Phase Identification of Cu-In Alloys with 45 and 41.25 at.% In Compositions

Autores
Baque, Laura Cecilia; Torrado, Darío; Aurelio, Gabriela; Lamas, Diego Germán; Aricó, Sergio Fabián; Craievich, Aldo F.; Sommadossi, Silvana Andrea
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, the thermal stability of Cu-In alloys with 45.0 and 41.2 at.% In nominal compositions was investigated by differential scanning calorimetry (DSC), scanning electron microscopy, wavelength dispersive spectroscopy, and in-situ synchrotron x-ray powder diffraction (S-PXRD) over a temperature range from 25 up to 400C. The studied samples are mainly composed of a Cu11In9 phase together with minor amounts of the B phase (based on the NiAs-Ni2In type structure and, in one of the samples, with a minor amount of pure In. No evidence of the Cu10In7 (41.2 at.% In) phase was detected, not even in the sample with 41.2 at.% In nominal overall composition. The combined use of the S-PXRD and DSC techniques allowed us to identify two phase transitions involving the Cu11In9 phase, one of them corresponding to the etha' = B + Cu11In9 reaction at T = 290C and the other to the peritectic etha' + L = Cu11In9 reaction at T = 311C.
Fil: Baque, Laura Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comision Nacional de Energia Atomica. Gerencia de Area de Aplicaciones de la Tecnología Nuclear; Argentina
Fil: Torrado, Darío. Universidad Nacional del Comahue. Facultad de Ingeniería; Argentina
Fil: Aurelio, Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Lamas, Diego Germán. Universidad Nacional del Comahue. Facultad de Ingeniería; Argentina
Fil: Aricó, Sergio Fabián. Comision Nacional de Energia Atomica. Gerencia de Area de Aplicaciones de la Tecnología Nuclear; Argentina
Fil: Craievich, Aldo F.. Universidade de Sao Paulo; Brasil
Fil: Sommadossi, Silvana Andrea. Universidad Nacional del Comahue. Facultad de Ingeniería; Argentina
Materia
Cu-In Alloys
Differential Scanning Calorimetry (Dsc)
Intermetallic Compounds
Phase Transitions
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/27552
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/27552
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network_name_str CONICET Digital (CONICET)
spelling Phase Identification of Cu-In Alloys with 45 and 41.25 at.% In CompositionsBaque, Laura CeciliaTorrado, DaríoAurelio, GabrielaLamas, Diego GermánAricó, Sergio FabiánCraievich, Aldo F.Sommadossi, Silvana AndreaCu-In AlloysDifferential Scanning Calorimetry (Dsc)Intermetallic CompoundsPhase TransitionsIn this work, the thermal stability of Cu-In alloys with 45.0 and 41.2 at.% In nominal compositions was investigated by differential scanning calorimetry (DSC), scanning electron microscopy, wavelength dispersive spectroscopy, and in-situ synchrotron x-ray powder diffraction (S-PXRD) over a temperature range from 25 up to 400C. The studied samples are mainly composed of a Cu11In9 phase together with minor amounts of the B phase (based on the NiAs-Ni2In type structure and, in one of the samples, with a minor amount of pure In. No evidence of the Cu10In7 (41.2 at.% In) phase was detected, not even in the sample with 41.2 at.% In nominal overall composition. The combined use of the S-PXRD and DSC techniques allowed us to identify two phase transitions involving the Cu11In9 phase, one of them corresponding to the etha' = B + Cu11In9 reaction at T = 290C and the other to the peritectic etha' + L = Cu11In9 reaction at T = 311C.Fil: Baque, Laura Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comision Nacional de Energia Atomica. Gerencia de Area de Aplicaciones de la Tecnología Nuclear; ArgentinaFil: Torrado, Darío. Universidad Nacional del Comahue. Facultad de Ingeniería; ArgentinaFil: Aurelio, Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Lamas, Diego Germán. Universidad Nacional del Comahue. Facultad de Ingeniería; ArgentinaFil: Aricó, Sergio Fabián. Comision Nacional de Energia Atomica. Gerencia de Area de Aplicaciones de la Tecnología Nuclear; ArgentinaFil: Craievich, Aldo F.. Universidade de Sao Paulo; BrasilFil: Sommadossi, Silvana Andrea. Universidad Nacional del Comahue. Facultad de Ingeniería; ArgentinaSpringer2014-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/27552Baque, Laura Cecilia; Torrado, Darío; Aurelio, Gabriela; Lamas, Diego Germán; Aricó, Sergio Fabián; et al.; Phase Identification of Cu-In Alloys with 45 and 41.25 at.% In Compositions; Springer; Journal Of Phase Equilibria And Diffusion; 35; 1; 2-2014; 2-101547-7037CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1007/s11669-013-0265-7info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007/s11669-013-0265-7info:eu-repo/semantics/altIdentifier/url/http://orbit.dtu.dk/en/publications/phase-identification-of-cuin-alloys-with-45-and-4125-at-in-compositions(815fed96-0704-4a59-b0d1-0e7a58ce275f)/export.htmlinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:00:48Zoai:ri.conicet.gov.ar:11336/27552instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:00:48.885CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Phase Identification of Cu-In Alloys with 45 and 41.25 at.% In Compositions
title Phase Identification of Cu-In Alloys with 45 and 41.25 at.% In Compositions
spellingShingle Phase Identification of Cu-In Alloys with 45 and 41.25 at.% In Compositions
Baque, Laura Cecilia
Cu-In Alloys
Differential Scanning Calorimetry (Dsc)
Intermetallic Compounds
Phase Transitions
title_short Phase Identification of Cu-In Alloys with 45 and 41.25 at.% In Compositions
title_full Phase Identification of Cu-In Alloys with 45 and 41.25 at.% In Compositions
title_fullStr Phase Identification of Cu-In Alloys with 45 and 41.25 at.% In Compositions
title_full_unstemmed Phase Identification of Cu-In Alloys with 45 and 41.25 at.% In Compositions
title_sort Phase Identification of Cu-In Alloys with 45 and 41.25 at.% In Compositions
dc.creator.none.fl_str_mv Baque, Laura Cecilia
Torrado, Darío
Aurelio, Gabriela
Lamas, Diego Germán
Aricó, Sergio Fabián
Craievich, Aldo F.
Sommadossi, Silvana Andrea
author Baque, Laura Cecilia
author_facet Baque, Laura Cecilia
Torrado, Darío
Aurelio, Gabriela
Lamas, Diego Germán
Aricó, Sergio Fabián
Craievich, Aldo F.
Sommadossi, Silvana Andrea
author_role author
author2 Torrado, Darío
Aurelio, Gabriela
Lamas, Diego Germán
Aricó, Sergio Fabián
Craievich, Aldo F.
Sommadossi, Silvana Andrea
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Cu-In Alloys
Differential Scanning Calorimetry (Dsc)
Intermetallic Compounds
Phase Transitions
topic Cu-In Alloys
Differential Scanning Calorimetry (Dsc)
Intermetallic Compounds
Phase Transitions
dc.description.none.fl_txt_mv In this work, the thermal stability of Cu-In alloys with 45.0 and 41.2 at.% In nominal compositions was investigated by differential scanning calorimetry (DSC), scanning electron microscopy, wavelength dispersive spectroscopy, and in-situ synchrotron x-ray powder diffraction (S-PXRD) over a temperature range from 25 up to 400C. The studied samples are mainly composed of a Cu11In9 phase together with minor amounts of the B phase (based on the NiAs-Ni2In type structure and, in one of the samples, with a minor amount of pure In. No evidence of the Cu10In7 (41.2 at.% In) phase was detected, not even in the sample with 41.2 at.% In nominal overall composition. The combined use of the S-PXRD and DSC techniques allowed us to identify two phase transitions involving the Cu11In9 phase, one of them corresponding to the etha' = B + Cu11In9 reaction at T = 290C and the other to the peritectic etha' + L = Cu11In9 reaction at T = 311C.
Fil: Baque, Laura Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comision Nacional de Energia Atomica. Gerencia de Area de Aplicaciones de la Tecnología Nuclear; Argentina
Fil: Torrado, Darío. Universidad Nacional del Comahue. Facultad de Ingeniería; Argentina
Fil: Aurelio, Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Lamas, Diego Germán. Universidad Nacional del Comahue. Facultad de Ingeniería; Argentina
Fil: Aricó, Sergio Fabián. Comision Nacional de Energia Atomica. Gerencia de Area de Aplicaciones de la Tecnología Nuclear; Argentina
Fil: Craievich, Aldo F.. Universidade de Sao Paulo; Brasil
Fil: Sommadossi, Silvana Andrea. Universidad Nacional del Comahue. Facultad de Ingeniería; Argentina
description In this work, the thermal stability of Cu-In alloys with 45.0 and 41.2 at.% In nominal compositions was investigated by differential scanning calorimetry (DSC), scanning electron microscopy, wavelength dispersive spectroscopy, and in-situ synchrotron x-ray powder diffraction (S-PXRD) over a temperature range from 25 up to 400C. The studied samples are mainly composed of a Cu11In9 phase together with minor amounts of the B phase (based on the NiAs-Ni2In type structure and, in one of the samples, with a minor amount of pure In. No evidence of the Cu10In7 (41.2 at.% In) phase was detected, not even in the sample with 41.2 at.% In nominal overall composition. The combined use of the S-PXRD and DSC techniques allowed us to identify two phase transitions involving the Cu11In9 phase, one of them corresponding to the etha' = B + Cu11In9 reaction at T = 290C and the other to the peritectic etha' + L = Cu11In9 reaction at T = 311C.
publishDate 2014
dc.date.none.fl_str_mv 2014-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/27552
Baque, Laura Cecilia; Torrado, Darío; Aurelio, Gabriela; Lamas, Diego Germán; Aricó, Sergio Fabián; et al.; Phase Identification of Cu-In Alloys with 45 and 41.25 at.% In Compositions; Springer; Journal Of Phase Equilibria And Diffusion; 35; 1; 2-2014; 2-10
1547-7037
CONICET Digital
CONICET
url http://hdl.handle.net/11336/27552
identifier_str_mv Baque, Laura Cecilia; Torrado, Darío; Aurelio, Gabriela; Lamas, Diego Germán; Aricó, Sergio Fabián; et al.; Phase Identification of Cu-In Alloys with 45 and 41.25 at.% In Compositions; Springer; Journal Of Phase Equilibria And Diffusion; 35; 1; 2-2014; 2-10
1547-7037
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1007/s11669-013-0265-7
info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007/s11669-013-0265-7
info:eu-repo/semantics/altIdentifier/url/http://orbit.dtu.dk/en/publications/phase-identification-of-cuin-alloys-with-45-and-4125-at-in-compositions(815fed96-0704-4a59-b0d1-0e7a58ce275f)/export.html
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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