“Living” Radical Polymerization in Tubular Reactors, 2 - Process Optimization for Tailor-Made Molecular Weight Distributions

Autores
Asteasuain, Mariano; Soares, Matheus; Lenzi, Marcelo K.; Hutchinson, Robin A.; Cunningham, Michael; Brandolin, Adriana; Pinto, José Carlos; Sarmoria, Claudia
Año de publicación
2008
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Living radical polymerization is a relatively new polymerization process that can be used for preparation of resins with controlled structure. In this work, a mathematical model developed previously to describe nitroxide-mediated living radical polymerizations performed in tubular reactors is used for the optimization of the process and obtainment of tailor-made MWDs. Operating conditions and design variables are determined with the help of optimization procedures in order to produce polymers with specified MWD. It is shown that bimodal and trimodal MWDs, with given peak locations, can be obtained through proper manipulation of the operating conditions. This indicates that the technique discussed in this work is suitable for detailed design of the MWD of the final polymer.
Fil: Asteasuain, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Soares, Matheus. Universidade Federal do Rio de Janeiro; Brasil
Fil: Lenzi, Marcelo K.. Universidade Federal do Paraná; Brasil
Fil: Hutchinson, Robin A.. Queens University; Canadá
Fil: Cunningham, Michael. Queens University; Canadá
Fil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Pinto, José Carlos. Universidade Federal do Rio de Janeiro; Brasil
Fil: Sarmoria, Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
Free Radicals
Living Polymerization
Modeling Molecular Weight Distribution
Probability Generating Functions
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/41973
Acceder
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network_name_str CONICET Digital (CONICET)
spelling “Living” Radical Polymerization in Tubular Reactors, 2 - Process Optimization for Tailor-Made Molecular Weight DistributionsAsteasuain, MarianoSoares, MatheusLenzi, Marcelo K.Hutchinson, Robin A.Cunningham, MichaelBrandolin, AdrianaPinto, José CarlosSarmoria, ClaudiaFree RadicalsLiving PolymerizationModeling Molecular Weight DistributionProbability Generating Functionshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Living radical polymerization is a relatively new polymerization process that can be used for preparation of resins with controlled structure. In this work, a mathematical model developed previously to describe nitroxide-mediated living radical polymerizations performed in tubular reactors is used for the optimization of the process and obtainment of tailor-made MWDs. Operating conditions and design variables are determined with the help of optimization procedures in order to produce polymers with specified MWD. It is shown that bimodal and trimodal MWDs, with given peak locations, can be obtained through proper manipulation of the operating conditions. This indicates that the technique discussed in this work is suitable for detailed design of the MWD of the final polymer.Fil: Asteasuain, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Soares, Matheus. Universidade Federal do Rio de Janeiro; BrasilFil: Lenzi, Marcelo K.. Universidade Federal do Paraná; BrasilFil: Hutchinson, Robin A.. Queens University; CanadáFil: Cunningham, Michael. Queens University; CanadáFil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Pinto, José Carlos. Universidade Federal do Rio de Janeiro; BrasilFil: Sarmoria, Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaWiley VCH Verlag2008-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/41973Asteasuain, Mariano; Soares, Matheus; Lenzi, Marcelo K.; Hutchinson, Robin A.; Cunningham, Michael; et al.; “Living” Radical Polymerization in Tubular Reactors, 2 - Process Optimization for Tailor-Made Molecular Weight Distributions; Wiley VCH Verlag; Macromolecular Reaction Engineering; 2; 5; 9-2008; 414-4211862-832XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/mren.200800015info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/mren.200800015info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:11:59Zoai:ri.conicet.gov.ar:11336/41973instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:12:00.257CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv “Living” Radical Polymerization in Tubular Reactors, 2 - Process Optimization for Tailor-Made Molecular Weight Distributions
title “Living” Radical Polymerization in Tubular Reactors, 2 - Process Optimization for Tailor-Made Molecular Weight Distributions
spellingShingle “Living” Radical Polymerization in Tubular Reactors, 2 - Process Optimization for Tailor-Made Molecular Weight Distributions
Asteasuain, Mariano
Free Radicals
Living Polymerization
Modeling Molecular Weight Distribution
Probability Generating Functions
title_short “Living” Radical Polymerization in Tubular Reactors, 2 - Process Optimization for Tailor-Made Molecular Weight Distributions
title_full “Living” Radical Polymerization in Tubular Reactors, 2 - Process Optimization for Tailor-Made Molecular Weight Distributions
title_fullStr “Living” Radical Polymerization in Tubular Reactors, 2 - Process Optimization for Tailor-Made Molecular Weight Distributions
title_full_unstemmed “Living” Radical Polymerization in Tubular Reactors, 2 - Process Optimization for Tailor-Made Molecular Weight Distributions
title_sort “Living” Radical Polymerization in Tubular Reactors, 2 - Process Optimization for Tailor-Made Molecular Weight Distributions
dc.creator.none.fl_str_mv Asteasuain, Mariano
Soares, Matheus
Lenzi, Marcelo K.
Hutchinson, Robin A.
Cunningham, Michael
Brandolin, Adriana
Pinto, José Carlos
Sarmoria, Claudia
author Asteasuain, Mariano
author_facet Asteasuain, Mariano
Soares, Matheus
Lenzi, Marcelo K.
Hutchinson, Robin A.
Cunningham, Michael
Brandolin, Adriana
Pinto, José Carlos
Sarmoria, Claudia
author_role author
author2 Soares, Matheus
Lenzi, Marcelo K.
Hutchinson, Robin A.
Cunningham, Michael
Brandolin, Adriana
Pinto, José Carlos
Sarmoria, Claudia
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Free Radicals
Living Polymerization
Modeling Molecular Weight Distribution
Probability Generating Functions
topic Free Radicals
Living Polymerization
Modeling Molecular Weight Distribution
Probability Generating Functions
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Living radical polymerization is a relatively new polymerization process that can be used for preparation of resins with controlled structure. In this work, a mathematical model developed previously to describe nitroxide-mediated living radical polymerizations performed in tubular reactors is used for the optimization of the process and obtainment of tailor-made MWDs. Operating conditions and design variables are determined with the help of optimization procedures in order to produce polymers with specified MWD. It is shown that bimodal and trimodal MWDs, with given peak locations, can be obtained through proper manipulation of the operating conditions. This indicates that the technique discussed in this work is suitable for detailed design of the MWD of the final polymer.
Fil: Asteasuain, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Soares, Matheus. Universidade Federal do Rio de Janeiro; Brasil
Fil: Lenzi, Marcelo K.. Universidade Federal do Paraná; Brasil
Fil: Hutchinson, Robin A.. Queens University; Canadá
Fil: Cunningham, Michael. Queens University; Canadá
Fil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Pinto, José Carlos. Universidade Federal do Rio de Janeiro; Brasil
Fil: Sarmoria, Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description Living radical polymerization is a relatively new polymerization process that can be used for preparation of resins with controlled structure. In this work, a mathematical model developed previously to describe nitroxide-mediated living radical polymerizations performed in tubular reactors is used for the optimization of the process and obtainment of tailor-made MWDs. Operating conditions and design variables are determined with the help of optimization procedures in order to produce polymers with specified MWD. It is shown that bimodal and trimodal MWDs, with given peak locations, can be obtained through proper manipulation of the operating conditions. This indicates that the technique discussed in this work is suitable for detailed design of the MWD of the final polymer.
publishDate 2008
dc.date.none.fl_str_mv 2008-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/41973
Asteasuain, Mariano; Soares, Matheus; Lenzi, Marcelo K.; Hutchinson, Robin A.; Cunningham, Michael; et al.; “Living” Radical Polymerization in Tubular Reactors, 2 - Process Optimization for Tailor-Made Molecular Weight Distributions; Wiley VCH Verlag; Macromolecular Reaction Engineering; 2; 5; 9-2008; 414-421
1862-832X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/41973
identifier_str_mv Asteasuain, Mariano; Soares, Matheus; Lenzi, Marcelo K.; Hutchinson, Robin A.; Cunningham, Michael; et al.; “Living” Radical Polymerization in Tubular Reactors, 2 - Process Optimization for Tailor-Made Molecular Weight Distributions; Wiley VCH Verlag; Macromolecular Reaction Engineering; 2; 5; 9-2008; 414-421
1862-832X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/mren.200800015
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/mren.200800015
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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