Two phase olive mill waste valorization. Hydrochar production and phenols extraction by hydrothermal carbonization

Autores
Gimenez, Marianela; Rodriguez, Manuel; Montoro, Laura; Sardella, Fabiana; Rodríguez Gutiérrez, Guillermo; Monetta, Pablo Miguel; Deiana, Cristina
Año de publicación
2020
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Olive oil is one of the main products from the Central-Western Region of Argentine Republic, which is mostly obtained by continuous two-phase centrifugation systems. Two-phase-olive-mill-waste (TPOMW) or Alperujo is the main waste generated by this process. This research was conducted in order to give value to this waste by producing hydrochar and phenolic antioxidant compounds, products of great interest today. For this, the hydrothermal carbonization process was applied, an effective technique to synthesize a broad range of carbon-rich materials. In this study the extraction of typical phenolic compounds of the olive from the liquid phase generated in this process was also analyzed. Box Benhken response surface method was applied to obtain the optimal values of the operating conditions of the process and the selected response variables: higher heating value of the hydrochar (HHV) and content of total phenol concentration (TPC) in the liquors. Values of 31.70 MJ.kg-1 and 4429 mL.g-1 were obtained, respectively. Effectiveness of hydrothermal carbonization for hydrochar was evidenced, achieving 70% increases in the value of HHV and 40% of carbon concentration, compared to raw alperujo. In addition, values of 1.36 and 0.17 were obtained for the H/C and O/C ratios, respectively, and energy yield of 85%. Furthermore, the physico chemical properties evaluated by scanning electron microscopy and Fourier transform infrared spectroscopy, showed their potential application as adsorbent precursor. In the liquid fraction obtained, phenols could be extracted in attractive concentrations, increasing the content of hydroxytyrosol and tyrosol 3 and 9 times with respect to the untreated alperujo, respectively.
EEA San Juan
Fil: Gimenez, Marianela. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina
Fil: Rodríguez, Manuel. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria San Juan; Argentina.
Fil: Montoro, Laura. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina.
Fil: Sardella, Fabiana. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina.
Fil: Rodríguez Gutierrez, Guillermo. Instituto de la Grasa-CSIC; España.
Fil: Monetta, Pablo Miguel. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria San Juan; Argentina.
Fil: Deiana, Cristina. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina.
Fuente
Biomass and Bioenergy 143 : 105875 (December 2020)
Materia
Olea Europaea
Residuos de Cosechas
Hidrocarburos
Hydrothermal Flow
Crop Residues
Hydrocarbons
Olivo
Alperujo
Nivel de accesibilidad
acceso restringido
Condiciones de uso
Repositorio
INTA Digital (INTA)
Institución
Instituto Nacional de Tecnología Agropecuaria
OAI Identificador
oai:localhost:20.500.12123/9813
Acceder
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oai_identifier_str oai:localhost:20.500.12123/9813
network_acronym_str INTADig
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spelling Two phase olive mill waste valorization. Hydrochar production and phenols extraction by hydrothermal carbonizationGimenez, MarianelaRodriguez, ManuelMontoro, LauraSardella, FabianaRodríguez Gutiérrez, GuillermoMonetta, Pablo MiguelDeiana, CristinaOlea EuropaeaResiduos de CosechasHidrocarburosHydrothermal FlowCrop ResiduesHydrocarbonsOlivoAlperujoOlive oil is one of the main products from the Central-Western Region of Argentine Republic, which is mostly obtained by continuous two-phase centrifugation systems. Two-phase-olive-mill-waste (TPOMW) or Alperujo is the main waste generated by this process. This research was conducted in order to give value to this waste by producing hydrochar and phenolic antioxidant compounds, products of great interest today. For this, the hydrothermal carbonization process was applied, an effective technique to synthesize a broad range of carbon-rich materials. In this study the extraction of typical phenolic compounds of the olive from the liquid phase generated in this process was also analyzed. Box Benhken response surface method was applied to obtain the optimal values of the operating conditions of the process and the selected response variables: higher heating value of the hydrochar (HHV) and content of total phenol concentration (TPC) in the liquors. Values of 31.70 MJ.kg-1 and 4429 mL.g-1 were obtained, respectively. Effectiveness of hydrothermal carbonization for hydrochar was evidenced, achieving 70% increases in the value of HHV and 40% of carbon concentration, compared to raw alperujo. In addition, values of 1.36 and 0.17 were obtained for the H/C and O/C ratios, respectively, and energy yield of 85%. Furthermore, the physico chemical properties evaluated by scanning electron microscopy and Fourier transform infrared spectroscopy, showed their potential application as adsorbent precursor. In the liquid fraction obtained, phenols could be extracted in attractive concentrations, increasing the content of hydroxytyrosol and tyrosol 3 and 9 times with respect to the untreated alperujo, respectively.EEA San JuanFil: Gimenez, Marianela. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; ArgentinaFil: Rodríguez, Manuel. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria San Juan; Argentina.Fil: Montoro, Laura. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina.Fil: Sardella, Fabiana. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina.Fil: Rodríguez Gutierrez, Guillermo. Instituto de la Grasa-CSIC; España.Fil: Monetta, Pablo Miguel. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria San Juan; Argentina.Fil: Deiana, Cristina. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina.Elsevier2021-07-14T19:17:19Z2021-07-14T19:17:19Z2020-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12123/9813https://www.sciencedirect.com/science/article/abs/pii/S09619534203040980961-9534https://doi.org/10.1016/j.biombioe.2020.105875Biomass and Bioenergy 143 : 105875 (December 2020)reponame:INTA Digital (INTA)instname:Instituto Nacional de Tecnología Agropecuariaenginfo:eu-repo/semantics/restrictedAccess2025-09-29T13:45:16Zoai:localhost:20.500.12123/9813instacron:INTAInstitucionalhttp://repositorio.inta.gob.ar/Organismo científico-tecnológicoNo correspondehttp://repositorio.inta.gob.ar/oai/requesttripaldi.nicolas@inta.gob.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:l2025-09-29 13:45:16.989INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuariafalse
dc.title.none.fl_str_mv Two phase olive mill waste valorization. Hydrochar production and phenols extraction by hydrothermal carbonization
title Two phase olive mill waste valorization. Hydrochar production and phenols extraction by hydrothermal carbonization
spellingShingle Two phase olive mill waste valorization. Hydrochar production and phenols extraction by hydrothermal carbonization
Gimenez, Marianela
Olea Europaea
Residuos de Cosechas
Hidrocarburos
Hydrothermal Flow
Crop Residues
Hydrocarbons
Olivo
Alperujo
title_short Two phase olive mill waste valorization. Hydrochar production and phenols extraction by hydrothermal carbonization
title_full Two phase olive mill waste valorization. Hydrochar production and phenols extraction by hydrothermal carbonization
title_fullStr Two phase olive mill waste valorization. Hydrochar production and phenols extraction by hydrothermal carbonization
title_full_unstemmed Two phase olive mill waste valorization. Hydrochar production and phenols extraction by hydrothermal carbonization
title_sort Two phase olive mill waste valorization. Hydrochar production and phenols extraction by hydrothermal carbonization
dc.creator.none.fl_str_mv Gimenez, Marianela
Rodriguez, Manuel
Montoro, Laura
Sardella, Fabiana
Rodríguez Gutiérrez, Guillermo
Monetta, Pablo Miguel
Deiana, Cristina
author Gimenez, Marianela
author_facet Gimenez, Marianela
Rodriguez, Manuel
Montoro, Laura
Sardella, Fabiana
Rodríguez Gutiérrez, Guillermo
Monetta, Pablo Miguel
Deiana, Cristina
author_role author
author2 Rodriguez, Manuel
Montoro, Laura
Sardella, Fabiana
Rodríguez Gutiérrez, Guillermo
Monetta, Pablo Miguel
Deiana, Cristina
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Olea Europaea
Residuos de Cosechas
Hidrocarburos
Hydrothermal Flow
Crop Residues
Hydrocarbons
Olivo
Alperujo
topic Olea Europaea
Residuos de Cosechas
Hidrocarburos
Hydrothermal Flow
Crop Residues
Hydrocarbons
Olivo
Alperujo
dc.description.none.fl_txt_mv Olive oil is one of the main products from the Central-Western Region of Argentine Republic, which is mostly obtained by continuous two-phase centrifugation systems. Two-phase-olive-mill-waste (TPOMW) or Alperujo is the main waste generated by this process. This research was conducted in order to give value to this waste by producing hydrochar and phenolic antioxidant compounds, products of great interest today. For this, the hydrothermal carbonization process was applied, an effective technique to synthesize a broad range of carbon-rich materials. In this study the extraction of typical phenolic compounds of the olive from the liquid phase generated in this process was also analyzed. Box Benhken response surface method was applied to obtain the optimal values of the operating conditions of the process and the selected response variables: higher heating value of the hydrochar (HHV) and content of total phenol concentration (TPC) in the liquors. Values of 31.70 MJ.kg-1 and 4429 mL.g-1 were obtained, respectively. Effectiveness of hydrothermal carbonization for hydrochar was evidenced, achieving 70% increases in the value of HHV and 40% of carbon concentration, compared to raw alperujo. In addition, values of 1.36 and 0.17 were obtained for the H/C and O/C ratios, respectively, and energy yield of 85%. Furthermore, the physico chemical properties evaluated by scanning electron microscopy and Fourier transform infrared spectroscopy, showed their potential application as adsorbent precursor. In the liquid fraction obtained, phenols could be extracted in attractive concentrations, increasing the content of hydroxytyrosol and tyrosol 3 and 9 times with respect to the untreated alperujo, respectively.
EEA San Juan
Fil: Gimenez, Marianela. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina
Fil: Rodríguez, Manuel. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria San Juan; Argentina.
Fil: Montoro, Laura. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina.
Fil: Sardella, Fabiana. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina.
Fil: Rodríguez Gutierrez, Guillermo. Instituto de la Grasa-CSIC; España.
Fil: Monetta, Pablo Miguel. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria San Juan; Argentina.
Fil: Deiana, Cristina. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina.
description Olive oil is one of the main products from the Central-Western Region of Argentine Republic, which is mostly obtained by continuous two-phase centrifugation systems. Two-phase-olive-mill-waste (TPOMW) or Alperujo is the main waste generated by this process. This research was conducted in order to give value to this waste by producing hydrochar and phenolic antioxidant compounds, products of great interest today. For this, the hydrothermal carbonization process was applied, an effective technique to synthesize a broad range of carbon-rich materials. In this study the extraction of typical phenolic compounds of the olive from the liquid phase generated in this process was also analyzed. Box Benhken response surface method was applied to obtain the optimal values of the operating conditions of the process and the selected response variables: higher heating value of the hydrochar (HHV) and content of total phenol concentration (TPC) in the liquors. Values of 31.70 MJ.kg-1 and 4429 mL.g-1 were obtained, respectively. Effectiveness of hydrothermal carbonization for hydrochar was evidenced, achieving 70% increases in the value of HHV and 40% of carbon concentration, compared to raw alperujo. In addition, values of 1.36 and 0.17 were obtained for the H/C and O/C ratios, respectively, and energy yield of 85%. Furthermore, the physico chemical properties evaluated by scanning electron microscopy and Fourier transform infrared spectroscopy, showed their potential application as adsorbent precursor. In the liquid fraction obtained, phenols could be extracted in attractive concentrations, increasing the content of hydroxytyrosol and tyrosol 3 and 9 times with respect to the untreated alperujo, respectively.
publishDate 2020
dc.date.none.fl_str_mv 2020-12
2021-07-14T19:17:19Z
2021-07-14T19:17:19Z
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12123/9813
https://www.sciencedirect.com/science/article/abs/pii/S0961953420304098
0961-9534
https://doi.org/10.1016/j.biombioe.2020.105875
url http://hdl.handle.net/20.500.12123/9813
https://www.sciencedirect.com/science/article/abs/pii/S0961953420304098
https://doi.org/10.1016/j.biombioe.2020.105875
identifier_str_mv 0961-9534
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/restrictedAccess
eu_rights_str_mv restrictedAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv Biomass and Bioenergy 143 : 105875 (December 2020)
reponame:INTA Digital (INTA)
instname:Instituto Nacional de Tecnología Agropecuaria
reponame_str INTA Digital (INTA)
collection INTA Digital (INTA)
instname_str Instituto Nacional de Tecnología Agropecuaria
repository.name.fl_str_mv INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuaria
repository.mail.fl_str_mv tripaldi.nicolas@inta.gob.ar
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score 12.558318

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