“Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions

Autores
Asteasuain, Mariano; Soares, Matheus; Lenzi, Marcelo K; Cunningham, Michael; Sarmoria, Claudia; Pinto, José Carlos; Brandolin, Adriana
Año de publicación
2007
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This is the first of a series of works aiming at developing a tool for designing “living” free radical polymerization processes in tubular reactors, in order to achieve tailor‐made MWDs. A mathematical model of the nitroxide‐mediated controlled free radical polymerization is built and implemented to predict the complete MWD. It is shown that this objective may be achieved accurately and efficiently by means of the probability generating function (pgf) transformation. Comparison with experimental data is good. The potential of the resulting model for optimization activities involving the complete MWD is also shown.
Fil: Asteasuain, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Soares, Matheus. Universidade Federal do Rio de Janeiro; Brasil
Fil: Lenzi, Marcelo K. Universidade Federal do Paraná; Brasil
Fil: Cunningham, Michael. Queens University; Canadá
Fil: Sarmoria, Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Pinto, José Carlos. Universidade Federal do Rio de Janeiro; Brasil
Fil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
Free Radical
Living Polymerization
Molecular Weight Distribution
Modeling
Probability Generating Functions
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/83578
Acceder
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network_name_str CONICET Digital (CONICET)
spelling “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating FunctionsAsteasuain, MarianoSoares, MatheusLenzi, Marcelo KCunningham, MichaelSarmoria, ClaudiaPinto, José CarlosBrandolin, AdrianaFree RadicalLiving PolymerizationMolecular Weight DistributionModelingProbability Generating Functionshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2This is the first of a series of works aiming at developing a tool for designing “living” free radical polymerization processes in tubular reactors, in order to achieve tailor‐made MWDs. A mathematical model of the nitroxide‐mediated controlled free radical polymerization is built and implemented to predict the complete MWD. It is shown that this objective may be achieved accurately and efficiently by means of the probability generating function (pgf) transformation. Comparison with experimental data is good. The potential of the resulting model for optimization activities involving the complete MWD is also shown.Fil: Asteasuain, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Soares, Matheus. Universidade Federal do Rio de Janeiro; BrasilFil: Lenzi, Marcelo K. Universidade Federal do Paraná; BrasilFil: Cunningham, Michael. Queens University; CanadáFil: Sarmoria, Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Pinto, José Carlos. Universidade Federal do Rio de Janeiro; BrasilFil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaWiley VCH Verlag2007-11-15info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/83578Asteasuain, Mariano; Soares, Matheus; Lenzi, Marcelo K; Cunningham, Michael; Sarmoria, Claudia; et al.; “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions; Wiley VCH Verlag; Macromolecular Reaction Engineering; 1; 6; 15-11-2007; 622-6341862-832X1862-8338CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/mren.200700026info:eu-repo/semantics/altIdentifier/doi/10.1002/mren.200700026info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:10:59Zoai:ri.conicet.gov.ar:11336/83578instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:10:59.445CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions
title “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions
spellingShingle “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions
Asteasuain, Mariano
Free Radical
Living Polymerization
Molecular Weight Distribution
Modeling
Probability Generating Functions
title_short “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions
title_full “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions
title_fullStr “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions
title_full_unstemmed “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions
title_sort “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions
dc.creator.none.fl_str_mv Asteasuain, Mariano
Soares, Matheus
Lenzi, Marcelo K
Cunningham, Michael
Sarmoria, Claudia
Pinto, José Carlos
Brandolin, Adriana
author Asteasuain, Mariano
author_facet Asteasuain, Mariano
Soares, Matheus
Lenzi, Marcelo K
Cunningham, Michael
Sarmoria, Claudia
Pinto, José Carlos
Brandolin, Adriana
author_role author
author2 Soares, Matheus
Lenzi, Marcelo K
Cunningham, Michael
Sarmoria, Claudia
Pinto, José Carlos
Brandolin, Adriana
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Free Radical
Living Polymerization
Molecular Weight Distribution
Modeling
Probability Generating Functions
topic Free Radical
Living Polymerization
Molecular Weight Distribution
Modeling
Probability Generating Functions
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv This is the first of a series of works aiming at developing a tool for designing “living” free radical polymerization processes in tubular reactors, in order to achieve tailor‐made MWDs. A mathematical model of the nitroxide‐mediated controlled free radical polymerization is built and implemented to predict the complete MWD. It is shown that this objective may be achieved accurately and efficiently by means of the probability generating function (pgf) transformation. Comparison with experimental data is good. The potential of the resulting model for optimization activities involving the complete MWD is also shown.
Fil: Asteasuain, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Soares, Matheus. Universidade Federal do Rio de Janeiro; Brasil
Fil: Lenzi, Marcelo K. Universidade Federal do Paraná; Brasil
Fil: Cunningham, Michael. Queens University; Canadá
Fil: Sarmoria, Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Pinto, José Carlos. Universidade Federal do Rio de Janeiro; Brasil
Fil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description This is the first of a series of works aiming at developing a tool for designing “living” free radical polymerization processes in tubular reactors, in order to achieve tailor‐made MWDs. A mathematical model of the nitroxide‐mediated controlled free radical polymerization is built and implemented to predict the complete MWD. It is shown that this objective may be achieved accurately and efficiently by means of the probability generating function (pgf) transformation. Comparison with experimental data is good. The potential of the resulting model for optimization activities involving the complete MWD is also shown.
publishDate 2007
dc.date.none.fl_str_mv 2007-11-15
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/83578
Asteasuain, Mariano; Soares, Matheus; Lenzi, Marcelo K; Cunningham, Michael; Sarmoria, Claudia; et al.; “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions; Wiley VCH Verlag; Macromolecular Reaction Engineering; 1; 6; 15-11-2007; 622-634
1862-832X
1862-8338
CONICET Digital
CONICET
url http://hdl.handle.net/11336/83578
identifier_str_mv Asteasuain, Mariano; Soares, Matheus; Lenzi, Marcelo K; Cunningham, Michael; Sarmoria, Claudia; et al.; “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions; Wiley VCH Verlag; Macromolecular Reaction Engineering; 1; 6; 15-11-2007; 622-634
1862-832X
1862-8338
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/mren.200700026
info:eu-repo/semantics/altIdentifier/doi/10.1002/mren.200700026
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842270140510502912
score 13.13397

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