Two phase olive mill waste valorization. Hydrochar production and phenols extraction by hydrothermal carbonization
- Autores
- Gimenez, Marianela; Rodriguez, Manuel; Montoro, Laura; Sardella, Fabiana; Rodríguez Gutiérrez, Guillermo; Monetta, Pablo Miguel; Deiana, Cristina
- Año de publicación
- 2020
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Olive oil is one of the main products from the Central-Western Region of Argentine Republic, which is mostly obtained by continuous two-phase centrifugation systems. Two-phase-olive-mill-waste (TPOMW) or Alperujo is the main waste generated by this process. This research was conducted in order to give value to this waste by producing hydrochar and phenolic antioxidant compounds, products of great interest today. For this, the hydrothermal carbonization process was applied, an effective technique to synthesize a broad range of carbon-rich materials. In this study the extraction of typical phenolic compounds of the olive from the liquid phase generated in this process was also analyzed. Box Benhken response surface method was applied to obtain the optimal values of the operating conditions of the process and the selected response variables: higher heating value of the hydrochar (HHV) and content of total phenol concentration (TPC) in the liquors. Values of 31.70 MJ.kg-1 and 4429 mL.g-1 were obtained, respectively. Effectiveness of hydrothermal carbonization for hydrochar was evidenced, achieving 70% increases in the value of HHV and 40% of carbon concentration, compared to raw alperujo. In addition, values of 1.36 and 0.17 were obtained for the H/C and O/C ratios, respectively, and energy yield of 85%. Furthermore, the physico chemical properties evaluated by scanning electron microscopy and Fourier transform infrared spectroscopy, showed their potential application as adsorbent precursor. In the liquid fraction obtained, phenols could be extracted in attractive concentrations, increasing the content of hydroxytyrosol and tyrosol 3 and 9 times with respect to the untreated alperujo, respectively.
EEA San Juan
Fil: Gimenez, Marianela. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina
Fil: Rodríguez, Manuel. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria San Juan; Argentina.
Fil: Montoro, Laura. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina.
Fil: Sardella, Fabiana. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina.
Fil: Rodríguez Gutierrez, Guillermo. Instituto de la Grasa-CSIC; España.
Fil: Monetta, Pablo Miguel. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria San Juan; Argentina.
Fil: Deiana, Cristina. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina. - Fuente
- Biomass and Bioenergy 143 : 105875 (December 2020)
- Materia
-
Olea Europaea
Residuos de Cosechas
Hidrocarburos
Hydrothermal Flow
Crop Residues
Hydrocarbons
Olivo
Alperujo - Nivel de accesibilidad
- acceso restringido
- Condiciones de uso
- Repositorio
- Institución
- Instituto Nacional de Tecnología Agropecuaria
- OAI Identificador
- oai:localhost:20.500.12123/9813
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Two phase olive mill waste valorization. Hydrochar production and phenols extraction by hydrothermal carbonizationGimenez, MarianelaRodriguez, ManuelMontoro, LauraSardella, FabianaRodríguez Gutiérrez, GuillermoMonetta, Pablo MiguelDeiana, CristinaOlea EuropaeaResiduos de CosechasHidrocarburosHydrothermal FlowCrop ResiduesHydrocarbonsOlivoAlperujoOlive oil is one of the main products from the Central-Western Region of Argentine Republic, which is mostly obtained by continuous two-phase centrifugation systems. Two-phase-olive-mill-waste (TPOMW) or Alperujo is the main waste generated by this process. This research was conducted in order to give value to this waste by producing hydrochar and phenolic antioxidant compounds, products of great interest today. For this, the hydrothermal carbonization process was applied, an effective technique to synthesize a broad range of carbon-rich materials. In this study the extraction of typical phenolic compounds of the olive from the liquid phase generated in this process was also analyzed. Box Benhken response surface method was applied to obtain the optimal values of the operating conditions of the process and the selected response variables: higher heating value of the hydrochar (HHV) and content of total phenol concentration (TPC) in the liquors. Values of 31.70 MJ.kg-1 and 4429 mL.g-1 were obtained, respectively. Effectiveness of hydrothermal carbonization for hydrochar was evidenced, achieving 70% increases in the value of HHV and 40% of carbon concentration, compared to raw alperujo. In addition, values of 1.36 and 0.17 were obtained for the H/C and O/C ratios, respectively, and energy yield of 85%. Furthermore, the physico chemical properties evaluated by scanning electron microscopy and Fourier transform infrared spectroscopy, showed their potential application as adsorbent precursor. In the liquid fraction obtained, phenols could be extracted in attractive concentrations, increasing the content of hydroxytyrosol and tyrosol 3 and 9 times with respect to the untreated alperujo, respectively.EEA San JuanFil: Gimenez, Marianela. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; ArgentinaFil: Rodríguez, Manuel. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria San Juan; Argentina.Fil: Montoro, Laura. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina.Fil: Sardella, Fabiana. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina.Fil: Rodríguez Gutierrez, Guillermo. Instituto de la Grasa-CSIC; España.Fil: Monetta, Pablo Miguel. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria San Juan; Argentina.Fil: Deiana, Cristina. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina.Elsevier2021-07-14T19:17:19Z2021-07-14T19:17:19Z2020-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12123/9813https://www.sciencedirect.com/science/article/abs/pii/S09619534203040980961-9534https://doi.org/10.1016/j.biombioe.2020.105875Biomass and Bioenergy 143 : 105875 (December 2020)reponame:INTA Digital (INTA)instname:Instituto Nacional de Tecnología Agropecuariaenginfo:eu-repo/semantics/restrictedAccess2025-09-04T09:48:58Zoai:localhost:20.500.12123/9813instacron:INTAInstitucionalhttp://repositorio.inta.gob.ar/Organismo científico-tecnológicoNo correspondehttp://repositorio.inta.gob.ar/oai/requesttripaldi.nicolas@inta.gob.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:l2025-09-04 09:48:58.601INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuariafalse |
dc.title.none.fl_str_mv |
Two phase olive mill waste valorization. Hydrochar production and phenols extraction by hydrothermal carbonization |
title |
Two phase olive mill waste valorization. Hydrochar production and phenols extraction by hydrothermal carbonization |
spellingShingle |
Two phase olive mill waste valorization. Hydrochar production and phenols extraction by hydrothermal carbonization Gimenez, Marianela Olea Europaea Residuos de Cosechas Hidrocarburos Hydrothermal Flow Crop Residues Hydrocarbons Olivo Alperujo |
title_short |
Two phase olive mill waste valorization. Hydrochar production and phenols extraction by hydrothermal carbonization |
title_full |
Two phase olive mill waste valorization. Hydrochar production and phenols extraction by hydrothermal carbonization |
title_fullStr |
Two phase olive mill waste valorization. Hydrochar production and phenols extraction by hydrothermal carbonization |
title_full_unstemmed |
Two phase olive mill waste valorization. Hydrochar production and phenols extraction by hydrothermal carbonization |
title_sort |
Two phase olive mill waste valorization. Hydrochar production and phenols extraction by hydrothermal carbonization |
dc.creator.none.fl_str_mv |
Gimenez, Marianela Rodriguez, Manuel Montoro, Laura Sardella, Fabiana Rodríguez Gutiérrez, Guillermo Monetta, Pablo Miguel Deiana, Cristina |
author |
Gimenez, Marianela |
author_facet |
Gimenez, Marianela Rodriguez, Manuel Montoro, Laura Sardella, Fabiana Rodríguez Gutiérrez, Guillermo Monetta, Pablo Miguel Deiana, Cristina |
author_role |
author |
author2 |
Rodriguez, Manuel Montoro, Laura Sardella, Fabiana Rodríguez Gutiérrez, Guillermo Monetta, Pablo Miguel Deiana, Cristina |
author2_role |
author author author author author author |
dc.subject.none.fl_str_mv |
Olea Europaea Residuos de Cosechas Hidrocarburos Hydrothermal Flow Crop Residues Hydrocarbons Olivo Alperujo |
topic |
Olea Europaea Residuos de Cosechas Hidrocarburos Hydrothermal Flow Crop Residues Hydrocarbons Olivo Alperujo |
dc.description.none.fl_txt_mv |
Olive oil is one of the main products from the Central-Western Region of Argentine Republic, which is mostly obtained by continuous two-phase centrifugation systems. Two-phase-olive-mill-waste (TPOMW) or Alperujo is the main waste generated by this process. This research was conducted in order to give value to this waste by producing hydrochar and phenolic antioxidant compounds, products of great interest today. For this, the hydrothermal carbonization process was applied, an effective technique to synthesize a broad range of carbon-rich materials. In this study the extraction of typical phenolic compounds of the olive from the liquid phase generated in this process was also analyzed. Box Benhken response surface method was applied to obtain the optimal values of the operating conditions of the process and the selected response variables: higher heating value of the hydrochar (HHV) and content of total phenol concentration (TPC) in the liquors. Values of 31.70 MJ.kg-1 and 4429 mL.g-1 were obtained, respectively. Effectiveness of hydrothermal carbonization for hydrochar was evidenced, achieving 70% increases in the value of HHV and 40% of carbon concentration, compared to raw alperujo. In addition, values of 1.36 and 0.17 were obtained for the H/C and O/C ratios, respectively, and energy yield of 85%. Furthermore, the physico chemical properties evaluated by scanning electron microscopy and Fourier transform infrared spectroscopy, showed their potential application as adsorbent precursor. In the liquid fraction obtained, phenols could be extracted in attractive concentrations, increasing the content of hydroxytyrosol and tyrosol 3 and 9 times with respect to the untreated alperujo, respectively. EEA San Juan Fil: Gimenez, Marianela. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina Fil: Rodríguez, Manuel. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria San Juan; Argentina. Fil: Montoro, Laura. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina. Fil: Sardella, Fabiana. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina. Fil: Rodríguez Gutierrez, Guillermo. Instituto de la Grasa-CSIC; España. Fil: Monetta, Pablo Miguel. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria San Juan; Argentina. Fil: Deiana, Cristina. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina. |
description |
Olive oil is one of the main products from the Central-Western Region of Argentine Republic, which is mostly obtained by continuous two-phase centrifugation systems. Two-phase-olive-mill-waste (TPOMW) or Alperujo is the main waste generated by this process. This research was conducted in order to give value to this waste by producing hydrochar and phenolic antioxidant compounds, products of great interest today. For this, the hydrothermal carbonization process was applied, an effective technique to synthesize a broad range of carbon-rich materials. In this study the extraction of typical phenolic compounds of the olive from the liquid phase generated in this process was also analyzed. Box Benhken response surface method was applied to obtain the optimal values of the operating conditions of the process and the selected response variables: higher heating value of the hydrochar (HHV) and content of total phenol concentration (TPC) in the liquors. Values of 31.70 MJ.kg-1 and 4429 mL.g-1 were obtained, respectively. Effectiveness of hydrothermal carbonization for hydrochar was evidenced, achieving 70% increases in the value of HHV and 40% of carbon concentration, compared to raw alperujo. In addition, values of 1.36 and 0.17 were obtained for the H/C and O/C ratios, respectively, and energy yield of 85%. Furthermore, the physico chemical properties evaluated by scanning electron microscopy and Fourier transform infrared spectroscopy, showed their potential application as adsorbent precursor. In the liquid fraction obtained, phenols could be extracted in attractive concentrations, increasing the content of hydroxytyrosol and tyrosol 3 and 9 times with respect to the untreated alperujo, respectively. |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-12 2021-07-14T19:17:19Z 2021-07-14T19:17:19Z |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/20.500.12123/9813 https://www.sciencedirect.com/science/article/abs/pii/S0961953420304098 0961-9534 https://doi.org/10.1016/j.biombioe.2020.105875 |
url |
http://hdl.handle.net/20.500.12123/9813 https://www.sciencedirect.com/science/article/abs/pii/S0961953420304098 https://doi.org/10.1016/j.biombioe.2020.105875 |
identifier_str_mv |
0961-9534 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/restrictedAccess |
eu_rights_str_mv |
restrictedAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
Biomass and Bioenergy 143 : 105875 (December 2020) reponame:INTA Digital (INTA) instname:Instituto Nacional de Tecnología Agropecuaria |
reponame_str |
INTA Digital (INTA) |
collection |
INTA Digital (INTA) |
instname_str |
Instituto Nacional de Tecnología Agropecuaria |
repository.name.fl_str_mv |
INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuaria |
repository.mail.fl_str_mv |
tripaldi.nicolas@inta.gob.ar |
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1842341388992118784 |
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12.623145 |