Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy

Autores
Diaz Pace, Diego Martin; Miguel, Roberto Esteban; Di Rocco, Hector Omar; Anabitarte García, F.; Pardini, L.; Legnaioli, S.; Lorenzetti, G.; Palleschi, V.
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Laser-induced breakdown spectroscopy (LIBS) was applied for quantitative analysis of the elemental composition of waste molding and core sands produced from industry as part of the casting process. To perform the analysis, waste foundry sands (WFS) were collected from metalcasting foundries and prepared in the form of solid pellets with the addition of polyvinyl alcohol as binder. The measurements were carried out using the Mobile double pulse instrument for LIBS analysis (Modì). The spectral analysis was carried out with the calibration-free approach (CF-LIBS). Metal elements commonly found in WFS including Al, Ba, Fe, Li, Mg, Mn, Pb, Ti, Zr, and Zn, were detected and quantified. The metal concentrations for WFS were compared with virgin sand to assess the influence of the casting material as well as the binders used in the foundries to reclaim the sands. The results demonstrated the feasibility of LIBS method as an alternative or complementary technique for the chemical characterization of WFS.
Fil: Diaz Pace, Diego Martin. Universidad Nacional del Centro de la Provincia de Buenos Aires. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina
Fil: Miguel, Roberto Esteban. Instituto Nacional de Tecnología Agropecuaria. Estación Experimental Agropecuaria Chilecito; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Di Rocco, Hector Omar. Universidad Nacional del Centro de la Provincia de Buenos Aires. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina
Fil: Anabitarte García, F.. Universidad de Cantabria; España
Fil: Pardini, L.. Institute of Chemistry of Organometallic Compounds; Italia
Fil: Legnaioli, S.. Institute of Chemistry of Organometallic Compounds; Italia
Fil: Lorenzetti, G.. Institute of Chemistry of Organometallic Compounds; Italia
Fil: Palleschi, V.. Institute of Chemistry of Organometallic Compounds; Italia
Materia
Laser-Induced Breakdown Spectroscopy
Libs
Plasma Characterization
Waste Sand
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/58186
Acceder
id CONICETDig_fd794bfca53171ee0c364b50742676b8
oai_identifier_str oai:ri.conicet.gov.ar:11336/58186
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopyDiaz Pace, Diego MartinMiguel, Roberto EstebanDi Rocco, Hector OmarAnabitarte García, F.Pardini, L.Legnaioli, S.Lorenzetti, G.Palleschi, V.Laser-Induced Breakdown SpectroscopyLibsPlasma CharacterizationWaste Sandhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1Laser-induced breakdown spectroscopy (LIBS) was applied for quantitative analysis of the elemental composition of waste molding and core sands produced from industry as part of the casting process. To perform the analysis, waste foundry sands (WFS) were collected from metalcasting foundries and prepared in the form of solid pellets with the addition of polyvinyl alcohol as binder. The measurements were carried out using the Mobile double pulse instrument for LIBS analysis (Modì). The spectral analysis was carried out with the calibration-free approach (CF-LIBS). Metal elements commonly found in WFS including Al, Ba, Fe, Li, Mg, Mn, Pb, Ti, Zr, and Zn, were detected and quantified. The metal concentrations for WFS were compared with virgin sand to assess the influence of the casting material as well as the binders used in the foundries to reclaim the sands. The results demonstrated the feasibility of LIBS method as an alternative or complementary technique for the chemical characterization of WFS.Fil: Diaz Pace, Diego Martin. Universidad Nacional del Centro de la Provincia de Buenos Aires. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; ArgentinaFil: Miguel, Roberto Esteban. Instituto Nacional de Tecnología Agropecuaria. Estación Experimental Agropecuaria Chilecito; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Di Rocco, Hector Omar. Universidad Nacional del Centro de la Provincia de Buenos Aires. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; ArgentinaFil: Anabitarte García, F.. Universidad de Cantabria; EspañaFil: Pardini, L.. Institute of Chemistry of Organometallic Compounds; ItaliaFil: Legnaioli, S.. Institute of Chemistry of Organometallic Compounds; ItaliaFil: Lorenzetti, G.. Institute of Chemistry of Organometallic Compounds; ItaliaFil: Palleschi, V.. Institute of Chemistry of Organometallic Compounds; ItaliaPergamon-Elsevier Science Ltd2017-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/58186Diaz Pace, Diego Martin; Miguel, Roberto Esteban; Di Rocco, Hector Omar; Anabitarte García, F.; Pardini, L.; et al.; Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy; Pergamon-Elsevier Science Ltd; Spectrochimica Acta Part B: Atomic Spectroscopy; 131; 5-2017; 58-650584-8547CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0584854716301628info:eu-repo/semantics/altIdentifier/doi/10.1016/j.sab.2017.03.007info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:40:02Zoai:ri.conicet.gov.ar:11336/58186instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:40:02.947CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
title Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
spellingShingle Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
Diaz Pace, Diego Martin
Laser-Induced Breakdown Spectroscopy
Libs
Plasma Characterization
Waste Sand
title_short Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
title_full Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
title_fullStr Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
title_full_unstemmed Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
title_sort Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
dc.creator.none.fl_str_mv Diaz Pace, Diego Martin
Miguel, Roberto Esteban
Di Rocco, Hector Omar
Anabitarte García, F.
Pardini, L.
Legnaioli, S.
Lorenzetti, G.
Palleschi, V.
author Diaz Pace, Diego Martin
author_facet Diaz Pace, Diego Martin
Miguel, Roberto Esteban
Di Rocco, Hector Omar
Anabitarte García, F.
Pardini, L.
Legnaioli, S.
Lorenzetti, G.
Palleschi, V.
author_role author
author2 Miguel, Roberto Esteban
Di Rocco, Hector Omar
Anabitarte García, F.
Pardini, L.
Legnaioli, S.
Lorenzetti, G.
Palleschi, V.
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Laser-Induced Breakdown Spectroscopy
Libs
Plasma Characterization
Waste Sand
topic Laser-Induced Breakdown Spectroscopy
Libs
Plasma Characterization
Waste Sand
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Laser-induced breakdown spectroscopy (LIBS) was applied for quantitative analysis of the elemental composition of waste molding and core sands produced from industry as part of the casting process. To perform the analysis, waste foundry sands (WFS) were collected from metalcasting foundries and prepared in the form of solid pellets with the addition of polyvinyl alcohol as binder. The measurements were carried out using the Mobile double pulse instrument for LIBS analysis (Modì). The spectral analysis was carried out with the calibration-free approach (CF-LIBS). Metal elements commonly found in WFS including Al, Ba, Fe, Li, Mg, Mn, Pb, Ti, Zr, and Zn, were detected and quantified. The metal concentrations for WFS were compared with virgin sand to assess the influence of the casting material as well as the binders used in the foundries to reclaim the sands. The results demonstrated the feasibility of LIBS method as an alternative or complementary technique for the chemical characterization of WFS.
Fil: Diaz Pace, Diego Martin. Universidad Nacional del Centro de la Provincia de Buenos Aires. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina
Fil: Miguel, Roberto Esteban. Instituto Nacional de Tecnología Agropecuaria. Estación Experimental Agropecuaria Chilecito; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Di Rocco, Hector Omar. Universidad Nacional del Centro de la Provincia de Buenos Aires. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. - Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina
Fil: Anabitarte García, F.. Universidad de Cantabria; España
Fil: Pardini, L.. Institute of Chemistry of Organometallic Compounds; Italia
Fil: Legnaioli, S.. Institute of Chemistry of Organometallic Compounds; Italia
Fil: Lorenzetti, G.. Institute of Chemistry of Organometallic Compounds; Italia
Fil: Palleschi, V.. Institute of Chemistry of Organometallic Compounds; Italia
description Laser-induced breakdown spectroscopy (LIBS) was applied for quantitative analysis of the elemental composition of waste molding and core sands produced from industry as part of the casting process. To perform the analysis, waste foundry sands (WFS) were collected from metalcasting foundries and prepared in the form of solid pellets with the addition of polyvinyl alcohol as binder. The measurements were carried out using the Mobile double pulse instrument for LIBS analysis (Modì). The spectral analysis was carried out with the calibration-free approach (CF-LIBS). Metal elements commonly found in WFS including Al, Ba, Fe, Li, Mg, Mn, Pb, Ti, Zr, and Zn, were detected and quantified. The metal concentrations for WFS were compared with virgin sand to assess the influence of the casting material as well as the binders used in the foundries to reclaim the sands. The results demonstrated the feasibility of LIBS method as an alternative or complementary technique for the chemical characterization of WFS.
publishDate 2017
dc.date.none.fl_str_mv 2017-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/58186
Diaz Pace, Diego Martin; Miguel, Roberto Esteban; Di Rocco, Hector Omar; Anabitarte García, F.; Pardini, L.; et al.; Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy; Pergamon-Elsevier Science Ltd; Spectrochimica Acta Part B: Atomic Spectroscopy; 131; 5-2017; 58-65
0584-8547
CONICET Digital
CONICET
url http://hdl.handle.net/11336/58186
identifier_str_mv Diaz Pace, Diego Martin; Miguel, Roberto Esteban; Di Rocco, Hector Omar; Anabitarte García, F.; Pardini, L.; et al.; Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy; Pergamon-Elsevier Science Ltd; Spectrochimica Acta Part B: Atomic Spectroscopy; 131; 5-2017; 58-65
0584-8547
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0584854716301628
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.sab.2017.03.007
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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