Probing the structure of nanograined CuO powders

Autores
Bianchi, Ana Elisa; Plivelic, Tomás S.; Punte, Graciela María del Carmen; Torriani, Iris L.
Año de publicación
2008
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The microstructural properties of polycrystalline CuO powders and their evolution during controlled high energetic ball milling (HEBM) were studied using conventional X-ray diffraction (XRD) techniques and in situ temperature-dependent small and wide angle scattering (SAXS–WAXS) synchrotron radiation experiments. Volume weighted average grain size, unit cell expansion, oxygen deficiency, and microstrain values as a function of milling time were obtained from XRD. SAXS data revealed different nanostructures for samples synthesized by one-step solid-state reaction (SSR) or HEBM-treated powders. The latter presented the characteristics of a multilayered nanoscale solid system with surface fractal behavior. Correlation of the XRD microstructural parameters and the power law exponent of the SAXS curves as a function of temperature and milling time provided a coherent picture of the structure of HEBM-treated powders. The overall structural information presented in this article may shed some light on the macroscopic physical properties of CuO nanostructures.
Facultad de Ciencias Exactas
Materia
Ciencias Exactas
Física
Isothermal Treatment
Surface Fractal Dimension
Unit Cell Expansion
WAXS Experiment
Surface Fractal Behavior
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/142370
Acceder
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oai_identifier_str oai:sedici.unlp.edu.ar:10915/142370
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Probing the structure of nanograined CuO powdersBianchi, Ana ElisaPlivelic, Tomás S.Punte, Graciela María del CarmenTorriani, Iris L.Ciencias ExactasFísicaIsothermal TreatmentSurface Fractal DimensionUnit Cell ExpansionWAXS ExperimentSurface Fractal BehaviorThe microstructural properties of polycrystalline CuO powders and their evolution during controlled high energetic ball milling (HEBM) were studied using conventional X-ray diffraction (XRD) techniques and in situ temperature-dependent small and wide angle scattering (SAXS–WAXS) synchrotron radiation experiments. Volume weighted average grain size, unit cell expansion, oxygen deficiency, and microstrain values as a function of milling time were obtained from XRD. SAXS data revealed different nanostructures for samples synthesized by one-step solid-state reaction (SSR) or HEBM-treated powders. The latter presented the characteristics of a multilayered nanoscale solid system with surface fractal behavior. Correlation of the XRD microstructural parameters and the power law exponent of the SAXS curves as a function of temperature and milling time provided a coherent picture of the structure of HEBM-treated powders. The overall structural information presented in this article may shed some light on the macroscopic physical properties of CuO nanostructures.Facultad de Ciencias Exactas2008-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf3704-3712http://sedici.unlp.edu.ar/handle/10915/142370enginfo:eu-repo/semantics/altIdentifier/issn/0022-2461info:eu-repo/semantics/altIdentifier/issn/1573-4803info:eu-repo/semantics/altIdentifier/doi/10.1007/s10853-008-2600-7info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:32:32Zoai:sedici.unlp.edu.ar:10915/142370Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:32:33.046SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Probing the structure of nanograined CuO powders
title Probing the structure of nanograined CuO powders
spellingShingle Probing the structure of nanograined CuO powders
Bianchi, Ana Elisa
Ciencias Exactas
Física
Isothermal Treatment
Surface Fractal Dimension
Unit Cell Expansion
WAXS Experiment
Surface Fractal Behavior
title_short Probing the structure of nanograined CuO powders
title_full Probing the structure of nanograined CuO powders
title_fullStr Probing the structure of nanograined CuO powders
title_full_unstemmed Probing the structure of nanograined CuO powders
title_sort Probing the structure of nanograined CuO powders
dc.creator.none.fl_str_mv Bianchi, Ana Elisa
Plivelic, Tomás S.
Punte, Graciela María del Carmen
Torriani, Iris L.
author Bianchi, Ana Elisa
author_facet Bianchi, Ana Elisa
Plivelic, Tomás S.
Punte, Graciela María del Carmen
Torriani, Iris L.
author_role author
author2 Plivelic, Tomás S.
Punte, Graciela María del Carmen
Torriani, Iris L.
author2_role author
author
author
dc.subject.none.fl_str_mv Ciencias Exactas
Física
Isothermal Treatment
Surface Fractal Dimension
Unit Cell Expansion
WAXS Experiment
Surface Fractal Behavior
topic Ciencias Exactas
Física
Isothermal Treatment
Surface Fractal Dimension
Unit Cell Expansion
WAXS Experiment
Surface Fractal Behavior
dc.description.none.fl_txt_mv The microstructural properties of polycrystalline CuO powders and their evolution during controlled high energetic ball milling (HEBM) were studied using conventional X-ray diffraction (XRD) techniques and in situ temperature-dependent small and wide angle scattering (SAXS–WAXS) synchrotron radiation experiments. Volume weighted average grain size, unit cell expansion, oxygen deficiency, and microstrain values as a function of milling time were obtained from XRD. SAXS data revealed different nanostructures for samples synthesized by one-step solid-state reaction (SSR) or HEBM-treated powders. The latter presented the characteristics of a multilayered nanoscale solid system with surface fractal behavior. Correlation of the XRD microstructural parameters and the power law exponent of the SAXS curves as a function of temperature and milling time provided a coherent picture of the structure of HEBM-treated powders. The overall structural information presented in this article may shed some light on the macroscopic physical properties of CuO nanostructures.
Facultad de Ciencias Exactas
description The microstructural properties of polycrystalline CuO powders and their evolution during controlled high energetic ball milling (HEBM) were studied using conventional X-ray diffraction (XRD) techniques and in situ temperature-dependent small and wide angle scattering (SAXS–WAXS) synchrotron radiation experiments. Volume weighted average grain size, unit cell expansion, oxygen deficiency, and microstrain values as a function of milling time were obtained from XRD. SAXS data revealed different nanostructures for samples synthesized by one-step solid-state reaction (SSR) or HEBM-treated powders. The latter presented the characteristics of a multilayered nanoscale solid system with surface fractal behavior. Correlation of the XRD microstructural parameters and the power law exponent of the SAXS curves as a function of temperature and milling time provided a coherent picture of the structure of HEBM-treated powders. The overall structural information presented in this article may shed some light on the macroscopic physical properties of CuO nanostructures.
publishDate 2008
dc.date.none.fl_str_mv 2008-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/142370
url http://sedici.unlp.edu.ar/handle/10915/142370
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0022-2461
info:eu-repo/semantics/altIdentifier/issn/1573-4803
info:eu-repo/semantics/altIdentifier/doi/10.1007/s10853-008-2600-7
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
3704-3712
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.070432

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