Deep eutectic solvent assisted hydrothermal synthesis of photochromic and nontoxic tungsten oxide nanoparticles

Autores
Ogungbesan, Shephrah Olubusola; Ejeromedoghene, Onome; Moglie, Yanina Fernanda; Buxaderas Perez de Armiñan, Eduardo; Cui, Bingbing; Adedokun, Rosemary Anwuli; Kalulu, Mulenga; Idowu, Mopelola Abidemi; Díaz Díaz, David; Fu, Guodong
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, hydrothermal methods and deep eutectic solvents were combined for the first time to prepare tungsten trioxide nanoparticles in an easy and green manner improving their optical and photochromic properties. Characterization of the synthesized nanoparticles was performed via Fourier transform infrared spectroscopy, X-ray diffraction, ultraviolet visible spectroscopy, scanning electron microscopy, energy dispersive X-ray, transform electron microscopy, dynamic light scattering, thermogravimetric analysis, and X-ray photoelectron spectroscopy. The average size of the spherical nanoparticles was ca. 1.83 nm as shown by TEM, and the nanoparticles exhibited high thermostability at least until 900 1C, and photostability and photosensitivity when they were exposed to UV light. Additionally, synthesized tungsten trioxide nanoparticles were found to be nontoxic with maximum cell viability observed even at 100 mg mL1 , making them potential candidates for biomedical applications.
Fil: Ogungbesan, Shephrah Olubusola. Southeast University; China
Fil: Ejeromedoghene, Onome. Soochow University; China
Fil: Moglie, Yanina Fernanda. Universidad Nacional del Sur. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Buxaderas Perez de Armiñan, Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Cui, Bingbing. Southeast University; China
Fil: Adedokun, Rosemary Anwuli. Chrislan University Abeokuta; Nigeria
Fil: Kalulu, Mulenga. Southeast University; China
Fil: Idowu, Mopelola Abidemi. Federal University Of Agriculture Abeokuta; Nigeria
Fil: Díaz Díaz, David. Universidad de la Laguna. Departamento de Química Orgánica. Instituto Universitario de Bio-Orgánica "Antonio González"; España
Fil: Fu, Guodong. Southeast University; China
Materia
deep eutectic solvents
tungsten oxide
nanoparticles
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/260411
Acceder
id CONICETDig_0e6afdf7ec2be365812c0c0e41c52b60
oai_identifier_str oai:ri.conicet.gov.ar:11336/260411
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Deep eutectic solvent assisted hydrothermal synthesis of photochromic and nontoxic tungsten oxide nanoparticlesOgungbesan, Shephrah OlubusolaEjeromedoghene, OnomeMoglie, Yanina FernandaBuxaderas Perez de Armiñan, EduardoCui, BingbingAdedokun, Rosemary AnwuliKalulu, MulengaIdowu, Mopelola AbidemiDíaz Díaz, DavidFu, Guodongdeep eutectic solventstungsten oxidenanoparticleshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In this work, hydrothermal methods and deep eutectic solvents were combined for the first time to prepare tungsten trioxide nanoparticles in an easy and green manner improving their optical and photochromic properties. Characterization of the synthesized nanoparticles was performed via Fourier transform infrared spectroscopy, X-ray diffraction, ultraviolet visible spectroscopy, scanning electron microscopy, energy dispersive X-ray, transform electron microscopy, dynamic light scattering, thermogravimetric analysis, and X-ray photoelectron spectroscopy. The average size of the spherical nanoparticles was ca. 1.83 nm as shown by TEM, and the nanoparticles exhibited high thermostability at least until 900 1C, and photostability and photosensitivity when they were exposed to UV light. Additionally, synthesized tungsten trioxide nanoparticles were found to be nontoxic with maximum cell viability observed even at 100 mg mL1 , making them potential candidates for biomedical applications.Fil: Ogungbesan, Shephrah Olubusola. Southeast University; ChinaFil: Ejeromedoghene, Onome. Soochow University; ChinaFil: Moglie, Yanina Fernanda. Universidad Nacional del Sur. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Buxaderas Perez de Armiñan, Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Cui, Bingbing. Southeast University; ChinaFil: Adedokun, Rosemary Anwuli. Chrislan University Abeokuta; NigeriaFil: Kalulu, Mulenga. Southeast University; ChinaFil: Idowu, Mopelola Abidemi. Federal University Of Agriculture Abeokuta; NigeriaFil: Díaz Díaz, David. Universidad de la Laguna. Departamento de Química Orgánica. Instituto Universitario de Bio-Orgánica "Antonio González"; EspañaFil: Fu, Guodong. Southeast University; ChinaRoyal Society of Chemistry2024-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/260411Ogungbesan, Shephrah Olubusola; Ejeromedoghene, Onome; Moglie, Yanina Fernanda; Buxaderas Perez de Armiñan, Eduardo; Cui, Bingbing; et al.; Deep eutectic solvent assisted hydrothermal synthesis of photochromic and nontoxic tungsten oxide nanoparticles; Royal Society of Chemistry; New Journal of Chemistry; 48; 35; 8-2024; 15428-154351144-0546CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://xlink.rsc.org/?DOI=D4NJ02995Jinfo:eu-repo/semantics/altIdentifier/doi/10.1039/D4NJ02995Jinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:58:34Zoai:ri.conicet.gov.ar:11336/260411instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:58:35.088CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Deep eutectic solvent assisted hydrothermal synthesis of photochromic and nontoxic tungsten oxide nanoparticles
title Deep eutectic solvent assisted hydrothermal synthesis of photochromic and nontoxic tungsten oxide nanoparticles
spellingShingle Deep eutectic solvent assisted hydrothermal synthesis of photochromic and nontoxic tungsten oxide nanoparticles
Ogungbesan, Shephrah Olubusola
deep eutectic solvents
tungsten oxide
nanoparticles
title_short Deep eutectic solvent assisted hydrothermal synthesis of photochromic and nontoxic tungsten oxide nanoparticles
title_full Deep eutectic solvent assisted hydrothermal synthesis of photochromic and nontoxic tungsten oxide nanoparticles
title_fullStr Deep eutectic solvent assisted hydrothermal synthesis of photochromic and nontoxic tungsten oxide nanoparticles
title_full_unstemmed Deep eutectic solvent assisted hydrothermal synthesis of photochromic and nontoxic tungsten oxide nanoparticles
title_sort Deep eutectic solvent assisted hydrothermal synthesis of photochromic and nontoxic tungsten oxide nanoparticles
dc.creator.none.fl_str_mv Ogungbesan, Shephrah Olubusola
Ejeromedoghene, Onome
Moglie, Yanina Fernanda
Buxaderas Perez de Armiñan, Eduardo
Cui, Bingbing
Adedokun, Rosemary Anwuli
Kalulu, Mulenga
Idowu, Mopelola Abidemi
Díaz Díaz, David
Fu, Guodong
author Ogungbesan, Shephrah Olubusola
author_facet Ogungbesan, Shephrah Olubusola
Ejeromedoghene, Onome
Moglie, Yanina Fernanda
Buxaderas Perez de Armiñan, Eduardo
Cui, Bingbing
Adedokun, Rosemary Anwuli
Kalulu, Mulenga
Idowu, Mopelola Abidemi
Díaz Díaz, David
Fu, Guodong
author_role author
author2 Ejeromedoghene, Onome
Moglie, Yanina Fernanda
Buxaderas Perez de Armiñan, Eduardo
Cui, Bingbing
Adedokun, Rosemary Anwuli
Kalulu, Mulenga
Idowu, Mopelola Abidemi
Díaz Díaz, David
Fu, Guodong
author2_role author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv deep eutectic solvents
tungsten oxide
nanoparticles
topic deep eutectic solvents
tungsten oxide
nanoparticles
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this work, hydrothermal methods and deep eutectic solvents were combined for the first time to prepare tungsten trioxide nanoparticles in an easy and green manner improving their optical and photochromic properties. Characterization of the synthesized nanoparticles was performed via Fourier transform infrared spectroscopy, X-ray diffraction, ultraviolet visible spectroscopy, scanning electron microscopy, energy dispersive X-ray, transform electron microscopy, dynamic light scattering, thermogravimetric analysis, and X-ray photoelectron spectroscopy. The average size of the spherical nanoparticles was ca. 1.83 nm as shown by TEM, and the nanoparticles exhibited high thermostability at least until 900 1C, and photostability and photosensitivity when they were exposed to UV light. Additionally, synthesized tungsten trioxide nanoparticles were found to be nontoxic with maximum cell viability observed even at 100 mg mL1 , making them potential candidates for biomedical applications.
Fil: Ogungbesan, Shephrah Olubusola. Southeast University; China
Fil: Ejeromedoghene, Onome. Soochow University; China
Fil: Moglie, Yanina Fernanda. Universidad Nacional del Sur. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Buxaderas Perez de Armiñan, Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Cui, Bingbing. Southeast University; China
Fil: Adedokun, Rosemary Anwuli. Chrislan University Abeokuta; Nigeria
Fil: Kalulu, Mulenga. Southeast University; China
Fil: Idowu, Mopelola Abidemi. Federal University Of Agriculture Abeokuta; Nigeria
Fil: Díaz Díaz, David. Universidad de la Laguna. Departamento de Química Orgánica. Instituto Universitario de Bio-Orgánica "Antonio González"; España
Fil: Fu, Guodong. Southeast University; China
description In this work, hydrothermal methods and deep eutectic solvents were combined for the first time to prepare tungsten trioxide nanoparticles in an easy and green manner improving their optical and photochromic properties. Characterization of the synthesized nanoparticles was performed via Fourier transform infrared spectroscopy, X-ray diffraction, ultraviolet visible spectroscopy, scanning electron microscopy, energy dispersive X-ray, transform electron microscopy, dynamic light scattering, thermogravimetric analysis, and X-ray photoelectron spectroscopy. The average size of the spherical nanoparticles was ca. 1.83 nm as shown by TEM, and the nanoparticles exhibited high thermostability at least until 900 1C, and photostability and photosensitivity when they were exposed to UV light. Additionally, synthesized tungsten trioxide nanoparticles were found to be nontoxic with maximum cell viability observed even at 100 mg mL1 , making them potential candidates for biomedical applications.
publishDate 2024
dc.date.none.fl_str_mv 2024-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/260411
Ogungbesan, Shephrah Olubusola; Ejeromedoghene, Onome; Moglie, Yanina Fernanda; Buxaderas Perez de Armiñan, Eduardo; Cui, Bingbing; et al.; Deep eutectic solvent assisted hydrothermal synthesis of photochromic and nontoxic tungsten oxide nanoparticles; Royal Society of Chemistry; New Journal of Chemistry; 48; 35; 8-2024; 15428-15435
1144-0546
CONICET Digital
CONICET
url http://hdl.handle.net/11336/260411
identifier_str_mv Ogungbesan, Shephrah Olubusola; Ejeromedoghene, Onome; Moglie, Yanina Fernanda; Buxaderas Perez de Armiñan, Eduardo; Cui, Bingbing; et al.; Deep eutectic solvent assisted hydrothermal synthesis of photochromic and nontoxic tungsten oxide nanoparticles; Royal Society of Chemistry; New Journal of Chemistry; 48; 35; 8-2024; 15428-15435
1144-0546
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://xlink.rsc.org/?DOI=D4NJ02995J
info:eu-repo/semantics/altIdentifier/doi/10.1039/D4NJ02995J
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269528723030016
score 13.13397

Publicaciones similares