Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C₄H₉)₄N]₂[Fe(CN)₅NO]·2H₂O, and vibrational spectra of ground and metastable excited states of the dihydrate and t...

Autores
Chacón Villalba, María Elizabeth; Güida, Jorge Alberto; Piro, Oscar Enrique; Castellano, Eduardo Ernesto; Aymonino, Pedro José
Año de publicación
2001
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The crystal structure of tetrabutylammonium nitroprusside dihydrate (TBANPDH, [(C₄H₉)₄N]₂[Fe(CN)₅NO]·2H₂O) was determined by single crystal X-ray diffraction (XRD) and the compound was also studied, as well as the anhydrous salt (TBANP), by room and low temperature Fourier Transform Infra-Red (FTIR) and room temperature Fourier Transform Near Infra-Red Raman (FTNIRR) spectroscopies. In addition to the ground states (GS), the metastable excited states (MSI and MSII) generated by laser excitation (488 nm) at low temperature were IR studied, both of the dihydrate and the anhydrate. TBANPDH crystallizes in the trigonal space group P3₂21, D⁶₃, with a = b = 13.777(2), c = 22.039(2) Å, and Z = 3. The structure was solved employing 1273 independent XR reflections, with I > 2σ(I), by Patterson and Fourier methods and refined by full-matrix least-squares to R1 = 0.054.
Centro de Química Inorgánica
Instituto de Física La Plata
Materia
Ciencias Exactas
Química
tetrabutylammonium nitroprusside
crystal structure
vibrational spectra
metastable states
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/146406
Acceder
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oai_identifier_str oai:sedici.unlp.edu.ar:10915/146406
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C₄H₉)₄N]₂[Fe(CN)₅NO]·2H₂O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrateChacón Villalba, María ElizabethGüida, Jorge AlbertoPiro, Oscar EnriqueCastellano, Eduardo ErnestoAymonino, Pedro JoséCiencias ExactasQuímicatetrabutylammonium nitroprussidecrystal structurevibrational spectrametastable statesThe crystal structure of tetrabutylammonium nitroprusside dihydrate (TBANPDH, [(C₄H₉)₄N]₂[Fe(CN)₅NO]·2H₂O) was determined by single crystal X-ray diffraction (XRD) and the compound was also studied, as well as the anhydrous salt (TBANP), by room and low temperature Fourier Transform Infra-Red (FTIR) and room temperature Fourier Transform Near Infra-Red Raman (FTNIRR) spectroscopies. In addition to the ground states (GS), the metastable excited states (MSI and MSII) generated by laser excitation (488 nm) at low temperature were IR studied, both of the dihydrate and the anhydrate. TBANPDH crystallizes in the trigonal space group P3₂21, D⁶₃, with a = b = 13.777(2), c = 22.039(2) Å, and Z = 3. The structure was solved employing 1273 independent XR reflections, with I > 2σ(I), by Patterson and Fourier methods and refined by full-matrix least-squares to R1 = 0.054.Centro de Química InorgánicaInstituto de Física La Plata2001-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf155-166http://sedici.unlp.edu.ar/handle/10915/146406enginfo:eu-repo/semantics/altIdentifier/issn/1074-1542info:eu-repo/semantics/altIdentifier/issn/1572-8854info:eu-repo/semantics/altIdentifier/doi/10.1023/a:1014367821364info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-17T10:15:10Zoai:sedici.unlp.edu.ar:10915/146406Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-17 10:15:10.283SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C₄H₉)₄N]₂[Fe(CN)₅NO]·2H₂O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrate
title Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C₄H₉)₄N]₂[Fe(CN)₅NO]·2H₂O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrate
spellingShingle Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C₄H₉)₄N]₂[Fe(CN)₅NO]·2H₂O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrate
Chacón Villalba, María Elizabeth
Ciencias Exactas
Química
tetrabutylammonium nitroprusside
crystal structure
vibrational spectra
metastable states
title_short Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C₄H₉)₄N]₂[Fe(CN)₅NO]·2H₂O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrate
title_full Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C₄H₉)₄N]₂[Fe(CN)₅NO]·2H₂O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrate
title_fullStr Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C₄H₉)₄N]₂[Fe(CN)₅NO]·2H₂O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrate
title_full_unstemmed Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C₄H₉)₄N]₂[Fe(CN)₅NO]·2H₂O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrate
title_sort Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C₄H₉)₄N]₂[Fe(CN)₅NO]·2H₂O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrate
dc.creator.none.fl_str_mv Chacón Villalba, María Elizabeth
Güida, Jorge Alberto
Piro, Oscar Enrique
Castellano, Eduardo Ernesto
Aymonino, Pedro José
author Chacón Villalba, María Elizabeth
author_facet Chacón Villalba, María Elizabeth
Güida, Jorge Alberto
Piro, Oscar Enrique
Castellano, Eduardo Ernesto
Aymonino, Pedro José
author_role author
author2 Güida, Jorge Alberto
Piro, Oscar Enrique
Castellano, Eduardo Ernesto
Aymonino, Pedro José
author2_role author
author
author
author
dc.subject.none.fl_str_mv Ciencias Exactas
Química
tetrabutylammonium nitroprusside
crystal structure
vibrational spectra
metastable states
topic Ciencias Exactas
Química
tetrabutylammonium nitroprusside
crystal structure
vibrational spectra
metastable states
dc.description.none.fl_txt_mv The crystal structure of tetrabutylammonium nitroprusside dihydrate (TBANPDH, [(C₄H₉)₄N]₂[Fe(CN)₅NO]·2H₂O) was determined by single crystal X-ray diffraction (XRD) and the compound was also studied, as well as the anhydrous salt (TBANP), by room and low temperature Fourier Transform Infra-Red (FTIR) and room temperature Fourier Transform Near Infra-Red Raman (FTNIRR) spectroscopies. In addition to the ground states (GS), the metastable excited states (MSI and MSII) generated by laser excitation (488 nm) at low temperature were IR studied, both of the dihydrate and the anhydrate. TBANPDH crystallizes in the trigonal space group P3₂21, D⁶₃, with a = b = 13.777(2), c = 22.039(2) Å, and Z = 3. The structure was solved employing 1273 independent XR reflections, with I > 2σ(I), by Patterson and Fourier methods and refined by full-matrix least-squares to R1 = 0.054.
Centro de Química Inorgánica
Instituto de Física La Plata
description The crystal structure of tetrabutylammonium nitroprusside dihydrate (TBANPDH, [(C₄H₉)₄N]₂[Fe(CN)₅NO]·2H₂O) was determined by single crystal X-ray diffraction (XRD) and the compound was also studied, as well as the anhydrous salt (TBANP), by room and low temperature Fourier Transform Infra-Red (FTIR) and room temperature Fourier Transform Near Infra-Red Raman (FTNIRR) spectroscopies. In addition to the ground states (GS), the metastable excited states (MSI and MSII) generated by laser excitation (488 nm) at low temperature were IR studied, both of the dihydrate and the anhydrate. TBANPDH crystallizes in the trigonal space group P3₂21, D⁶₃, with a = b = 13.777(2), c = 22.039(2) Å, and Z = 3. The structure was solved employing 1273 independent XR reflections, with I > 2σ(I), by Patterson and Fourier methods and refined by full-matrix least-squares to R1 = 0.054.
publishDate 2001
dc.date.none.fl_str_mv 2001-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/146406
url http://sedici.unlp.edu.ar/handle/10915/146406
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/1074-1542
info:eu-repo/semantics/altIdentifier/issn/1572-8854
info:eu-repo/semantics/altIdentifier/doi/10.1023/a:1014367821364
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
155-166
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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