Four-way modeling of 4.2 K time-resolved excitation emission fluorescence data for the quantitation of polycyclic aromatic hydrocarbons in soil samples

Autores
Goicoechea, Hector Casimiro; Yu, Shenjiang; Moore, Anthony F.T.; Campiglia, Andres D.
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A screening method for the soil analysis of 15 Environmental Protection Agency-polycyclic aromatic hydrocarbons (EPA-PAHs) is reported. The new method is based on the collection of 4.2 K fluorescence time-resolved excitation-emission cubes (TREECs) via laser-excited time-resolved Shpol'skii spectroscopy. 4.2 K fluorescence TREECs result from the superposition of fluorescence time-resolved excitation emission matrices recorded at different time windows from the laser excitation pulse. Potential interference from unknown sample concomitants is handled by processing the four-way 4.2 K fluorescence TREEC data arrays with either parallel factor analysis (PARAFAC) or unfolded partial least-squares/residual-trilinearization(U-PLS/RTL). The sensitivity of the two approaches makes possible to determine PAHs at the ng g-1 to pg g-1 concentration level with no need for sample pre-concentration. Its selectivity eliminates sample clean-up steps and chromatographic separation. These features reduce PAH loss, analysis time and cost. The method is environmentally friendly as the complete screening of the 15 EPA-PAHs takes only 250 μL of organic solvent per sample.
Fil: Goicoechea, Hector Casimiro. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Yu, Shenjiang. No especifíca;
Fil: Moore, Anthony F.T.. University of Florida; Estados Unidos
Fil: Campiglia, Andres D.. University of Florida; Estados Unidos
Materia
PARAFAC
POLYCYCLIC AROMATIC HYDROCARBONS (PAHS)
SHPOL'SKII SPECTROSCOPY
SOILS
THIRD-ORDER MULTIVARIATE CALIBRATION
TIME-RESOLVED EXCITATION-EMISSION CUBES (TREECS)
U-PLS/RTL
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/197261
Acceder
id CONICETDig_1085fd872d6a8198d2b3cb6810903993
oai_identifier_str oai:ri.conicet.gov.ar:11336/197261
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Four-way modeling of 4.2 K time-resolved excitation emission fluorescence data for the quantitation of polycyclic aromatic hydrocarbons in soil samplesGoicoechea, Hector CasimiroYu, ShenjiangMoore, Anthony F.T.Campiglia, Andres D.PARAFACPOLYCYCLIC AROMATIC HYDROCARBONS (PAHS)SHPOL'SKII SPECTROSCOPYSOILSTHIRD-ORDER MULTIVARIATE CALIBRATIONTIME-RESOLVED EXCITATION-EMISSION CUBES (TREECS)U-PLS/RTLhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A screening method for the soil analysis of 15 Environmental Protection Agency-polycyclic aromatic hydrocarbons (EPA-PAHs) is reported. The new method is based on the collection of 4.2 K fluorescence time-resolved excitation-emission cubes (TREECs) via laser-excited time-resolved Shpol'skii spectroscopy. 4.2 K fluorescence TREECs result from the superposition of fluorescence time-resolved excitation emission matrices recorded at different time windows from the laser excitation pulse. Potential interference from unknown sample concomitants is handled by processing the four-way 4.2 K fluorescence TREEC data arrays with either parallel factor analysis (PARAFAC) or unfolded partial least-squares/residual-trilinearization(U-PLS/RTL). The sensitivity of the two approaches makes possible to determine PAHs at the ng g-1 to pg g-1 concentration level with no need for sample pre-concentration. Its selectivity eliminates sample clean-up steps and chromatographic separation. These features reduce PAH loss, analysis time and cost. The method is environmentally friendly as the complete screening of the 15 EPA-PAHs takes only 250 μL of organic solvent per sample.Fil: Goicoechea, Hector Casimiro. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Yu, Shenjiang. No especifíca;Fil: Moore, Anthony F.T.. University of Florida; Estados UnidosFil: Campiglia, Andres D.. University of Florida; Estados UnidosElsevier Science2012-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/197261Goicoechea, Hector Casimiro; Yu, Shenjiang; Moore, Anthony F.T.; Campiglia, Andres D.; Four-way modeling of 4.2 K time-resolved excitation emission fluorescence data for the quantitation of polycyclic aromatic hydrocarbons in soil samples; Elsevier Science; Talanta; 101; 9-2012; 330-3360039-9140CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0039914012007916info:eu-repo/semantics/altIdentifier/doi/10.1016/j.talanta.2012.09.035info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:57:42Zoai:ri.conicet.gov.ar:11336/197261instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:57:42.335CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Four-way modeling of 4.2 K time-resolved excitation emission fluorescence data for the quantitation of polycyclic aromatic hydrocarbons in soil samples
title Four-way modeling of 4.2 K time-resolved excitation emission fluorescence data for the quantitation of polycyclic aromatic hydrocarbons in soil samples
spellingShingle Four-way modeling of 4.2 K time-resolved excitation emission fluorescence data for the quantitation of polycyclic aromatic hydrocarbons in soil samples
Goicoechea, Hector Casimiro
PARAFAC
POLYCYCLIC AROMATIC HYDROCARBONS (PAHS)
SHPOL'SKII SPECTROSCOPY
SOILS
THIRD-ORDER MULTIVARIATE CALIBRATION
TIME-RESOLVED EXCITATION-EMISSION CUBES (TREECS)
U-PLS/RTL
title_short Four-way modeling of 4.2 K time-resolved excitation emission fluorescence data for the quantitation of polycyclic aromatic hydrocarbons in soil samples
title_full Four-way modeling of 4.2 K time-resolved excitation emission fluorescence data for the quantitation of polycyclic aromatic hydrocarbons in soil samples
title_fullStr Four-way modeling of 4.2 K time-resolved excitation emission fluorescence data for the quantitation of polycyclic aromatic hydrocarbons in soil samples
title_full_unstemmed Four-way modeling of 4.2 K time-resolved excitation emission fluorescence data for the quantitation of polycyclic aromatic hydrocarbons in soil samples
title_sort Four-way modeling of 4.2 K time-resolved excitation emission fluorescence data for the quantitation of polycyclic aromatic hydrocarbons in soil samples
dc.creator.none.fl_str_mv Goicoechea, Hector Casimiro
Yu, Shenjiang
Moore, Anthony F.T.
Campiglia, Andres D.
author Goicoechea, Hector Casimiro
author_facet Goicoechea, Hector Casimiro
Yu, Shenjiang
Moore, Anthony F.T.
Campiglia, Andres D.
author_role author
author2 Yu, Shenjiang
Moore, Anthony F.T.
Campiglia, Andres D.
author2_role author
author
author
dc.subject.none.fl_str_mv PARAFAC
POLYCYCLIC AROMATIC HYDROCARBONS (PAHS)
SHPOL'SKII SPECTROSCOPY
SOILS
THIRD-ORDER MULTIVARIATE CALIBRATION
TIME-RESOLVED EXCITATION-EMISSION CUBES (TREECS)
U-PLS/RTL
topic PARAFAC
POLYCYCLIC AROMATIC HYDROCARBONS (PAHS)
SHPOL'SKII SPECTROSCOPY
SOILS
THIRD-ORDER MULTIVARIATE CALIBRATION
TIME-RESOLVED EXCITATION-EMISSION CUBES (TREECS)
U-PLS/RTL
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A screening method for the soil analysis of 15 Environmental Protection Agency-polycyclic aromatic hydrocarbons (EPA-PAHs) is reported. The new method is based on the collection of 4.2 K fluorescence time-resolved excitation-emission cubes (TREECs) via laser-excited time-resolved Shpol'skii spectroscopy. 4.2 K fluorescence TREECs result from the superposition of fluorescence time-resolved excitation emission matrices recorded at different time windows from the laser excitation pulse. Potential interference from unknown sample concomitants is handled by processing the four-way 4.2 K fluorescence TREEC data arrays with either parallel factor analysis (PARAFAC) or unfolded partial least-squares/residual-trilinearization(U-PLS/RTL). The sensitivity of the two approaches makes possible to determine PAHs at the ng g-1 to pg g-1 concentration level with no need for sample pre-concentration. Its selectivity eliminates sample clean-up steps and chromatographic separation. These features reduce PAH loss, analysis time and cost. The method is environmentally friendly as the complete screening of the 15 EPA-PAHs takes only 250 μL of organic solvent per sample.
Fil: Goicoechea, Hector Casimiro. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Yu, Shenjiang. No especifíca;
Fil: Moore, Anthony F.T.. University of Florida; Estados Unidos
Fil: Campiglia, Andres D.. University of Florida; Estados Unidos
description A screening method for the soil analysis of 15 Environmental Protection Agency-polycyclic aromatic hydrocarbons (EPA-PAHs) is reported. The new method is based on the collection of 4.2 K fluorescence time-resolved excitation-emission cubes (TREECs) via laser-excited time-resolved Shpol'skii spectroscopy. 4.2 K fluorescence TREECs result from the superposition of fluorescence time-resolved excitation emission matrices recorded at different time windows from the laser excitation pulse. Potential interference from unknown sample concomitants is handled by processing the four-way 4.2 K fluorescence TREEC data arrays with either parallel factor analysis (PARAFAC) or unfolded partial least-squares/residual-trilinearization(U-PLS/RTL). The sensitivity of the two approaches makes possible to determine PAHs at the ng g-1 to pg g-1 concentration level with no need for sample pre-concentration. Its selectivity eliminates sample clean-up steps and chromatographic separation. These features reduce PAH loss, analysis time and cost. The method is environmentally friendly as the complete screening of the 15 EPA-PAHs takes only 250 μL of organic solvent per sample.
publishDate 2012
dc.date.none.fl_str_mv 2012-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/197261
Goicoechea, Hector Casimiro; Yu, Shenjiang; Moore, Anthony F.T.; Campiglia, Andres D.; Four-way modeling of 4.2 K time-resolved excitation emission fluorescence data for the quantitation of polycyclic aromatic hydrocarbons in soil samples; Elsevier Science; Talanta; 101; 9-2012; 330-336
0039-9140
CONICET Digital
CONICET
url http://hdl.handle.net/11336/197261
identifier_str_mv Goicoechea, Hector Casimiro; Yu, Shenjiang; Moore, Anthony F.T.; Campiglia, Andres D.; Four-way modeling of 4.2 K time-resolved excitation emission fluorescence data for the quantitation of polycyclic aromatic hydrocarbons in soil samples; Elsevier Science; Talanta; 101; 9-2012; 330-336
0039-9140
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0039914012007916
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.talanta.2012.09.035
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083116176769024
score 13.22299

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