Crystal and molecular structure determination, TGA, DTA, and infrared and Raman spectra of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O
- Autores
- Soria, Delia Beatriz; Piro, Oscar Enrique; Castellano, Eduardo Ernesto; Aymonino, Pedro José
- Año de publicación
- 1999
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The crystal structure of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O, has been determined from X-ray diffraction data and refined using direct and Fourier methods to R = 0.066 and Rw = 0.075, employing 1894 independent reflections with I > 3 (I). The substance crystallizes in the monoclinic space group C2/c (C62h), with a = 13.987(2), b = 10.241(1), c = 18.151(1) Å, β = 110.94°, and Z = 8. Anions are located at C1 sites, one per asymmetric unit, and are slightly distorted octahedra. TGA, DTA, FTIR, and FTIR Raman results were interpreted on the basis of the formula of the compound, its crystal structure, and the behavior of other nitroprussides.
Centro de Química Inorgánica - Materia
-
Química
Rubidium nitroprusside monohydrate
Crystal structure
Properties - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by-nc-sa/4.0/
- Repositorio
.jpg)
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/146429
Ver los metadatos del registro completo
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Crystal and molecular structure determination, TGA, DTA, and infrared and Raman spectra of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂OSoria, Delia BeatrizPiro, Oscar EnriqueCastellano, Eduardo ErnestoAymonino, Pedro JoséQuímicaRubidium nitroprusside monohydrateCrystal structurePropertiesThe crystal structure of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O, has been determined from X-ray diffraction data and refined using direct and Fourier methods to R = 0.066 and Rw = 0.075, employing 1894 independent reflections with I > 3 (I). The substance crystallizes in the monoclinic space group C2/c (C62h), with a = 13.987(2), b = 10.241(1), c = 18.151(1) Å, β = 110.94°, and Z = 8. Anions are located at C1 sites, one per asymmetric unit, and are slightly distorted octahedra. TGA, DTA, FTIR, and FTIR Raman results were interpreted on the basis of the formula of the compound, its crystal structure, and the behavior of other nitroprussides.Centro de Química Inorgánica1999info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf75-80http://sedici.unlp.edu.ar/handle/10915/146429enginfo:eu-repo/semantics/altIdentifier/issn/1074-1542info:eu-repo/semantics/altIdentifier/issn/1572-8854info:eu-repo/semantics/altIdentifier/issn/0308-4086info:eu-repo/semantics/altIdentifier/issn/0277-8068info:eu-repo/semantics/altIdentifier/doi/10.1023/a:1009575415668info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-17T10:15:11Zoai:sedici.unlp.edu.ar:10915/146429Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-17 10:15:11.461SEDICI (UNLP) - Universidad Nacional de La Platafalse |
| dc.title.none.fl_str_mv |
Crystal and molecular structure determination, TGA, DTA, and infrared and Raman spectra of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O |
| title |
Crystal and molecular structure determination, TGA, DTA, and infrared and Raman spectra of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O |
| spellingShingle |
Crystal and molecular structure determination, TGA, DTA, and infrared and Raman spectra of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O Soria, Delia Beatriz Química Rubidium nitroprusside monohydrate Crystal structure Properties |
| title_short |
Crystal and molecular structure determination, TGA, DTA, and infrared and Raman spectra of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O |
| title_full |
Crystal and molecular structure determination, TGA, DTA, and infrared and Raman spectra of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O |
| title_fullStr |
Crystal and molecular structure determination, TGA, DTA, and infrared and Raman spectra of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O |
| title_full_unstemmed |
Crystal and molecular structure determination, TGA, DTA, and infrared and Raman spectra of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O |
| title_sort |
Crystal and molecular structure determination, TGA, DTA, and infrared and Raman spectra of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O |
| dc.creator.none.fl_str_mv |
Soria, Delia Beatriz Piro, Oscar Enrique Castellano, Eduardo Ernesto Aymonino, Pedro José |
| author |
Soria, Delia Beatriz |
| author_facet |
Soria, Delia Beatriz Piro, Oscar Enrique Castellano, Eduardo Ernesto Aymonino, Pedro José |
| author_role |
author |
| author2 |
Piro, Oscar Enrique Castellano, Eduardo Ernesto Aymonino, Pedro José |
| author2_role |
author author author |
| dc.subject.none.fl_str_mv |
Química Rubidium nitroprusside monohydrate Crystal structure Properties |
| topic |
Química Rubidium nitroprusside monohydrate Crystal structure Properties |
| dc.description.none.fl_txt_mv |
The crystal structure of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O, has been determined from X-ray diffraction data and refined using direct and Fourier methods to R = 0.066 and Rw = 0.075, employing 1894 independent reflections with I > 3 (I). The substance crystallizes in the monoclinic space group C2/c (C62h), with a = 13.987(2), b = 10.241(1), c = 18.151(1) Å, β = 110.94°, and Z = 8. Anions are located at C1 sites, one per asymmetric unit, and are slightly distorted octahedra. TGA, DTA, FTIR, and FTIR Raman results were interpreted on the basis of the formula of the compound, its crystal structure, and the behavior of other nitroprussides. Centro de Química Inorgánica |
| description |
The crystal structure of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O, has been determined from X-ray diffraction data and refined using direct and Fourier methods to R = 0.066 and Rw = 0.075, employing 1894 independent reflections with I > 3 (I). The substance crystallizes in the monoclinic space group C2/c (C62h), with a = 13.987(2), b = 10.241(1), c = 18.151(1) Å, β = 110.94°, and Z = 8. Anions are located at C1 sites, one per asymmetric unit, and are slightly distorted octahedra. TGA, DTA, FTIR, and FTIR Raman results were interpreted on the basis of the formula of the compound, its crystal structure, and the behavior of other nitroprussides. |
| publishDate |
1999 |
| dc.date.none.fl_str_mv |
1999 |
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info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
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article |
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http://sedici.unlp.edu.ar/handle/10915/146429 |
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eng |
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eng |
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