Crystal and anion structure, TGA, DTA, and infrared and Raman spectra of managanese(II) nitroprusside dihydrate, Mn [Fe(CN)5NO]·2H2O
- Autores
- Benavente, A.; de Morán, J; Piro, Oscar Enrique; Castellano, Eduardo Ernesto; Aymonino, Pedro José
- Año de publicación
- 1997
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The single crystal and anion structure of Mn[Fe(CN)5NO·2H2O, obtained by slow interdiffusion of reactant solutions through a TMS gel, was solved by X-ray diffraction methods and refined toR1=0.036. Spatial group: orthorhombic, Pnma, a=14.069(2), b=7.538(1), c=10.543(1)A, Z=4. The Mn(II) ion and the water molecules are sited on mirror planes, which bisect the nitroprusside ions. One of the water molecules is coordinated to Mn(II) and the other, strongly hydrogen (as acceptor) bonded to the first molecule. The IR spectrum confirms the bonding of the water molecules and TGA results are in accordance with the dihydrate character of the substance and its dehydration in two successive steps. DTA results and the Raman spectrum agree with other results and the comparison between IR and Raman vNO wavenumbers confirms the expected strong vibrational interaction between the closely packed antiparallel (eclipsed) NO groups. There is a topotactic relationship between the dihydrate and the trihydrate, which crystallizes in the space subgroupP2; 1/n.
Centro de Química Inorgánica - Materia
-
Química
Ciencias Exactas
Manganese nitroprusside dihydrate
crystal structure
properties - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by/4.0/
- Repositorio
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/141596
Ver los metadatos del registro completo
id |
SEDICI_f7959d84621bb8a88f2c0241151ad708 |
---|---|
oai_identifier_str |
oai:sedici.unlp.edu.ar:10915/141596 |
network_acronym_str |
SEDICI |
repository_id_str |
1329 |
network_name_str |
SEDICI (UNLP) |
spelling |
Crystal and anion structure, TGA, DTA, and infrared and Raman spectra of managanese(II) nitroprusside dihydrate, Mn [Fe(CN)5NO]·2H2OBenavente, A.de Morán, JPiro, Oscar EnriqueCastellano, Eduardo ErnestoAymonino, Pedro JoséQuímicaCiencias ExactasManganese nitroprusside dihydratecrystal structurepropertiesThe single crystal and anion structure of Mn[Fe(CN)5NO·2H2O, obtained by slow interdiffusion of reactant solutions through a TMS gel, was solved by X-ray diffraction methods and refined toR1=0.036. Spatial group: orthorhombic, Pnma, a=14.069(2), b=7.538(1), c=10.543(1)A, Z=4. The Mn(II) ion and the water molecules are sited on mirror planes, which bisect the nitroprusside ions. One of the water molecules is coordinated to Mn(II) and the other, strongly hydrogen (as acceptor) bonded to the first molecule. The IR spectrum confirms the bonding of the water molecules and TGA results are in accordance with the dihydrate character of the substance and its dehydration in two successive steps. DTA results and the Raman spectrum agree with other results and the comparison between IR and Raman vNO wavenumbers confirms the expected strong vibrational interaction between the closely packed antiparallel (eclipsed) NO groups. There is a topotactic relationship between the dihydrate and the trihydrate, which crystallizes in the space subgroupP2; 1/n.Centro de Química Inorgánica1997info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf343-352http://sedici.unlp.edu.ar/handle/10915/141596enginfo:eu-repo/semantics/altIdentifier/issn/1074-1542info:eu-repo/semantics/altIdentifier/issn/1572-8854info:eu-repo/semantics/altIdentifier/issn/0308-4086info:eu-repo/semantics/altIdentifier/issn/0277-8068info:eu-repo/semantics/altIdentifier/doi/10.1007/bf02576566info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:32:07Zoai:sedici.unlp.edu.ar:10915/141596Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:32:08.288SEDICI (UNLP) - Universidad Nacional de La Platafalse |
dc.title.none.fl_str_mv |
Crystal and anion structure, TGA, DTA, and infrared and Raman spectra of managanese(II) nitroprusside dihydrate, Mn [Fe(CN)5NO]·2H2O |
title |
Crystal and anion structure, TGA, DTA, and infrared and Raman spectra of managanese(II) nitroprusside dihydrate, Mn [Fe(CN)5NO]·2H2O |
spellingShingle |
Crystal and anion structure, TGA, DTA, and infrared and Raman spectra of managanese(II) nitroprusside dihydrate, Mn [Fe(CN)5NO]·2H2O Benavente, A. Química Ciencias Exactas Manganese nitroprusside dihydrate crystal structure properties |
title_short |
Crystal and anion structure, TGA, DTA, and infrared and Raman spectra of managanese(II) nitroprusside dihydrate, Mn [Fe(CN)5NO]·2H2O |
title_full |
Crystal and anion structure, TGA, DTA, and infrared and Raman spectra of managanese(II) nitroprusside dihydrate, Mn [Fe(CN)5NO]·2H2O |
title_fullStr |
Crystal and anion structure, TGA, DTA, and infrared and Raman spectra of managanese(II) nitroprusside dihydrate, Mn [Fe(CN)5NO]·2H2O |
title_full_unstemmed |
Crystal and anion structure, TGA, DTA, and infrared and Raman spectra of managanese(II) nitroprusside dihydrate, Mn [Fe(CN)5NO]·2H2O |
title_sort |
Crystal and anion structure, TGA, DTA, and infrared and Raman spectra of managanese(II) nitroprusside dihydrate, Mn [Fe(CN)5NO]·2H2O |
dc.creator.none.fl_str_mv |
Benavente, A. de Morán, J Piro, Oscar Enrique Castellano, Eduardo Ernesto Aymonino, Pedro José |
author |
Benavente, A. |
author_facet |
Benavente, A. de Morán, J Piro, Oscar Enrique Castellano, Eduardo Ernesto Aymonino, Pedro José |
author_role |
author |
author2 |
de Morán, J Piro, Oscar Enrique Castellano, Eduardo Ernesto Aymonino, Pedro José |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
Química Ciencias Exactas Manganese nitroprusside dihydrate crystal structure properties |
topic |
Química Ciencias Exactas Manganese nitroprusside dihydrate crystal structure properties |
dc.description.none.fl_txt_mv |
The single crystal and anion structure of Mn[Fe(CN)5NO·2H2O, obtained by slow interdiffusion of reactant solutions through a TMS gel, was solved by X-ray diffraction methods and refined toR1=0.036. Spatial group: orthorhombic, Pnma, a=14.069(2), b=7.538(1), c=10.543(1)A, Z=4. The Mn(II) ion and the water molecules are sited on mirror planes, which bisect the nitroprusside ions. One of the water molecules is coordinated to Mn(II) and the other, strongly hydrogen (as acceptor) bonded to the first molecule. The IR spectrum confirms the bonding of the water molecules and TGA results are in accordance with the dihydrate character of the substance and its dehydration in two successive steps. DTA results and the Raman spectrum agree with other results and the comparison between IR and Raman vNO wavenumbers confirms the expected strong vibrational interaction between the closely packed antiparallel (eclipsed) NO groups. There is a topotactic relationship between the dihydrate and the trihydrate, which crystallizes in the space subgroupP2; 1/n. Centro de Química Inorgánica |
description |
The single crystal and anion structure of Mn[Fe(CN)5NO·2H2O, obtained by slow interdiffusion of reactant solutions through a TMS gel, was solved by X-ray diffraction methods and refined toR1=0.036. Spatial group: orthorhombic, Pnma, a=14.069(2), b=7.538(1), c=10.543(1)A, Z=4. The Mn(II) ion and the water molecules are sited on mirror planes, which bisect the nitroprusside ions. One of the water molecules is coordinated to Mn(II) and the other, strongly hydrogen (as acceptor) bonded to the first molecule. The IR spectrum confirms the bonding of the water molecules and TGA results are in accordance with the dihydrate character of the substance and its dehydration in two successive steps. DTA results and the Raman spectrum agree with other results and the comparison between IR and Raman vNO wavenumbers confirms the expected strong vibrational interaction between the closely packed antiparallel (eclipsed) NO groups. There is a topotactic relationship between the dihydrate and the trihydrate, which crystallizes in the space subgroupP2; 1/n. |
publishDate |
1997 |
dc.date.none.fl_str_mv |
1997 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/141596 |
url |
http://sedici.unlp.edu.ar/handle/10915/141596 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/issn/1074-1542 info:eu-repo/semantics/altIdentifier/issn/1572-8854 info:eu-repo/semantics/altIdentifier/issn/0308-4086 info:eu-repo/semantics/altIdentifier/issn/0277-8068 info:eu-repo/semantics/altIdentifier/doi/10.1007/bf02576566 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
dc.format.none.fl_str_mv |
application/pdf 343-352 |
dc.source.none.fl_str_mv |
reponame:SEDICI (UNLP) instname:Universidad Nacional de La Plata instacron:UNLP |
reponame_str |
SEDICI (UNLP) |
collection |
SEDICI (UNLP) |
instname_str |
Universidad Nacional de La Plata |
instacron_str |
UNLP |
institution |
UNLP |
repository.name.fl_str_mv |
SEDICI (UNLP) - Universidad Nacional de La Plata |
repository.mail.fl_str_mv |
alira@sedici.unlp.edu.ar |
_version_ |
1844616201133621248 |
score |
13.070432 |