Thermodynamic analysis of a polymerization-induced phase separation in nanoparticle-monomer-polymer blends
- Autores
- Soulé, Ezequiel Rodolfo; Borrajo Fernandez, Julio; Williams, Roberto Juan Jose
- Año de publicación
- 2007
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- We perform a thermodynamic analysis of the polymerization-induced phase separation in nanoparticle-monomer-polymer blends using a simple model recently proposed by Ginzburg (Macromolecules 2005, 38, 2362). The model was adapted for ternary blends constituted by nanoparticles, a monomer and a linear polymer, where the relative fractions of polymer and monomer determine the conversion in the polymerization reaction. The analysis showed that phase separation can occur in the course of polymerization for a large range of values of the relevant parameters (interaction parameter and polymer and particle sizes). This possibility has to be considered when the intention is to fix a uniform dispersion of nanoparticles in a monomer through its polymerization. © 2007 American Chemical Society.
Fil: Soulé, Ezequiel Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Borrajo Fernandez, Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina - Materia
-
Nanoparticles
Polymers
Phase Diagrams - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/75830
Ver los metadatos del registro completo
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Thermodynamic analysis of a polymerization-induced phase separation in nanoparticle-monomer-polymer blendsSoulé, Ezequiel RodolfoBorrajo Fernandez, JulioWilliams, Roberto Juan JoseNanoparticlesPolymersPhase Diagramshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2We perform a thermodynamic analysis of the polymerization-induced phase separation in nanoparticle-monomer-polymer blends using a simple model recently proposed by Ginzburg (Macromolecules 2005, 38, 2362). The model was adapted for ternary blends constituted by nanoparticles, a monomer and a linear polymer, where the relative fractions of polymer and monomer determine the conversion in the polymerization reaction. The analysis showed that phase separation can occur in the course of polymerization for a large range of values of the relevant parameters (interaction parameter and polymer and particle sizes). This possibility has to be considered when the intention is to fix a uniform dispersion of nanoparticles in a monomer through its polymerization. © 2007 American Chemical Society.Fil: Soulé, Ezequiel Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Borrajo Fernandez, Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaAmerican Chemical Society2007-10-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/75830Soulé, Ezequiel Rodolfo; Borrajo Fernandez, Julio; Williams, Roberto Juan Jose; Thermodynamic analysis of a polymerization-induced phase separation in nanoparticle-monomer-polymer blends; American Chemical Society; Macromolecules; 40; 22; 4-10-2007; 8082-80860024-9297CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ma071369cinfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/ma071369cinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:49:40Zoai:ri.conicet.gov.ar:11336/75830instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:49:41.112CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Thermodynamic analysis of a polymerization-induced phase separation in nanoparticle-monomer-polymer blends |
title |
Thermodynamic analysis of a polymerization-induced phase separation in nanoparticle-monomer-polymer blends |
spellingShingle |
Thermodynamic analysis of a polymerization-induced phase separation in nanoparticle-monomer-polymer blends Soulé, Ezequiel Rodolfo Nanoparticles Polymers Phase Diagrams |
title_short |
Thermodynamic analysis of a polymerization-induced phase separation in nanoparticle-monomer-polymer blends |
title_full |
Thermodynamic analysis of a polymerization-induced phase separation in nanoparticle-monomer-polymer blends |
title_fullStr |
Thermodynamic analysis of a polymerization-induced phase separation in nanoparticle-monomer-polymer blends |
title_full_unstemmed |
Thermodynamic analysis of a polymerization-induced phase separation in nanoparticle-monomer-polymer blends |
title_sort |
Thermodynamic analysis of a polymerization-induced phase separation in nanoparticle-monomer-polymer blends |
dc.creator.none.fl_str_mv |
Soulé, Ezequiel Rodolfo Borrajo Fernandez, Julio Williams, Roberto Juan Jose |
author |
Soulé, Ezequiel Rodolfo |
author_facet |
Soulé, Ezequiel Rodolfo Borrajo Fernandez, Julio Williams, Roberto Juan Jose |
author_role |
author |
author2 |
Borrajo Fernandez, Julio Williams, Roberto Juan Jose |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Nanoparticles Polymers Phase Diagrams |
topic |
Nanoparticles Polymers Phase Diagrams |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
We perform a thermodynamic analysis of the polymerization-induced phase separation in nanoparticle-monomer-polymer blends using a simple model recently proposed by Ginzburg (Macromolecules 2005, 38, 2362). The model was adapted for ternary blends constituted by nanoparticles, a monomer and a linear polymer, where the relative fractions of polymer and monomer determine the conversion in the polymerization reaction. The analysis showed that phase separation can occur in the course of polymerization for a large range of values of the relevant parameters (interaction parameter and polymer and particle sizes). This possibility has to be considered when the intention is to fix a uniform dispersion of nanoparticles in a monomer through its polymerization. © 2007 American Chemical Society. Fil: Soulé, Ezequiel Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Borrajo Fernandez, Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina |
description |
We perform a thermodynamic analysis of the polymerization-induced phase separation in nanoparticle-monomer-polymer blends using a simple model recently proposed by Ginzburg (Macromolecules 2005, 38, 2362). The model was adapted for ternary blends constituted by nanoparticles, a monomer and a linear polymer, where the relative fractions of polymer and monomer determine the conversion in the polymerization reaction. The analysis showed that phase separation can occur in the course of polymerization for a large range of values of the relevant parameters (interaction parameter and polymer and particle sizes). This possibility has to be considered when the intention is to fix a uniform dispersion of nanoparticles in a monomer through its polymerization. © 2007 American Chemical Society. |
publishDate |
2007 |
dc.date.none.fl_str_mv |
2007-10-04 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/75830 Soulé, Ezequiel Rodolfo; Borrajo Fernandez, Julio; Williams, Roberto Juan Jose; Thermodynamic analysis of a polymerization-induced phase separation in nanoparticle-monomer-polymer blends; American Chemical Society; Macromolecules; 40; 22; 4-10-2007; 8082-8086 0024-9297 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/75830 |
identifier_str_mv |
Soulé, Ezequiel Rodolfo; Borrajo Fernandez, Julio; Williams, Roberto Juan Jose; Thermodynamic analysis of a polymerization-induced phase separation in nanoparticle-monomer-polymer blends; American Chemical Society; Macromolecules; 40; 22; 4-10-2007; 8082-8086 0024-9297 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1021/ma071369c info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/ma071369c |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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13.070432 |