Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy

Autores
Diaz Pace, Diego Martin; Miguel, Roberto Esteban; Di Rocco, Hector Omar; Anabitarte García, F.; Pardini, L.; Legnaioli, S.; Lorenzetti, G.; Palleschi, V.
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Laser-induced breakdown spectroscopy (LIBS) was applied for quantitative analysis of the elemental composition of waste molding and core sands produced from industry as part of the casting process. To perform the analysis, waste foundry sands (WFS) were collected from metalcasting foundries and prepared in the form of solid pellets with the addition of polyvinyl alcohol as binder. The measurements were carried out using the Mobile double pulse instrument for LIBS analysis (Modì). The spectral analysis was carried out with the calibration-free approach (CF-LIBS). Metal elements commonly found in WFS including Al, Ba, Fe, Li, Mg, Mn, Pb, Ti, Zr, and Zn, were detected and quantified. The metal concentrations for WFS were compared with virgin sand to assess the influence of the casting material as well as the binders used in the foundries to reclaim the sands. The results demonstrated the feasibility of LIBS method as an alternative or complementary technique for the chemical characterization of WFS.
EEA Chilecito
Fil: Diaz Pace, Diego Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Tandil. Centro de Investigaciones En Física E Ingeniería del Centro de la Provincia de Buenos Aires; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Fisica Arroyo Seco; Argentina
Fil: Miguel, Roberto Esteban. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Chilecito; Argentina
Fil: Di Rocco, Hector Omar. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Fisica Arroyo Seco; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina
Fil: Anabitarte García, F. Universidad de Cantabria. Photonic Engineering Group; España
Fil: Pardini, L. National Research Council. Research Area. Institute of Chemistry of Organometallic Compounds; Italia
Fil: Legnaioli, S. National Research Council. Research Area. Institute of Chemistry of Organometallic Compounds; Italia
Fil: Lorenzetti, G. National Research Council. Research Area. Institute of Chemistry of Organometallic Compounds; Italia
Fil: Palleschi, V. National Research Council. Research Area. Institute of Chemistry of Organometallic Compounds; Italia
Fuente
Spectrochimica Acta Part B: Atomic Spectroscopy 131 : 58-65 (May 2017)
Materia
Arena
Metales
Análisis Cuantitativo
Espectroscopia
Laser
Sand
Metals
Quantitative Analysis
Spectroscopy
Lasers
Arena de Fundición
Nivel de accesibilidad
acceso restringido
Condiciones de uso
Repositorio
INTA Digital (INTA)
Institución
Instituto Nacional de Tecnología Agropecuaria
OAI Identificador
oai:localhost:20.500.12123/2747
Acceder
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oai_identifier_str oai:localhost:20.500.12123/2747
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spelling Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopyDiaz Pace, Diego MartinMiguel, Roberto EstebanDi Rocco, Hector OmarAnabitarte García, F.Pardini, L.Legnaioli, S.Lorenzetti, G.Palleschi, V.ArenaMetalesAnálisis CuantitativoEspectroscopiaLaserSandMetalsQuantitative AnalysisSpectroscopyLasersArena de FundiciónLaser-induced breakdown spectroscopy (LIBS) was applied for quantitative analysis of the elemental composition of waste molding and core sands produced from industry as part of the casting process. To perform the analysis, waste foundry sands (WFS) were collected from metalcasting foundries and prepared in the form of solid pellets with the addition of polyvinyl alcohol as binder. The measurements were carried out using the Mobile double pulse instrument for LIBS analysis (Modì). The spectral analysis was carried out with the calibration-free approach (CF-LIBS). Metal elements commonly found in WFS including Al, Ba, Fe, Li, Mg, Mn, Pb, Ti, Zr, and Zn, were detected and quantified. The metal concentrations for WFS were compared with virgin sand to assess the influence of the casting material as well as the binders used in the foundries to reclaim the sands. The results demonstrated the feasibility of LIBS method as an alternative or complementary technique for the chemical characterization of WFS.EEA ChilecitoFil: Diaz Pace, Diego Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Tandil. Centro de Investigaciones En Física E Ingeniería del Centro de la Provincia de Buenos Aires; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Fisica Arroyo Seco; ArgentinaFil: Miguel, Roberto Esteban. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Chilecito; ArgentinaFil: Di Rocco, Hector Omar. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Fisica Arroyo Seco; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; ArgentinaFil: Anabitarte García, F. Universidad de Cantabria. Photonic Engineering Group; EspañaFil: Pardini, L. National Research Council. Research Area. Institute of Chemistry of Organometallic Compounds; ItaliaFil: Legnaioli, S. National Research Council. Research Area. Institute of Chemistry of Organometallic Compounds; ItaliaFil: Lorenzetti, G. National Research Council. Research Area. Institute of Chemistry of Organometallic Compounds; ItaliaFil: Palleschi, V. National Research Council. Research Area. Institute of Chemistry of Organometallic Compounds; Italia2018-07-10T13:49:14Z2018-07-10T13:49:14Z2017-05-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttps://www.sciencedirect.com/science/article/pii/S0584854716301628http://hdl.handle.net/20.500.12123/27470584-8547https://doi.org/10.1016/j.sab.2017.03.007Spectrochimica Acta Part B: Atomic Spectroscopy 131 : 58-65 (May 2017)reponame:INTA Digital (INTA)instname:Instituto Nacional de Tecnología Agropecuariaenginfo:eu-repo/semantics/restrictedAccess2025-09-29T13:44:21Zoai:localhost:20.500.12123/2747instacron:INTAInstitucionalhttp://repositorio.inta.gob.ar/Organismo científico-tecnológicoNo correspondehttp://repositorio.inta.gob.ar/oai/requesttripaldi.nicolas@inta.gob.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:l2025-09-29 13:44:22.046INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuariafalse
dc.title.none.fl_str_mv Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
title Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
spellingShingle Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
Diaz Pace, Diego Martin
Arena
Metales
Análisis Cuantitativo
Espectroscopia
Laser
Sand
Metals
Quantitative Analysis
Spectroscopy
Lasers
Arena de Fundición
title_short Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
title_full Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
title_fullStr Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
title_full_unstemmed Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
title_sort Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
dc.creator.none.fl_str_mv Diaz Pace, Diego Martin
Miguel, Roberto Esteban
Di Rocco, Hector Omar
Anabitarte García, F.
Pardini, L.
Legnaioli, S.
Lorenzetti, G.
Palleschi, V.
author Diaz Pace, Diego Martin
author_facet Diaz Pace, Diego Martin
Miguel, Roberto Esteban
Di Rocco, Hector Omar
Anabitarte García, F.
Pardini, L.
Legnaioli, S.
Lorenzetti, G.
Palleschi, V.
author_role author
author2 Miguel, Roberto Esteban
Di Rocco, Hector Omar
Anabitarte García, F.
Pardini, L.
Legnaioli, S.
Lorenzetti, G.
Palleschi, V.
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Arena
Metales
Análisis Cuantitativo
Espectroscopia
Laser
Sand
Metals
Quantitative Analysis
Spectroscopy
Lasers
Arena de Fundición
topic Arena
Metales
Análisis Cuantitativo
Espectroscopia
Laser
Sand
Metals
Quantitative Analysis
Spectroscopy
Lasers
Arena de Fundición
dc.description.none.fl_txt_mv Laser-induced breakdown spectroscopy (LIBS) was applied for quantitative analysis of the elemental composition of waste molding and core sands produced from industry as part of the casting process. To perform the analysis, waste foundry sands (WFS) were collected from metalcasting foundries and prepared in the form of solid pellets with the addition of polyvinyl alcohol as binder. The measurements were carried out using the Mobile double pulse instrument for LIBS analysis (Modì). The spectral analysis was carried out with the calibration-free approach (CF-LIBS). Metal elements commonly found in WFS including Al, Ba, Fe, Li, Mg, Mn, Pb, Ti, Zr, and Zn, were detected and quantified. The metal concentrations for WFS were compared with virgin sand to assess the influence of the casting material as well as the binders used in the foundries to reclaim the sands. The results demonstrated the feasibility of LIBS method as an alternative or complementary technique for the chemical characterization of WFS.
EEA Chilecito
Fil: Diaz Pace, Diego Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Tandil. Centro de Investigaciones En Física E Ingeniería del Centro de la Provincia de Buenos Aires; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Fisica Arroyo Seco; Argentina
Fil: Miguel, Roberto Esteban. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Chilecito; Argentina
Fil: Di Rocco, Hector Omar. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Fisica Arroyo Seco; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina
Fil: Anabitarte García, F. Universidad de Cantabria. Photonic Engineering Group; España
Fil: Pardini, L. National Research Council. Research Area. Institute of Chemistry of Organometallic Compounds; Italia
Fil: Legnaioli, S. National Research Council. Research Area. Institute of Chemistry of Organometallic Compounds; Italia
Fil: Lorenzetti, G. National Research Council. Research Area. Institute of Chemistry of Organometallic Compounds; Italia
Fil: Palleschi, V. National Research Council. Research Area. Institute of Chemistry of Organometallic Compounds; Italia
description Laser-induced breakdown spectroscopy (LIBS) was applied for quantitative analysis of the elemental composition of waste molding and core sands produced from industry as part of the casting process. To perform the analysis, waste foundry sands (WFS) were collected from metalcasting foundries and prepared in the form of solid pellets with the addition of polyvinyl alcohol as binder. The measurements were carried out using the Mobile double pulse instrument for LIBS analysis (Modì). The spectral analysis was carried out with the calibration-free approach (CF-LIBS). Metal elements commonly found in WFS including Al, Ba, Fe, Li, Mg, Mn, Pb, Ti, Zr, and Zn, were detected and quantified. The metal concentrations for WFS were compared with virgin sand to assess the influence of the casting material as well as the binders used in the foundries to reclaim the sands. The results demonstrated the feasibility of LIBS method as an alternative or complementary technique for the chemical characterization of WFS.
publishDate 2017
dc.date.none.fl_str_mv 2017-05-01
2018-07-10T13:49:14Z
2018-07-10T13:49:14Z
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://www.sciencedirect.com/science/article/pii/S0584854716301628
http://hdl.handle.net/20.500.12123/2747
0584-8547
https://doi.org/10.1016/j.sab.2017.03.007
url https://www.sciencedirect.com/science/article/pii/S0584854716301628
http://hdl.handle.net/20.500.12123/2747
https://doi.org/10.1016/j.sab.2017.03.007
identifier_str_mv 0584-8547
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/restrictedAccess
eu_rights_str_mv restrictedAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv Spectrochimica Acta Part B: Atomic Spectroscopy 131 : 58-65 (May 2017)
reponame:INTA Digital (INTA)
instname:Instituto Nacional de Tecnología Agropecuaria
reponame_str INTA Digital (INTA)
collection INTA Digital (INTA)
instname_str Instituto Nacional de Tecnología Agropecuaria
repository.name.fl_str_mv INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuaria
repository.mail.fl_str_mv tripaldi.nicolas@inta.gob.ar
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score 12.559606

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