Determining the geographical origin of Sechium edule fruits by multielement analysis and advanced chemometric techniques

Autores
Hidalgo, Melisa Jazmín; Fechner, Diana Corina; Marchevsky, Eduardo Jorge; Pellerano, Roberto Gerardo
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Fil: Hidalgo, Melisa Jazmín. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; Argentina.
Fil: Fechner, Diana Corina. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; Argentina.
Fil: Marchevsky, Eduardo Jorge. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; Argentina.
Fil: Marchevsky, Eduardo Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet-San Luis; Argentina.
Fil: Pellerano, Roberto Gerardo. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; Argentina.
Fil: Pellerano, Roberto Gerardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Química Básica y Aplicada del Nordeste Argentino; Argentina.
Fil: Hidalgo, Melisa Jazmín. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Química Básica y Aplicada del Nordeste Argentino; Argentina.
This paper describes the determination and evaluation of the major and trace element composition (Al, As, Ba, Ca, Cd, Co, Cu, Fe, K, Mg, Mn, Na, Pb, Sr and Zn) of Sechium edule (Jacq) Swartz fruits collected from four different places of production in Corrientes province, Argentina. Element concentrations were determined by using inductively coupled plasma optical emission spectrometry (ICP OES) after microwave digestion. The accuracy was confirmed with standard reference material of spinach leaves (NIST, 1570a) and spiking tests. Principal component analysis (PCA), linear discriminant analysis (LDA), knearest neighbors (kNN), partial least square-discriminant analysis (PLS-DA) and support vector machine (SVM) were applied to the results for discriminating the geographical origin of S. edule fruits. Finally, the LDA method was found to perform best with up to 90% accuracy rate based on the following elements: Ca, Ba, Cu, Mn, Na, Sr, and Zn.
Fuente
Food Chemistry, 2016, vol. 210, p. 228-234.
Materia
ICP-OES
Mineral composition
Multivariate analysis
Classification
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
Repositorio Institucional de la Universidad Nacional del Nordeste (UNNE)
Institución
Universidad Nacional del Nordeste
OAI Identificador
oai:repositorio.unne.edu.ar:123456789/27954
Acceder
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network_acronym_str RIUNNE
repository_id_str 4871
network_name_str Repositorio Institucional de la Universidad Nacional del Nordeste (UNNE)
spelling Determining the geographical origin of Sechium edule fruits by multielement analysis and advanced chemometric techniquesHidalgo, Melisa JazmínFechner, Diana CorinaMarchevsky, Eduardo JorgePellerano, Roberto GerardoICP-OESMineral compositionMultivariate analysisClassificationFil: Hidalgo, Melisa Jazmín. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; Argentina.Fil: Fechner, Diana Corina. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; Argentina.Fil: Marchevsky, Eduardo Jorge. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; Argentina.Fil: Marchevsky, Eduardo Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet-San Luis; Argentina.Fil: Pellerano, Roberto Gerardo. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; Argentina.Fil: Pellerano, Roberto Gerardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Química Básica y Aplicada del Nordeste Argentino; Argentina.Fil: Hidalgo, Melisa Jazmín. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Química Básica y Aplicada del Nordeste Argentino; Argentina.This paper describes the determination and evaluation of the major and trace element composition (Al, As, Ba, Ca, Cd, Co, Cu, Fe, K, Mg, Mn, Na, Pb, Sr and Zn) of Sechium edule (Jacq) Swartz fruits collected from four different places of production in Corrientes province, Argentina. Element concentrations were determined by using inductively coupled plasma optical emission spectrometry (ICP OES) after microwave digestion. The accuracy was confirmed with standard reference material of spinach leaves (NIST, 1570a) and spiking tests. Principal component analysis (PCA), linear discriminant analysis (LDA), knearest neighbors (kNN), partial least square-discriminant analysis (PLS-DA) and support vector machine (SVM) were applied to the results for discriminating the geographical origin of S. edule fruits. Finally, the LDA method was found to perform best with up to 90% accuracy rate based on the following elements: Ca, Ba, Cu, Mn, Na, Sr, and Zn.Elsevier2016info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfHidalgo, Melisa Jazmín, et al., 2016. Determining the geographical origin of Sechium edule fruits by multielement analysis and advanced chemometric techniques. Food Chemistry. Amsterdam: Elsevier, vol. 210, p. 228-234. ISSN 0308-8146.0308-8146http://repositorio.unne.edu.ar/handle/123456789/27954Food Chemistry, 2016, vol. 210, p. 228-234.reponame:Repositorio Institucional de la Universidad Nacional del Nordeste (UNNE)instname:Universidad Nacional del Nordesteenginfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/2.5/ar/Atribución-NoComercial-SinDerivadas 2.5 Argentina2025-10-16T10:07:11Zoai:repositorio.unne.edu.ar:123456789/27954instacron:UNNEInstitucionalhttp://repositorio.unne.edu.ar/Universidad públicaNo correspondehttp://repositorio.unne.edu.ar/oaiososa@bib.unne.edu.ar;sergio.alegria@unne.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:48712025-10-16 10:07:11.243Repositorio Institucional de la Universidad Nacional del Nordeste (UNNE) - Universidad Nacional del Nordestefalse
dc.title.none.fl_str_mv Determining the geographical origin of Sechium edule fruits by multielement analysis and advanced chemometric techniques
title Determining the geographical origin of Sechium edule fruits by multielement analysis and advanced chemometric techniques
spellingShingle Determining the geographical origin of Sechium edule fruits by multielement analysis and advanced chemometric techniques
Hidalgo, Melisa Jazmín
ICP-OES
Mineral composition
Multivariate analysis
Classification
title_short Determining the geographical origin of Sechium edule fruits by multielement analysis and advanced chemometric techniques
title_full Determining the geographical origin of Sechium edule fruits by multielement analysis and advanced chemometric techniques
title_fullStr Determining the geographical origin of Sechium edule fruits by multielement analysis and advanced chemometric techniques
title_full_unstemmed Determining the geographical origin of Sechium edule fruits by multielement analysis and advanced chemometric techniques
title_sort Determining the geographical origin of Sechium edule fruits by multielement analysis and advanced chemometric techniques
dc.creator.none.fl_str_mv Hidalgo, Melisa Jazmín
Fechner, Diana Corina
Marchevsky, Eduardo Jorge
Pellerano, Roberto Gerardo
author Hidalgo, Melisa Jazmín
author_facet Hidalgo, Melisa Jazmín
Fechner, Diana Corina
Marchevsky, Eduardo Jorge
Pellerano, Roberto Gerardo
author_role author
author2 Fechner, Diana Corina
Marchevsky, Eduardo Jorge
Pellerano, Roberto Gerardo
author2_role author
author
author
dc.subject.none.fl_str_mv ICP-OES
Mineral composition
Multivariate analysis
Classification
topic ICP-OES
Mineral composition
Multivariate analysis
Classification
dc.description.none.fl_txt_mv Fil: Hidalgo, Melisa Jazmín. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; Argentina.
Fil: Fechner, Diana Corina. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; Argentina.
Fil: Marchevsky, Eduardo Jorge. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; Argentina.
Fil: Marchevsky, Eduardo Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet-San Luis; Argentina.
Fil: Pellerano, Roberto Gerardo. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; Argentina.
Fil: Pellerano, Roberto Gerardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Química Básica y Aplicada del Nordeste Argentino; Argentina.
Fil: Hidalgo, Melisa Jazmín. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Química Básica y Aplicada del Nordeste Argentino; Argentina.
This paper describes the determination and evaluation of the major and trace element composition (Al, As, Ba, Ca, Cd, Co, Cu, Fe, K, Mg, Mn, Na, Pb, Sr and Zn) of Sechium edule (Jacq) Swartz fruits collected from four different places of production in Corrientes province, Argentina. Element concentrations were determined by using inductively coupled plasma optical emission spectrometry (ICP OES) after microwave digestion. The accuracy was confirmed with standard reference material of spinach leaves (NIST, 1570a) and spiking tests. Principal component analysis (PCA), linear discriminant analysis (LDA), knearest neighbors (kNN), partial least square-discriminant analysis (PLS-DA) and support vector machine (SVM) were applied to the results for discriminating the geographical origin of S. edule fruits. Finally, the LDA method was found to perform best with up to 90% accuracy rate based on the following elements: Ca, Ba, Cu, Mn, Na, Sr, and Zn.
description Fil: Hidalgo, Melisa Jazmín. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; Argentina.
publishDate 2016
dc.date.none.fl_str_mv 2016
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv Hidalgo, Melisa Jazmín, et al., 2016. Determining the geographical origin of Sechium edule fruits by multielement analysis and advanced chemometric techniques. Food Chemistry. Amsterdam: Elsevier, vol. 210, p. 228-234. ISSN 0308-8146.
0308-8146
http://repositorio.unne.edu.ar/handle/123456789/27954
identifier_str_mv Hidalgo, Melisa Jazmín, et al., 2016. Determining the geographical origin of Sechium edule fruits by multielement analysis and advanced chemometric techniques. Food Chemistry. Amsterdam: Elsevier, vol. 210, p. 228-234. ISSN 0308-8146.
0308-8146
url http://repositorio.unne.edu.ar/handle/123456789/27954
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Atribución-NoComercial-SinDerivadas 2.5 Argentina
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Atribución-NoComercial-SinDerivadas 2.5 Argentina
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv Food Chemistry, 2016, vol. 210, p. 228-234.
reponame:Repositorio Institucional de la Universidad Nacional del Nordeste (UNNE)
instname:Universidad Nacional del Nordeste
reponame_str Repositorio Institucional de la Universidad Nacional del Nordeste (UNNE)
collection Repositorio Institucional de la Universidad Nacional del Nordeste (UNNE)
instname_str Universidad Nacional del Nordeste
repository.name.fl_str_mv Repositorio Institucional de la Universidad Nacional del Nordeste (UNNE) - Universidad Nacional del Nordeste
repository.mail.fl_str_mv ososa@bib.unne.edu.ar;sergio.alegria@unne.edu.ar
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score 12.712165

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