Redox mediation at poly(o-aminophenol) coated electrodes: mechanistic diagnosis from steady state polarization curves

Autores
Ybarra, Gabriel; Moina, Carlos; Florit, María Inés; Posadas, Dionisio
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, the mediated reduction and oxidation of Fe(CN) 6 3-/4- and Fe 3+ in poly(o-aminophenol) coated electrodes is analyzed by means of diagnosis diagram based on the features of steady state current-potential curves. This analysis allows to identify the current determining process and to reproduce the experimental characteristics of the polarization curve from the relevant kinetic and thermodynamical parameters with a minimum amount of experimental measurements.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Materia
Química
Current rectification
Diagnostic diagrams
Electroactive polymers
Redox polymers
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/128505
Acceder
id SEDICI_00e07d4afd8adf0ffc4b73fd39ebba0e
oai_identifier_str oai:sedici.unlp.edu.ar:10915/128505
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Redox mediation at poly(o-aminophenol) coated electrodes: mechanistic diagnosis from steady state polarization curvesYbarra, GabrielMoina, CarlosFlorit, María InésPosadas, DionisioQuímicaCurrent rectificationDiagnostic diagramsElectroactive polymersRedox polymersIn this work, the mediated reduction and oxidation of Fe(CN) 6 3-/4- and Fe 3+ in poly(o-aminophenol) coated electrodes is analyzed by means of diagnosis diagram based on the features of steady state current-potential curves. This analysis allows to identify the current determining process and to reproduce the experimental characteristics of the polarization curve from the relevant kinetic and thermodynamical parameters with a minimum amount of experimental measurements.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas2018info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf271-280http://sedici.unlp.edu.ar/handle/10915/128505enginfo:eu-repo/semantics/altIdentifier/issn/1847-9286info:eu-repo/semantics/altIdentifier/doi/10.5599/jese.516info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-15T11:22:58Zoai:sedici.unlp.edu.ar:10915/128505Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-15 11:22:59.156SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Redox mediation at poly(o-aminophenol) coated electrodes: mechanistic diagnosis from steady state polarization curves
title Redox mediation at poly(o-aminophenol) coated electrodes: mechanistic diagnosis from steady state polarization curves
spellingShingle Redox mediation at poly(o-aminophenol) coated electrodes: mechanistic diagnosis from steady state polarization curves
Ybarra, Gabriel
Química
Current rectification
Diagnostic diagrams
Electroactive polymers
Redox polymers
title_short Redox mediation at poly(o-aminophenol) coated electrodes: mechanistic diagnosis from steady state polarization curves
title_full Redox mediation at poly(o-aminophenol) coated electrodes: mechanistic diagnosis from steady state polarization curves
title_fullStr Redox mediation at poly(o-aminophenol) coated electrodes: mechanistic diagnosis from steady state polarization curves
title_full_unstemmed Redox mediation at poly(o-aminophenol) coated electrodes: mechanistic diagnosis from steady state polarization curves
title_sort Redox mediation at poly(o-aminophenol) coated electrodes: mechanistic diagnosis from steady state polarization curves
dc.creator.none.fl_str_mv Ybarra, Gabriel
Moina, Carlos
Florit, María Inés
Posadas, Dionisio
author Ybarra, Gabriel
author_facet Ybarra, Gabriel
Moina, Carlos
Florit, María Inés
Posadas, Dionisio
author_role author
author2 Moina, Carlos
Florit, María Inés
Posadas, Dionisio
author2_role author
author
author
dc.subject.none.fl_str_mv Química
Current rectification
Diagnostic diagrams
Electroactive polymers
Redox polymers
topic Química
Current rectification
Diagnostic diagrams
Electroactive polymers
Redox polymers
dc.description.none.fl_txt_mv In this work, the mediated reduction and oxidation of Fe(CN) 6 3-/4- and Fe 3+ in poly(o-aminophenol) coated electrodes is analyzed by means of diagnosis diagram based on the features of steady state current-potential curves. This analysis allows to identify the current determining process and to reproduce the experimental characteristics of the polarization curve from the relevant kinetic and thermodynamical parameters with a minimum amount of experimental measurements.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
description In this work, the mediated reduction and oxidation of Fe(CN) 6 3-/4- and Fe 3+ in poly(o-aminophenol) coated electrodes is analyzed by means of diagnosis diagram based on the features of steady state current-potential curves. This analysis allows to identify the current determining process and to reproduce the experimental characteristics of the polarization curve from the relevant kinetic and thermodynamical parameters with a minimum amount of experimental measurements.
publishDate 2018
dc.date.none.fl_str_mv 2018
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/128505
url http://sedici.unlp.edu.ar/handle/10915/128505
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/1847-9286
info:eu-repo/semantics/altIdentifier/doi/10.5599/jese.516
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
271-280
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.22299

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