Spherulitic growth and crystallization kinetics in PHB/DGEBA blends

Autores
Tognana, Sebastian Alberto; Salgueiro, Walter; Silva, Leonel Ignacio
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A study of spherulitic growth in PHB and PHB/DGEBA (poly(3-hydroxybutyrate)/diglycidyl ether ofbisphenol A) blends with PHB/DGEBA weight ratios of 100/0, 90/10, 80/20, 70/30 and 60/40 crystallizedat temperatures in the range of 45?110◦C is carried out. The spherulitic growth rates at the crystallizationtemperatures are studied by optical microscopy. Differential scanning calorimetry is used to study thesame isothermal process to fit the results by means of the Avrami theory to determine the characteristicparameters of the process. The obtained characteristic parameters are compared to the spherulitic growthrates that are determined by optical microscopy. The observed differences are discussed considering theprocess of nucleation. An increase in the secondary crystallization process is observed with increasingcrystallization temperature and DGEBA content in the blend. Changes in the crystallization associatedwith an increase in the rigid amorphous fraction (RAF) mobility are discussed.
Fil: Tognana, Sebastian Alberto. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina
Fil: Salgueiro, Walter. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Tandil. Centro de Investigaciones En Física E Ingeniería del Centro de la Provincia de Buenos Aires; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina
Fil: Silva, Leonel Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Materia
Crystallization
Blends
Phb
Dgeba
Poly(3-Hydroxybutyrate)
Epoxy Resin
Differential Scanning
Calorimetry (Dsc)
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/10419
Acceder
id CONICETDig_414813d4076b743745a4f915f269570c
oai_identifier_str oai:ri.conicet.gov.ar:11336/10419
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Spherulitic growth and crystallization kinetics in PHB/DGEBA blendsTognana, Sebastian AlbertoSalgueiro, WalterSilva, Leonel IgnacioCrystallizationBlendsPhbDgebaPoly(3-Hydroxybutyrate)Epoxy ResinDifferential ScanningCalorimetry (Dsc)https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1A study of spherulitic growth in PHB and PHB/DGEBA (poly(3-hydroxybutyrate)/diglycidyl ether ofbisphenol A) blends with PHB/DGEBA weight ratios of 100/0, 90/10, 80/20, 70/30 and 60/40 crystallizedat temperatures in the range of 45?110◦C is carried out. The spherulitic growth rates at the crystallizationtemperatures are studied by optical microscopy. Differential scanning calorimetry is used to study thesame isothermal process to fit the results by means of the Avrami theory to determine the characteristicparameters of the process. The obtained characteristic parameters are compared to the spherulitic growthrates that are determined by optical microscopy. The observed differences are discussed considering theprocess of nucleation. An increase in the secondary crystallization process is observed with increasingcrystallization temperature and DGEBA content in the blend. Changes in the crystallization associatedwith an increase in the rigid amorphous fraction (RAF) mobility are discussed.Fil: Tognana, Sebastian Alberto. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; ArgentinaFil: Salgueiro, Walter. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Tandil. Centro de Investigaciones En Física E Ingeniería del Centro de la Provincia de Buenos Aires; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; ArgentinaFil: Silva, Leonel Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaElsevier Science2015-11-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/10419Tognana, Sebastian Alberto; Salgueiro, Walter; Silva, Leonel Ignacio; Spherulitic growth and crystallization kinetics in PHB/DGEBA blends; Elsevier Science; Thermochimica Acta; 623; 10-11-2015; 1-80040-6031enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0040603115004438info:eu-repo/semantics/altIdentifier/doi/10.1016/j.tca.2015.11.009info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:09:25Zoai:ri.conicet.gov.ar:11336/10419instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:09:25.29CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Spherulitic growth and crystallization kinetics in PHB/DGEBA blends
title Spherulitic growth and crystallization kinetics in PHB/DGEBA blends
spellingShingle Spherulitic growth and crystallization kinetics in PHB/DGEBA blends
Tognana, Sebastian Alberto
Crystallization
Blends
Phb
Dgeba
Poly(3-Hydroxybutyrate)
Epoxy Resin
Differential Scanning
Calorimetry (Dsc)
title_short Spherulitic growth and crystallization kinetics in PHB/DGEBA blends
title_full Spherulitic growth and crystallization kinetics in PHB/DGEBA blends
title_fullStr Spherulitic growth and crystallization kinetics in PHB/DGEBA blends
title_full_unstemmed Spherulitic growth and crystallization kinetics in PHB/DGEBA blends
title_sort Spherulitic growth and crystallization kinetics in PHB/DGEBA blends
dc.creator.none.fl_str_mv Tognana, Sebastian Alberto
Salgueiro, Walter
Silva, Leonel Ignacio
author Tognana, Sebastian Alberto
author_facet Tognana, Sebastian Alberto
Salgueiro, Walter
Silva, Leonel Ignacio
author_role author
author2 Salgueiro, Walter
Silva, Leonel Ignacio
author2_role author
author
dc.subject.none.fl_str_mv Crystallization
Blends
Phb
Dgeba
Poly(3-Hydroxybutyrate)
Epoxy Resin
Differential Scanning
Calorimetry (Dsc)
topic Crystallization
Blends
Phb
Dgeba
Poly(3-Hydroxybutyrate)
Epoxy Resin
Differential Scanning
Calorimetry (Dsc)
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A study of spherulitic growth in PHB and PHB/DGEBA (poly(3-hydroxybutyrate)/diglycidyl ether ofbisphenol A) blends with PHB/DGEBA weight ratios of 100/0, 90/10, 80/20, 70/30 and 60/40 crystallizedat temperatures in the range of 45?110◦C is carried out. The spherulitic growth rates at the crystallizationtemperatures are studied by optical microscopy. Differential scanning calorimetry is used to study thesame isothermal process to fit the results by means of the Avrami theory to determine the characteristicparameters of the process. The obtained characteristic parameters are compared to the spherulitic growthrates that are determined by optical microscopy. The observed differences are discussed considering theprocess of nucleation. An increase in the secondary crystallization process is observed with increasingcrystallization temperature and DGEBA content in the blend. Changes in the crystallization associatedwith an increase in the rigid amorphous fraction (RAF) mobility are discussed.
Fil: Tognana, Sebastian Alberto. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina
Fil: Salgueiro, Walter. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Tandil. Centro de Investigaciones En Física E Ingeniería del Centro de la Provincia de Buenos Aires; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina
Fil: Silva, Leonel Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
description A study of spherulitic growth in PHB and PHB/DGEBA (poly(3-hydroxybutyrate)/diglycidyl ether ofbisphenol A) blends with PHB/DGEBA weight ratios of 100/0, 90/10, 80/20, 70/30 and 60/40 crystallizedat temperatures in the range of 45?110◦C is carried out. The spherulitic growth rates at the crystallizationtemperatures are studied by optical microscopy. Differential scanning calorimetry is used to study thesame isothermal process to fit the results by means of the Avrami theory to determine the characteristicparameters of the process. The obtained characteristic parameters are compared to the spherulitic growthrates that are determined by optical microscopy. The observed differences are discussed considering theprocess of nucleation. An increase in the secondary crystallization process is observed with increasingcrystallization temperature and DGEBA content in the blend. Changes in the crystallization associatedwith an increase in the rigid amorphous fraction (RAF) mobility are discussed.
publishDate 2015
dc.date.none.fl_str_mv 2015-11-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/10419
Tognana, Sebastian Alberto; Salgueiro, Walter; Silva, Leonel Ignacio; Spherulitic growth and crystallization kinetics in PHB/DGEBA blends; Elsevier Science; Thermochimica Acta; 623; 10-11-2015; 1-8
0040-6031
url http://hdl.handle.net/11336/10419
identifier_str_mv Tognana, Sebastian Alberto; Salgueiro, Walter; Silva, Leonel Ignacio; Spherulitic growth and crystallization kinetics in PHB/DGEBA blends; Elsevier Science; Thermochimica Acta; 623; 10-11-2015; 1-8
0040-6031
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0040603115004438
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.tca.2015.11.009
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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