Crystal and molecular structure and spectroscopic properties of tris(o-phenanthroline)iron(II) nitroprusside dihydrate: [Fe(o-phen)₃]-[Fe(CN)₅NO]·2H₂O

Autores
Ronco, Silvia Elisa; Garcia Pose, M. E.; Aymonino, Pedro José; Piro, Oscar Enrique; Rivero, Blas Eduardo; Mercader, Roberto Carlos; Castellano, Eduardo Ernesto
Año de publicación
1986
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The crystal and molecular structure of the title compound has been determined by X-ray diffraction methods. It crystallizes in the monoclinic space groupP2₁/n witha=10.072(2),b=19.434(7),c=19.462(3) Å,β=101.07(1)° andZ=4. The anion has a geometry similar to that observed in other related complexes. The two water molecules are hydrogen bonded to each other and are located at van der Waals distances from nitrogen atoms of neighbor nitroprusside anions.
Facultad de Ciencias Exactas
Materia
Física
Química
Hydrogen
Nitrogen
Iron
2H2O
Water Molecule
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/146535
Acceder
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oai_identifier_str oai:sedici.unlp.edu.ar:10915/146535
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Crystal and molecular structure and spectroscopic properties of tris(o-phenanthroline)iron(II) nitroprusside dihydrate: [Fe(o-phen)₃]-[Fe(CN)₅NO]·2H₂ORonco, Silvia ElisaGarcia Pose, M. E.Aymonino, Pedro JoséPiro, Oscar EnriqueRivero, Blas EduardoMercader, Roberto CarlosCastellano, Eduardo ErnestoFísicaQuímicaHydrogenNitrogenIron2H2OWater MoleculeThe crystal and molecular structure of the title compound has been determined by X-ray diffraction methods. It crystallizes in the monoclinic space groupP2₁/n witha=10.072(2),b=19.434(7),c=19.462(3) Å,β=101.07(1)° andZ=4. The anion has a geometry similar to that observed in other related complexes. The two water molecules are hydrogen bonded to each other and are located at van der Waals distances from nitrogen atoms of neighbor nitroprusside anions.Facultad de Ciencias Exactas1986info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf585-595http://sedici.unlp.edu.ar/handle/10915/146535enginfo:eu-repo/semantics/altIdentifier/issn/0277-8068info:eu-repo/semantics/altIdentifier/issn/1572-8854info:eu-repo/semantics/altIdentifier/issn/1074-1542info:eu-repo/semantics/altIdentifier/issn/0308-4086info:eu-repo/semantics/altIdentifier/doi/10.1007/bf01161046info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-22T17:13:31Zoai:sedici.unlp.edu.ar:10915/146535Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-22 17:13:31.34SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Crystal and molecular structure and spectroscopic properties of tris(o-phenanthroline)iron(II) nitroprusside dihydrate: [Fe(o-phen)₃]-[Fe(CN)₅NO]·2H₂O
title Crystal and molecular structure and spectroscopic properties of tris(o-phenanthroline)iron(II) nitroprusside dihydrate: [Fe(o-phen)₃]-[Fe(CN)₅NO]·2H₂O
spellingShingle Crystal and molecular structure and spectroscopic properties of tris(o-phenanthroline)iron(II) nitroprusside dihydrate: [Fe(o-phen)₃]-[Fe(CN)₅NO]·2H₂O
Ronco, Silvia Elisa
Física
Química
Hydrogen
Nitrogen
Iron
2H2O
Water Molecule
title_short Crystal and molecular structure and spectroscopic properties of tris(o-phenanthroline)iron(II) nitroprusside dihydrate: [Fe(o-phen)₃]-[Fe(CN)₅NO]·2H₂O
title_full Crystal and molecular structure and spectroscopic properties of tris(o-phenanthroline)iron(II) nitroprusside dihydrate: [Fe(o-phen)₃]-[Fe(CN)₅NO]·2H₂O
title_fullStr Crystal and molecular structure and spectroscopic properties of tris(o-phenanthroline)iron(II) nitroprusside dihydrate: [Fe(o-phen)₃]-[Fe(CN)₅NO]·2H₂O
title_full_unstemmed Crystal and molecular structure and spectroscopic properties of tris(o-phenanthroline)iron(II) nitroprusside dihydrate: [Fe(o-phen)₃]-[Fe(CN)₅NO]·2H₂O
title_sort Crystal and molecular structure and spectroscopic properties of tris(o-phenanthroline)iron(II) nitroprusside dihydrate: [Fe(o-phen)₃]-[Fe(CN)₅NO]·2H₂O
dc.creator.none.fl_str_mv Ronco, Silvia Elisa
Garcia Pose, M. E.
Aymonino, Pedro José
Piro, Oscar Enrique
Rivero, Blas Eduardo
Mercader, Roberto Carlos
Castellano, Eduardo Ernesto
author Ronco, Silvia Elisa
author_facet Ronco, Silvia Elisa
Garcia Pose, M. E.
Aymonino, Pedro José
Piro, Oscar Enrique
Rivero, Blas Eduardo
Mercader, Roberto Carlos
Castellano, Eduardo Ernesto
author_role author
author2 Garcia Pose, M. E.
Aymonino, Pedro José
Piro, Oscar Enrique
Rivero, Blas Eduardo
Mercader, Roberto Carlos
Castellano, Eduardo Ernesto
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Física
Química
Hydrogen
Nitrogen
Iron
2H2O
Water Molecule
topic Física
Química
Hydrogen
Nitrogen
Iron
2H2O
Water Molecule
dc.description.none.fl_txt_mv The crystal and molecular structure of the title compound has been determined by X-ray diffraction methods. It crystallizes in the monoclinic space groupP2₁/n witha=10.072(2),b=19.434(7),c=19.462(3) Å,β=101.07(1)° andZ=4. The anion has a geometry similar to that observed in other related complexes. The two water molecules are hydrogen bonded to each other and are located at van der Waals distances from nitrogen atoms of neighbor nitroprusside anions.
Facultad de Ciencias Exactas
description The crystal and molecular structure of the title compound has been determined by X-ray diffraction methods. It crystallizes in the monoclinic space groupP2₁/n witha=10.072(2),b=19.434(7),c=19.462(3) Å,β=101.07(1)° andZ=4. The anion has a geometry similar to that observed in other related complexes. The two water molecules are hydrogen bonded to each other and are located at van der Waals distances from nitrogen atoms of neighbor nitroprusside anions.
publishDate 1986
dc.date.none.fl_str_mv 1986
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/146535
url http://sedici.unlp.edu.ar/handle/10915/146535
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0277-8068
info:eu-repo/semantics/altIdentifier/issn/1572-8854
info:eu-repo/semantics/altIdentifier/issn/1074-1542
info:eu-repo/semantics/altIdentifier/issn/0308-4086
info:eu-repo/semantics/altIdentifier/doi/10.1007/bf01161046
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
585-595
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 12.982451

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