MFI ranges. Smoother transitions and reduced off-specs can be produced through a simple readjustment (with respect to the original plant policy) of the two intermediate chain transfer agent (CTA) loads into the batch dissolver. For the transitions that involve a large difference in their MFIs, the off-specs can be reduced by 60%, with respect to the original plant policy, by including a transient feed of CTA into an intermediate stirred reactor.
publishDate 2005
dc.date.none.fl_str_mv 2005-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/26628
Luciani, Carla Vanesa; Estenoz, Diana Alejandra; Meira, Gregorio Raul; Oliva, Haydée M.; Reduction of Transients between Steady States in the Continuous Production of High-Impact Polystyrene; American Chemical Society; Industrial & Engineering Chemical Research; 44; 22; 12-2005; 8354-8367
0888-5885
CONICET Digital
CONICET
url http://hdl.handle.net/11336/26628
identifier_str_mv Luciani, Carla Vanesa; Estenoz, Diana Alejandra; Meira, Gregorio Raul; Oliva, Haydée M.; Reduction of Transients between Steady States in the Continuous Production of High-Impact Polystyrene; American Chemical Society; Industrial & Engineering Chemical Research; 44; 22; 12-2005; 8354-8367
0888-5885
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/ie050657z
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/ie050657z
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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