Multidimensional voltammetry: Four-way multivariate calibration with third-order differential pulse voltammetric data for multi-analyte quantification in the presence of uncalibrat...

Autores
Jalalvand, Ali R.; Gholivand, Mohammad Bagher; Goicoechea, Hector Casimiro
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A four-way multivariate calibration approach based on the combination of differential pulse voltammetric (DPV) data and four-way algorithms is described for the first time. To achieve this goal, the DPV response of each sample was recorded thirty-six times. Six current-potential matrices were recorded at six different pulse durations. Each matrix consists of six vectors which have been recorded at six different pulse heights. The three-way data array obtained for the calibration set and for each of the test samples were joined into a single four-way data array. The recorded four-way data array was nonlinear, thus, the non-linearities were tackled by potential shift correction using correlation-optimized warping (COW) algorithm and subsequently was analyzed with unfolded-partial least squares/residual trilinearization (U-PLS/RTL) and multi-way-PLS/RTL (N-PLS/RTL) as third-order multivariate calibration algorithms. A comprehensive and systematic strategy for comparing the performance of the two algorithms was presented in this work, in particular with a view of practical applications. This comparison was developed to identify which algorithm offers the best predictions for the simultaneous determination of levodopa (LD), carbidopa (CD), methyldopa (MD), acetaminophen (AC), tramadol (TRA), lidocaine (LC), tolperisone (TOP), ofloxacin (OF), levofloxacin (LOF), and norfloxacin (NOF) in the presence of benserazide (BA), dopamine (DP), and ciprofloxacin (COF) as uncalibrated interferences using a multi-walled carbon nanotubes modified glassy carbon electrode (MWCNTs/GCE). This study demonstrated the more superiority of U-PLS/RTL to resolve the complex systems. The results of applying U-PLS/RTL for the simultaneous determination of the studied analytes in human serum samples as experimental cases were also encouraging.
Fil: Jalalvand, Ali R.. Razi University. Faculty of Chemistry. Department of Analytical Chemistry; Irán. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química. Área Química Analítica; Argentina
Fil: Gholivand, Mohammad Bagher. Razi University. Faculty of Chemistry. Department of Analytical Chemistry; Irán
Fil: Goicoechea, Hector Casimiro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química. Área Química Analítica; Argentina
Materia
Four-Way Voltammetric Array
Multi-Analyte Quantification
N-Pls/Rtl
Third-Order Multivariate Calibration
U-Pls/Rtl
Uncalibrated Interference
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/16031
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/16031
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Multidimensional voltammetry: Four-way multivariate calibration with third-order differential pulse voltammetric data for multi-analyte quantification in the presence of uncalibrated interferencesJalalvand, Ali R.Gholivand, Mohammad BagherGoicoechea, Hector CasimiroFour-Way Voltammetric ArrayMulti-Analyte QuantificationN-Pls/RtlThird-Order Multivariate CalibrationU-Pls/RtlUncalibrated Interferencehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A four-way multivariate calibration approach based on the combination of differential pulse voltammetric (DPV) data and four-way algorithms is described for the first time. To achieve this goal, the DPV response of each sample was recorded thirty-six times. Six current-potential matrices were recorded at six different pulse durations. Each matrix consists of six vectors which have been recorded at six different pulse heights. The three-way data array obtained for the calibration set and for each of the test samples were joined into a single four-way data array. The recorded four-way data array was nonlinear, thus, the non-linearities were tackled by potential shift correction using correlation-optimized warping (COW) algorithm and subsequently was analyzed with unfolded-partial least squares/residual trilinearization (U-PLS/RTL) and multi-way-PLS/RTL (N-PLS/RTL) as third-order multivariate calibration algorithms. A comprehensive and systematic strategy for comparing the performance of the two algorithms was presented in this work, in particular with a view of practical applications. This comparison was developed to identify which algorithm offers the best predictions for the simultaneous determination of levodopa (LD), carbidopa (CD), methyldopa (MD), acetaminophen (AC), tramadol (TRA), lidocaine (LC), tolperisone (TOP), ofloxacin (OF), levofloxacin (LOF), and norfloxacin (NOF) in the presence of benserazide (BA), dopamine (DP), and ciprofloxacin (COF) as uncalibrated interferences using a multi-walled carbon nanotubes modified glassy carbon electrode (MWCNTs/GCE). This study demonstrated the more superiority of U-PLS/RTL to resolve the complex systems. The results of applying U-PLS/RTL for the simultaneous determination of the studied analytes in human serum samples as experimental cases were also encouraging.Fil: Jalalvand, Ali R.. Razi University. Faculty of Chemistry. Department of Analytical Chemistry; Irán. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química. Área Química Analítica; ArgentinaFil: Gholivand, Mohammad Bagher. Razi University. Faculty of Chemistry. Department of Analytical Chemistry; IránFil: Goicoechea, Hector Casimiro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química. Área Química Analítica; ArgentinaElsevier Science2015-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/16031Jalalvand, Ali R.; Gholivand, Mohammad Bagher; Goicoechea, Hector Casimiro; Multidimensional voltammetry: Four-way multivariate calibration with third-order differential pulse voltammetric data for multi-analyte quantification in the presence of uncalibrated interferences; Elsevier Science; Chemometrics and Intelligent Laboratory Systems; 148; 11-2015; 60-710169-7439enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.chemolab.2015.09.003info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0169743915002191info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:26:15Zoai:ri.conicet.gov.ar:11336/16031instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:26:15.864CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Multidimensional voltammetry: Four-way multivariate calibration with third-order differential pulse voltammetric data for multi-analyte quantification in the presence of uncalibrated interferences
title Multidimensional voltammetry: Four-way multivariate calibration with third-order differential pulse voltammetric data for multi-analyte quantification in the presence of uncalibrated interferences
spellingShingle Multidimensional voltammetry: Four-way multivariate calibration with third-order differential pulse voltammetric data for multi-analyte quantification in the presence of uncalibrated interferences
Jalalvand, Ali R.
Four-Way Voltammetric Array
Multi-Analyte Quantification
N-Pls/Rtl
Third-Order Multivariate Calibration
U-Pls/Rtl
Uncalibrated Interference
title_short Multidimensional voltammetry: Four-way multivariate calibration with third-order differential pulse voltammetric data for multi-analyte quantification in the presence of uncalibrated interferences
title_full Multidimensional voltammetry: Four-way multivariate calibration with third-order differential pulse voltammetric data for multi-analyte quantification in the presence of uncalibrated interferences
title_fullStr Multidimensional voltammetry: Four-way multivariate calibration with third-order differential pulse voltammetric data for multi-analyte quantification in the presence of uncalibrated interferences
title_full_unstemmed Multidimensional voltammetry: Four-way multivariate calibration with third-order differential pulse voltammetric data for multi-analyte quantification in the presence of uncalibrated interferences
title_sort Multidimensional voltammetry: Four-way multivariate calibration with third-order differential pulse voltammetric data for multi-analyte quantification in the presence of uncalibrated interferences
dc.creator.none.fl_str_mv Jalalvand, Ali R.
Gholivand, Mohammad Bagher
Goicoechea, Hector Casimiro
author Jalalvand, Ali R.
author_facet Jalalvand, Ali R.
Gholivand, Mohammad Bagher
Goicoechea, Hector Casimiro
author_role author
author2 Gholivand, Mohammad Bagher
Goicoechea, Hector Casimiro
author2_role author
author
dc.subject.none.fl_str_mv Four-Way Voltammetric Array
Multi-Analyte Quantification
N-Pls/Rtl
Third-Order Multivariate Calibration
U-Pls/Rtl
Uncalibrated Interference
topic Four-Way Voltammetric Array
Multi-Analyte Quantification
N-Pls/Rtl
Third-Order Multivariate Calibration
U-Pls/Rtl
Uncalibrated Interference
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A four-way multivariate calibration approach based on the combination of differential pulse voltammetric (DPV) data and four-way algorithms is described for the first time. To achieve this goal, the DPV response of each sample was recorded thirty-six times. Six current-potential matrices were recorded at six different pulse durations. Each matrix consists of six vectors which have been recorded at six different pulse heights. The three-way data array obtained for the calibration set and for each of the test samples were joined into a single four-way data array. The recorded four-way data array was nonlinear, thus, the non-linearities were tackled by potential shift correction using correlation-optimized warping (COW) algorithm and subsequently was analyzed with unfolded-partial least squares/residual trilinearization (U-PLS/RTL) and multi-way-PLS/RTL (N-PLS/RTL) as third-order multivariate calibration algorithms. A comprehensive and systematic strategy for comparing the performance of the two algorithms was presented in this work, in particular with a view of practical applications. This comparison was developed to identify which algorithm offers the best predictions for the simultaneous determination of levodopa (LD), carbidopa (CD), methyldopa (MD), acetaminophen (AC), tramadol (TRA), lidocaine (LC), tolperisone (TOP), ofloxacin (OF), levofloxacin (LOF), and norfloxacin (NOF) in the presence of benserazide (BA), dopamine (DP), and ciprofloxacin (COF) as uncalibrated interferences using a multi-walled carbon nanotubes modified glassy carbon electrode (MWCNTs/GCE). This study demonstrated the more superiority of U-PLS/RTL to resolve the complex systems. The results of applying U-PLS/RTL for the simultaneous determination of the studied analytes in human serum samples as experimental cases were also encouraging.
Fil: Jalalvand, Ali R.. Razi University. Faculty of Chemistry. Department of Analytical Chemistry; Irán. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química. Área Química Analítica; Argentina
Fil: Gholivand, Mohammad Bagher. Razi University. Faculty of Chemistry. Department of Analytical Chemistry; Irán
Fil: Goicoechea, Hector Casimiro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química. Área Química Analítica; Argentina
description A four-way multivariate calibration approach based on the combination of differential pulse voltammetric (DPV) data and four-way algorithms is described for the first time. To achieve this goal, the DPV response of each sample was recorded thirty-six times. Six current-potential matrices were recorded at six different pulse durations. Each matrix consists of six vectors which have been recorded at six different pulse heights. The three-way data array obtained for the calibration set and for each of the test samples were joined into a single four-way data array. The recorded four-way data array was nonlinear, thus, the non-linearities were tackled by potential shift correction using correlation-optimized warping (COW) algorithm and subsequently was analyzed with unfolded-partial least squares/residual trilinearization (U-PLS/RTL) and multi-way-PLS/RTL (N-PLS/RTL) as third-order multivariate calibration algorithms. A comprehensive and systematic strategy for comparing the performance of the two algorithms was presented in this work, in particular with a view of practical applications. This comparison was developed to identify which algorithm offers the best predictions for the simultaneous determination of levodopa (LD), carbidopa (CD), methyldopa (MD), acetaminophen (AC), tramadol (TRA), lidocaine (LC), tolperisone (TOP), ofloxacin (OF), levofloxacin (LOF), and norfloxacin (NOF) in the presence of benserazide (BA), dopamine (DP), and ciprofloxacin (COF) as uncalibrated interferences using a multi-walled carbon nanotubes modified glassy carbon electrode (MWCNTs/GCE). This study demonstrated the more superiority of U-PLS/RTL to resolve the complex systems. The results of applying U-PLS/RTL for the simultaneous determination of the studied analytes in human serum samples as experimental cases were also encouraging.
publishDate 2015
dc.date.none.fl_str_mv 2015-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/16031
Jalalvand, Ali R.; Gholivand, Mohammad Bagher; Goicoechea, Hector Casimiro; Multidimensional voltammetry: Four-way multivariate calibration with third-order differential pulse voltammetric data for multi-analyte quantification in the presence of uncalibrated interferences; Elsevier Science; Chemometrics and Intelligent Laboratory Systems; 148; 11-2015; 60-71
0169-7439
url http://hdl.handle.net/11336/16031
identifier_str_mv Jalalvand, Ali R.; Gholivand, Mohammad Bagher; Goicoechea, Hector Casimiro; Multidimensional voltammetry: Four-way multivariate calibration with third-order differential pulse voltammetric data for multi-analyte quantification in the presence of uncalibrated interferences; Elsevier Science; Chemometrics and Intelligent Laboratory Systems; 148; 11-2015; 60-71
0169-7439
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.chemolab.2015.09.003
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0169743915002191
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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