Multiresidues of pesticides in the particulate matter (PM10) emitted by rural soils of the semiarid pampas, Argentina. A potential source of air pollution

Autores
Ramirez Haberkon, Nancy; Aparicio, Virginia Carolina; De Geronimo, Eduardo; Mendez, Mariano
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The aim of this work was to evaluate the presence of 40 pesticides in the PM10 emitted by rural soils of the semiarid region of Argentina. Six agricultural soils for grain production under no till and with high use of pesticides (AG), 5 agricultural soils for forage and grain production under conventional tillage (AFG) and 5 unpaved rural roads (RR) were sampled. The PM10 was generated using the Easy Dust Generator and it was collected with an electrostatic precipitator. The presence of 20 herbicides, 14 insecticides and 6 fungicides was analyzed in the soil and in the PM10. More than 70% of the pesticides analyzed were detected in the soil and in the PM10. All agricultural soils and 87% of RR soils showed at least one residue of pesticides. Multiresidues of pesticides were found in the 100% of PM10 emitted by rural soils. The mean number of pesticides was higher in the PM10 (7) than in the soil (5). Some pesticides were not detected in the soils but they were detected in the PM10 (triticonazole, carbofuran, metsulfuron methyl) and vice versa. In general, the concentrations of herbicides were higher in the PM10 than in the soil, while the concentrations of insecticides and fungicides were lower in the PM10 than in the soil. These results suggest that the concentrations of pesticide in the PM10 (inhalable fraction) should be used instead the concentrations of pesticide in the soil to calculate the exposure factor to pesticides by dust inhalation. This study provides the initial evidence of the presence of multiple pesticide residues in PM10 emitted by rural soils under different land management. Also confirms that the PM10 is a potential source of air contamination with pesticides. Future studies should be driven to measure the concentrations of pesticides and their dynamics in the PM10.
EEA Balcarce
Fil: Ramirez Haberkon, Nancy. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de La Pampa; Argentina. Instituto de Ciencias de la Tierra y Ambientales de La Pampa; Argentina
Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
Fil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
Fil: Mendez, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de La Pampa; Argentina. Instituto de Ciencias de la Tierra y Ambientales de La Pampa; Argentina
Fuente
Environmental Pollution 360 : 124617 (November 2024)
Materia
Plaguicida
Suelos Agrícolas
Residuos de Plaguicidas
Contaminación
Argentina
Pesticides
Agricultural Soils
Pesticide Residues
Contamination
Región Pampeana Semiárida
Nivel de accesibilidad
acceso restringido
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
INTA Digital (INTA)
Institución
Instituto Nacional de Tecnología Agropecuaria
OAI Identificador
oai:localhost:20.500.12123/18744
Acceder
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oai_identifier_str oai:localhost:20.500.12123/18744
network_acronym_str INTADig
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network_name_str INTA Digital (INTA)
spelling Multiresidues of pesticides in the particulate matter (PM10) emitted by rural soils of the semiarid pampas, Argentina. A potential source of air pollutionRamirez Haberkon, NancyAparicio, Virginia CarolinaDe Geronimo, EduardoMendez, MarianoPlaguicidaSuelos AgrícolasResiduos de PlaguicidasContaminaciónArgentinaPesticidesAgricultural SoilsPesticide ResiduesContaminationRegión Pampeana SemiáridaThe aim of this work was to evaluate the presence of 40 pesticides in the PM10 emitted by rural soils of the semiarid region of Argentina. Six agricultural soils for grain production under no till and with high use of pesticides (AG), 5 agricultural soils for forage and grain production under conventional tillage (AFG) and 5 unpaved rural roads (RR) were sampled. The PM10 was generated using the Easy Dust Generator and it was collected with an electrostatic precipitator. The presence of 20 herbicides, 14 insecticides and 6 fungicides was analyzed in the soil and in the PM10. More than 70% of the pesticides analyzed were detected in the soil and in the PM10. All agricultural soils and 87% of RR soils showed at least one residue of pesticides. Multiresidues of pesticides were found in the 100% of PM10 emitted by rural soils. The mean number of pesticides was higher in the PM10 (7) than in the soil (5). Some pesticides were not detected in the soils but they were detected in the PM10 (triticonazole, carbofuran, metsulfuron methyl) and vice versa. In general, the concentrations of herbicides were higher in the PM10 than in the soil, while the concentrations of insecticides and fungicides were lower in the PM10 than in the soil. These results suggest that the concentrations of pesticide in the PM10 (inhalable fraction) should be used instead the concentrations of pesticide in the soil to calculate the exposure factor to pesticides by dust inhalation. This study provides the initial evidence of the presence of multiple pesticide residues in PM10 emitted by rural soils under different land management. Also confirms that the PM10 is a potential source of air contamination with pesticides. Future studies should be driven to measure the concentrations of pesticides and their dynamics in the PM10.EEA BalcarceFil: Ramirez Haberkon, Nancy. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de La Pampa; Argentina. Instituto de Ciencias de la Tierra y Ambientales de La Pampa; ArgentinaFil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; ArgentinaFil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; ArgentinaFil: Mendez, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de La Pampa; Argentina. Instituto de Ciencias de la Tierra y Ambientales de La Pampa; ArgentinaElsevier2024-08-01T11:14:59Z2024-08-01T11:14:59Z2024-07-26info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12123/18744https://www.sciencedirect.com/science/article/abs/pii/S02697491240133190269-7491 (print)1873-6424 (online)https://doi.org/10.1016/j.envpol.2024.124617Environmental Pollution 360 : 124617 (November 2024)reponame:INTA Digital (INTA)instname:Instituto Nacional de Tecnología Agropecuariaenginfo:eu-repo/semantics/restrictedAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)2025-10-16T09:31:46Zoai:localhost:20.500.12123/18744instacron:INTAInstitucionalhttp://repositorio.inta.gob.ar/Organismo científico-tecnológicoNo correspondehttp://repositorio.inta.gob.ar/oai/requesttripaldi.nicolas@inta.gob.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:l2025-10-16 09:31:47.14INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuariafalse
dc.title.none.fl_str_mv Multiresidues of pesticides in the particulate matter (PM10) emitted by rural soils of the semiarid pampas, Argentina. A potential source of air pollution
title Multiresidues of pesticides in the particulate matter (PM10) emitted by rural soils of the semiarid pampas, Argentina. A potential source of air pollution
spellingShingle Multiresidues of pesticides in the particulate matter (PM10) emitted by rural soils of the semiarid pampas, Argentina. A potential source of air pollution
Ramirez Haberkon, Nancy
Plaguicida
Suelos Agrícolas
Residuos de Plaguicidas
Contaminación
Argentina
Pesticides
Agricultural Soils
Pesticide Residues
Contamination
Región Pampeana Semiárida
title_short Multiresidues of pesticides in the particulate matter (PM10) emitted by rural soils of the semiarid pampas, Argentina. A potential source of air pollution
title_full Multiresidues of pesticides in the particulate matter (PM10) emitted by rural soils of the semiarid pampas, Argentina. A potential source of air pollution
title_fullStr Multiresidues of pesticides in the particulate matter (PM10) emitted by rural soils of the semiarid pampas, Argentina. A potential source of air pollution
title_full_unstemmed Multiresidues of pesticides in the particulate matter (PM10) emitted by rural soils of the semiarid pampas, Argentina. A potential source of air pollution
title_sort Multiresidues of pesticides in the particulate matter (PM10) emitted by rural soils of the semiarid pampas, Argentina. A potential source of air pollution
dc.creator.none.fl_str_mv Ramirez Haberkon, Nancy
Aparicio, Virginia Carolina
De Geronimo, Eduardo
Mendez, Mariano
author Ramirez Haberkon, Nancy
author_facet Ramirez Haberkon, Nancy
Aparicio, Virginia Carolina
De Geronimo, Eduardo
Mendez, Mariano
author_role author
author2 Aparicio, Virginia Carolina
De Geronimo, Eduardo
Mendez, Mariano
author2_role author
author
author
dc.subject.none.fl_str_mv Plaguicida
Suelos Agrícolas
Residuos de Plaguicidas
Contaminación
Argentina
Pesticides
Agricultural Soils
Pesticide Residues
Contamination
Región Pampeana Semiárida
topic Plaguicida
Suelos Agrícolas
Residuos de Plaguicidas
Contaminación
Argentina
Pesticides
Agricultural Soils
Pesticide Residues
Contamination
Región Pampeana Semiárida
dc.description.none.fl_txt_mv The aim of this work was to evaluate the presence of 40 pesticides in the PM10 emitted by rural soils of the semiarid region of Argentina. Six agricultural soils for grain production under no till and with high use of pesticides (AG), 5 agricultural soils for forage and grain production under conventional tillage (AFG) and 5 unpaved rural roads (RR) were sampled. The PM10 was generated using the Easy Dust Generator and it was collected with an electrostatic precipitator. The presence of 20 herbicides, 14 insecticides and 6 fungicides was analyzed in the soil and in the PM10. More than 70% of the pesticides analyzed were detected in the soil and in the PM10. All agricultural soils and 87% of RR soils showed at least one residue of pesticides. Multiresidues of pesticides were found in the 100% of PM10 emitted by rural soils. The mean number of pesticides was higher in the PM10 (7) than in the soil (5). Some pesticides were not detected in the soils but they were detected in the PM10 (triticonazole, carbofuran, metsulfuron methyl) and vice versa. In general, the concentrations of herbicides were higher in the PM10 than in the soil, while the concentrations of insecticides and fungicides were lower in the PM10 than in the soil. These results suggest that the concentrations of pesticide in the PM10 (inhalable fraction) should be used instead the concentrations of pesticide in the soil to calculate the exposure factor to pesticides by dust inhalation. This study provides the initial evidence of the presence of multiple pesticide residues in PM10 emitted by rural soils under different land management. Also confirms that the PM10 is a potential source of air contamination with pesticides. Future studies should be driven to measure the concentrations of pesticides and their dynamics in the PM10.
EEA Balcarce
Fil: Ramirez Haberkon, Nancy. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de La Pampa; Argentina. Instituto de Ciencias de la Tierra y Ambientales de La Pampa; Argentina
Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
Fil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
Fil: Mendez, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de La Pampa; Argentina. Instituto de Ciencias de la Tierra y Ambientales de La Pampa; Argentina
description The aim of this work was to evaluate the presence of 40 pesticides in the PM10 emitted by rural soils of the semiarid region of Argentina. Six agricultural soils for grain production under no till and with high use of pesticides (AG), 5 agricultural soils for forage and grain production under conventional tillage (AFG) and 5 unpaved rural roads (RR) were sampled. The PM10 was generated using the Easy Dust Generator and it was collected with an electrostatic precipitator. The presence of 20 herbicides, 14 insecticides and 6 fungicides was analyzed in the soil and in the PM10. More than 70% of the pesticides analyzed were detected in the soil and in the PM10. All agricultural soils and 87% of RR soils showed at least one residue of pesticides. Multiresidues of pesticides were found in the 100% of PM10 emitted by rural soils. The mean number of pesticides was higher in the PM10 (7) than in the soil (5). Some pesticides were not detected in the soils but they were detected in the PM10 (triticonazole, carbofuran, metsulfuron methyl) and vice versa. In general, the concentrations of herbicides were higher in the PM10 than in the soil, while the concentrations of insecticides and fungicides were lower in the PM10 than in the soil. These results suggest that the concentrations of pesticide in the PM10 (inhalable fraction) should be used instead the concentrations of pesticide in the soil to calculate the exposure factor to pesticides by dust inhalation. This study provides the initial evidence of the presence of multiple pesticide residues in PM10 emitted by rural soils under different land management. Also confirms that the PM10 is a potential source of air contamination with pesticides. Future studies should be driven to measure the concentrations of pesticides and their dynamics in the PM10.
publishDate 2024
dc.date.none.fl_str_mv 2024-08-01T11:14:59Z
2024-08-01T11:14:59Z
2024-07-26
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12123/18744
https://www.sciencedirect.com/science/article/abs/pii/S0269749124013319
0269-7491 (print)
1873-6424 (online)
https://doi.org/10.1016/j.envpol.2024.124617
url http://hdl.handle.net/20.500.12123/18744
https://www.sciencedirect.com/science/article/abs/pii/S0269749124013319
https://doi.org/10.1016/j.envpol.2024.124617
identifier_str_mv 0269-7491 (print)
1873-6424 (online)
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/restrictedAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv restrictedAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv Environmental Pollution 360 : 124617 (November 2024)
reponame:INTA Digital (INTA)
instname:Instituto Nacional de Tecnología Agropecuaria
reponame_str INTA Digital (INTA)
collection INTA Digital (INTA)
instname_str Instituto Nacional de Tecnología Agropecuaria
repository.name.fl_str_mv INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuaria
repository.mail.fl_str_mv tripaldi.nicolas@inta.gob.ar
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score 12.711113

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