Rapid monitoring of heavy metals in fluvial sediments using laser-induced breakdown spectroscopy

Autores
Martino, Lucila Juliana; D'angelo, Cristian Adrián; Rodriguez, Corina Iris; Diaz Pace, Diego Martin
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, a quantitative analysis of heavy metals Cr and Cu in fluvial sediments was carried out by Laser-induced breakdown Spectroscopy (LIBS) to assess the anthropogenic. To perform the analysis, different sediment samples were collected at selected positions. Standard addition calibration curves were constructed for Cr and Cu by measuring the Cr I line at 357.87 nm and Cu I line at 324.75 nm. The moisture and organic matter contents of the sediments were taken into account to overcome the matrix effect. The quantitative models were evaluated statistically to evaluate the robustness and prediction ability of the method. Low values for root-mean-square errors for calibration (RMSEC), prediction (RMSEP) and cross-validation (RMSECV) were calculated. High values of the correlation coefficients of calibration (Rc2 = 0:984 for Cr; Rc2= 0:986 for Cu) and cross-validation (Rcv2 = 0:985 for Cr; Rcv2 = 0:981 for Cu) were obtained. The calculated limits of detection (LoD) were 2.9 ppm for Cr and 3.3 ppm for Cu, and the limits of quantification (LoQ) were 9.5 ppm for Cr and 11 ppm for Cu. Concentrations of Cr and Cu higher than the baseline values were obtained in the sediments downstream (Cr: 49 ppm, Cu: 81 ppm) which are indicative of the pollution of the basin by heavy metals due to the spill of untreated effluents derived from anthropogenic activities. LIBS analysis was optimized for reliable heavy metal monitoring in fluvial sediments.
Fil: Martino, Lucila Juliana. Universidad Nacional del Centro de la Provincia de Buenos Aires. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina
Fil: D'angelo, Cristian Adrián. Universidad Nacional del Centro de la Provincia de Buenos Aires. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina
Fil: Rodriguez, Corina Iris. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Humanas. Departamento de Ciencias Ambientales. Centro de Investigación y Estudios Ambientales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Diaz Pace, Diego Martin. Universidad Nacional del Centro de la Provincia de Buenos Aires. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina
Materia
FLUVIAL SEDIMENT
CHROMIUM
COPPER
LASER-INDUCED BREAKDOWN SPECTROSCOPY
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/111423
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/111423
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Rapid monitoring of heavy metals in fluvial sediments using laser-induced breakdown spectroscopyMartino, Lucila JulianaD'angelo, Cristian AdriánRodriguez, Corina IrisDiaz Pace, Diego MartinFLUVIAL SEDIMENTCHROMIUMCOPPERLASER-INDUCED BREAKDOWN SPECTROSCOPYhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1In this work, a quantitative analysis of heavy metals Cr and Cu in fluvial sediments was carried out by Laser-induced breakdown Spectroscopy (LIBS) to assess the anthropogenic. To perform the analysis, different sediment samples were collected at selected positions. Standard addition calibration curves were constructed for Cr and Cu by measuring the Cr I line at 357.87 nm and Cu I line at 324.75 nm. The moisture and organic matter contents of the sediments were taken into account to overcome the matrix effect. The quantitative models were evaluated statistically to evaluate the robustness and prediction ability of the method. Low values for root-mean-square errors for calibration (RMSEC), prediction (RMSEP) and cross-validation (RMSECV) were calculated. High values of the correlation coefficients of calibration (Rc2 = 0:984 for Cr; Rc2= 0:986 for Cu) and cross-validation (Rcv2 = 0:985 for Cr; Rcv2 = 0:981 for Cu) were obtained. The calculated limits of detection (LoD) were 2.9 ppm for Cr and 3.3 ppm for Cu, and the limits of quantification (LoQ) were 9.5 ppm for Cr and 11 ppm for Cu. Concentrations of Cr and Cu higher than the baseline values were obtained in the sediments downstream (Cr: 49 ppm, Cu: 81 ppm) which are indicative of the pollution of the basin by heavy metals due to the spill of untreated effluents derived from anthropogenic activities. LIBS analysis was optimized for reliable heavy metal monitoring in fluvial sediments.Fil: Martino, Lucila Juliana. Universidad Nacional del Centro de la Provincia de Buenos Aires. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; ArgentinaFil: D'angelo, Cristian Adrián. Universidad Nacional del Centro de la Provincia de Buenos Aires. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; ArgentinaFil: Rodriguez, Corina Iris. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Humanas. Departamento de Ciencias Ambientales. Centro de Investigación y Estudios Ambientales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Diaz Pace, Diego Martin. Universidad Nacional del Centro de la Provincia de Buenos Aires. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; ArgentinaSociedad Mexicana de Física2019-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/111423Martino, Lucila Juliana; D'angelo, Cristian Adrián; Rodriguez, Corina Iris; Diaz Pace, Diego Martin; Rapid monitoring of heavy metals in fluvial sediments using laser-induced breakdown spectroscopy; Sociedad Mexicana de Física; Revista Mexicana de Física; 65; 5; 9-2019; 440-4480035-001X2683-2224CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://rmf.smf.mx/ojs/rmf/article/view/4293info:eu-repo/semantics/altIdentifier/doi/10.31349/RevMexFis.65.440info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:00:33Zoai:ri.conicet.gov.ar:11336/111423instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:00:33.454CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Rapid monitoring of heavy metals in fluvial sediments using laser-induced breakdown spectroscopy
title Rapid monitoring of heavy metals in fluvial sediments using laser-induced breakdown spectroscopy
spellingShingle Rapid monitoring of heavy metals in fluvial sediments using laser-induced breakdown spectroscopy
Martino, Lucila Juliana
FLUVIAL SEDIMENT
CHROMIUM
COPPER
LASER-INDUCED BREAKDOWN SPECTROSCOPY
title_short Rapid monitoring of heavy metals in fluvial sediments using laser-induced breakdown spectroscopy
title_full Rapid monitoring of heavy metals in fluvial sediments using laser-induced breakdown spectroscopy
title_fullStr Rapid monitoring of heavy metals in fluvial sediments using laser-induced breakdown spectroscopy
title_full_unstemmed Rapid monitoring of heavy metals in fluvial sediments using laser-induced breakdown spectroscopy
title_sort Rapid monitoring of heavy metals in fluvial sediments using laser-induced breakdown spectroscopy
dc.creator.none.fl_str_mv Martino, Lucila Juliana
D'angelo, Cristian Adrián
Rodriguez, Corina Iris
Diaz Pace, Diego Martin
author Martino, Lucila Juliana
author_facet Martino, Lucila Juliana
D'angelo, Cristian Adrián
Rodriguez, Corina Iris
Diaz Pace, Diego Martin
author_role author
author2 D'angelo, Cristian Adrián
Rodriguez, Corina Iris
Diaz Pace, Diego Martin
author2_role author
author
author
dc.subject.none.fl_str_mv FLUVIAL SEDIMENT
CHROMIUM
COPPER
LASER-INDUCED BREAKDOWN SPECTROSCOPY
topic FLUVIAL SEDIMENT
CHROMIUM
COPPER
LASER-INDUCED BREAKDOWN SPECTROSCOPY
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this work, a quantitative analysis of heavy metals Cr and Cu in fluvial sediments was carried out by Laser-induced breakdown Spectroscopy (LIBS) to assess the anthropogenic. To perform the analysis, different sediment samples were collected at selected positions. Standard addition calibration curves were constructed for Cr and Cu by measuring the Cr I line at 357.87 nm and Cu I line at 324.75 nm. The moisture and organic matter contents of the sediments were taken into account to overcome the matrix effect. The quantitative models were evaluated statistically to evaluate the robustness and prediction ability of the method. Low values for root-mean-square errors for calibration (RMSEC), prediction (RMSEP) and cross-validation (RMSECV) were calculated. High values of the correlation coefficients of calibration (Rc2 = 0:984 for Cr; Rc2= 0:986 for Cu) and cross-validation (Rcv2 = 0:985 for Cr; Rcv2 = 0:981 for Cu) were obtained. The calculated limits of detection (LoD) were 2.9 ppm for Cr and 3.3 ppm for Cu, and the limits of quantification (LoQ) were 9.5 ppm for Cr and 11 ppm for Cu. Concentrations of Cr and Cu higher than the baseline values were obtained in the sediments downstream (Cr: 49 ppm, Cu: 81 ppm) which are indicative of the pollution of the basin by heavy metals due to the spill of untreated effluents derived from anthropogenic activities. LIBS analysis was optimized for reliable heavy metal monitoring in fluvial sediments.
Fil: Martino, Lucila Juliana. Universidad Nacional del Centro de la Provincia de Buenos Aires. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina
Fil: D'angelo, Cristian Adrián. Universidad Nacional del Centro de la Provincia de Buenos Aires. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina
Fil: Rodriguez, Corina Iris. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Humanas. Departamento de Ciencias Ambientales. Centro de Investigación y Estudios Ambientales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Diaz Pace, Diego Martin. Universidad Nacional del Centro de la Provincia de Buenos Aires. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina
description In this work, a quantitative analysis of heavy metals Cr and Cu in fluvial sediments was carried out by Laser-induced breakdown Spectroscopy (LIBS) to assess the anthropogenic. To perform the analysis, different sediment samples were collected at selected positions. Standard addition calibration curves were constructed for Cr and Cu by measuring the Cr I line at 357.87 nm and Cu I line at 324.75 nm. The moisture and organic matter contents of the sediments were taken into account to overcome the matrix effect. The quantitative models were evaluated statistically to evaluate the robustness and prediction ability of the method. Low values for root-mean-square errors for calibration (RMSEC), prediction (RMSEP) and cross-validation (RMSECV) were calculated. High values of the correlation coefficients of calibration (Rc2 = 0:984 for Cr; Rc2= 0:986 for Cu) and cross-validation (Rcv2 = 0:985 for Cr; Rcv2 = 0:981 for Cu) were obtained. The calculated limits of detection (LoD) were 2.9 ppm for Cr and 3.3 ppm for Cu, and the limits of quantification (LoQ) were 9.5 ppm for Cr and 11 ppm for Cu. Concentrations of Cr and Cu higher than the baseline values were obtained in the sediments downstream (Cr: 49 ppm, Cu: 81 ppm) which are indicative of the pollution of the basin by heavy metals due to the spill of untreated effluents derived from anthropogenic activities. LIBS analysis was optimized for reliable heavy metal monitoring in fluvial sediments.
publishDate 2019
dc.date.none.fl_str_mv 2019-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/111423
Martino, Lucila Juliana; D'angelo, Cristian Adrián; Rodriguez, Corina Iris; Diaz Pace, Diego Martin; Rapid monitoring of heavy metals in fluvial sediments using laser-induced breakdown spectroscopy; Sociedad Mexicana de Física; Revista Mexicana de Física; 65; 5; 9-2019; 440-448
0035-001X
2683-2224
CONICET Digital
CONICET
url http://hdl.handle.net/11336/111423
identifier_str_mv Martino, Lucila Juliana; D'angelo, Cristian Adrián; Rodriguez, Corina Iris; Diaz Pace, Diego Martin; Rapid monitoring of heavy metals in fluvial sediments using laser-induced breakdown spectroscopy; Sociedad Mexicana de Física; Revista Mexicana de Física; 65; 5; 9-2019; 440-448
0035-001X
2683-2224
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://rmf.smf.mx/ojs/rmf/article/view/4293
info:eu-repo/semantics/altIdentifier/doi/10.31349/RevMexFis.65.440
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Sociedad Mexicana de Física
publisher.none.fl_str_mv Sociedad Mexicana de Física
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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