Mathematical modeling of reverse atom transfer radical polymerization in miniemulsion
- Autores
- Zurman, Ayelen; Sarmoria, Claudia; Brandolin, Adriana; Asteasuain, Mariano
- Año de publicación
- 2018
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- In this work, we study the reverse atom transfer radical polymerization in miniemulsion using a water-soluble initiator. This study is motivated by the technological advantages of performing polymerizations in dispersed systems, and the attractive possibilities of controlled radical polymerization techniques to produce tailor made polymers. A mathematical model for this system is presented. The model predicts average molecular properties as well as the full molecular weight distribution (MWD) for different experimental conditions. The method of moments is applied for calculating average properties and the probability generating function (pgf) technique is used to model the MWD. The model is based on the mass balance equations of In this work, we study the reverse atom transfer radical polymerization in miniemulsion using a water-soluble initiator. This study is motivated by the technological advantages of performing polymerizations in dispersed systems, and the attractive possibilities of controlled radical polymerization techniques to produce tailor made polymers. A mathematical model for this system is presented. The model predicts average molecular properties as well as the full molecular weight distribution (MWD) for different experimental conditions. The method of moments is applied for calculating average properties and the probability generating function (pgf) technique is used to model the MWD. The model is based on the mass balance equations of the reacting species. It takes into account the reactions in both the aqueous and organic phases and the mass transfer between them. Predicted conversions, average molecular weights, polydispersity indexes and MWDs for different experimental conditions agree well with experimental data reported in the literature. reacting species. It takes into account the reactions in both the aqueous and organic phases and the mass transfer between them. Predicted conversions, average molecular weights, polydispersity indexes and MWDs for different experimental conditions agree well with experimental data reported in the literature.
Fil: Zurman, Ayelen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Sarmoria, Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
Fil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
Fil: Asteasuain, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina - Materia
-
REVERSE ATOM TRANSFER RADICAL POLYMERIZATION
MINIEMULSION
WATER-SOLUBLE INITIATOR
MOLECULAR WEIGHT DISTRIBUTION
MATHEMATICAL MODELING - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/90918
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Mathematical modeling of reverse atom transfer radical polymerization in miniemulsionZurman, AyelenSarmoria, ClaudiaBrandolin, AdrianaAsteasuain, MarianoREVERSE ATOM TRANSFER RADICAL POLYMERIZATIONMINIEMULSIONWATER-SOLUBLE INITIATORMOLECULAR WEIGHT DISTRIBUTIONMATHEMATICAL MODELINGhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2In this work, we study the reverse atom transfer radical polymerization in miniemulsion using a water-soluble initiator. This study is motivated by the technological advantages of performing polymerizations in dispersed systems, and the attractive possibilities of controlled radical polymerization techniques to produce tailor made polymers. A mathematical model for this system is presented. The model predicts average molecular properties as well as the full molecular weight distribution (MWD) for different experimental conditions. The method of moments is applied for calculating average properties and the probability generating function (pgf) technique is used to model the MWD. The model is based on the mass balance equations of In this work, we study the reverse atom transfer radical polymerization in miniemulsion using a water-soluble initiator. This study is motivated by the technological advantages of performing polymerizations in dispersed systems, and the attractive possibilities of controlled radical polymerization techniques to produce tailor made polymers. A mathematical model for this system is presented. The model predicts average molecular properties as well as the full molecular weight distribution (MWD) for different experimental conditions. The method of moments is applied for calculating average properties and the probability generating function (pgf) technique is used to model the MWD. The model is based on the mass balance equations of the reacting species. It takes into account the reactions in both the aqueous and organic phases and the mass transfer between them. Predicted conversions, average molecular weights, polydispersity indexes and MWDs for different experimental conditions agree well with experimental data reported in the literature. reacting species. It takes into account the reactions in both the aqueous and organic phases and the mass transfer between them. Predicted conversions, average molecular weights, polydispersity indexes and MWDs for different experimental conditions agree well with experimental data reported in the literature.Fil: Zurman, Ayelen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Sarmoria, Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; ArgentinaFil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; ArgentinaFil: Asteasuain, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; ArgentinaElsevier2018-04-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/90918Zurman, Ayelen; Sarmoria, Claudia; Brandolin, Adriana; Asteasuain, Mariano; Mathematical modeling of reverse atom transfer radical polymerization in miniemulsion; Elsevier; Computational Materials Science; 145; 1-4-2018; 48-590927-0256CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0927025617307267info:eu-repo/semantics/altIdentifier/doi/10.1016/j.commatsci.2017.12.038info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:36:38Zoai:ri.conicet.gov.ar:11336/90918instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:36:38.717CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Mathematical modeling of reverse atom transfer radical polymerization in miniemulsion |
title |
Mathematical modeling of reverse atom transfer radical polymerization in miniemulsion |
spellingShingle |
Mathematical modeling of reverse atom transfer radical polymerization in miniemulsion Zurman, Ayelen REVERSE ATOM TRANSFER RADICAL POLYMERIZATION MINIEMULSION WATER-SOLUBLE INITIATOR MOLECULAR WEIGHT DISTRIBUTION MATHEMATICAL MODELING |
title_short |
Mathematical modeling of reverse atom transfer radical polymerization in miniemulsion |
title_full |
Mathematical modeling of reverse atom transfer radical polymerization in miniemulsion |
title_fullStr |
Mathematical modeling of reverse atom transfer radical polymerization in miniemulsion |
title_full_unstemmed |
Mathematical modeling of reverse atom transfer radical polymerization in miniemulsion |
title_sort |
Mathematical modeling of reverse atom transfer radical polymerization in miniemulsion |
dc.creator.none.fl_str_mv |
Zurman, Ayelen Sarmoria, Claudia Brandolin, Adriana Asteasuain, Mariano |
author |
Zurman, Ayelen |
author_facet |
Zurman, Ayelen Sarmoria, Claudia Brandolin, Adriana Asteasuain, Mariano |
author_role |
author |
author2 |
Sarmoria, Claudia Brandolin, Adriana Asteasuain, Mariano |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
REVERSE ATOM TRANSFER RADICAL POLYMERIZATION MINIEMULSION WATER-SOLUBLE INITIATOR MOLECULAR WEIGHT DISTRIBUTION MATHEMATICAL MODELING |
topic |
REVERSE ATOM TRANSFER RADICAL POLYMERIZATION MINIEMULSION WATER-SOLUBLE INITIATOR MOLECULAR WEIGHT DISTRIBUTION MATHEMATICAL MODELING |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
In this work, we study the reverse atom transfer radical polymerization in miniemulsion using a water-soluble initiator. This study is motivated by the technological advantages of performing polymerizations in dispersed systems, and the attractive possibilities of controlled radical polymerization techniques to produce tailor made polymers. A mathematical model for this system is presented. The model predicts average molecular properties as well as the full molecular weight distribution (MWD) for different experimental conditions. The method of moments is applied for calculating average properties and the probability generating function (pgf) technique is used to model the MWD. The model is based on the mass balance equations of In this work, we study the reverse atom transfer radical polymerization in miniemulsion using a water-soluble initiator. This study is motivated by the technological advantages of performing polymerizations in dispersed systems, and the attractive possibilities of controlled radical polymerization techniques to produce tailor made polymers. A mathematical model for this system is presented. The model predicts average molecular properties as well as the full molecular weight distribution (MWD) for different experimental conditions. The method of moments is applied for calculating average properties and the probability generating function (pgf) technique is used to model the MWD. The model is based on the mass balance equations of the reacting species. It takes into account the reactions in both the aqueous and organic phases and the mass transfer between them. Predicted conversions, average molecular weights, polydispersity indexes and MWDs for different experimental conditions agree well with experimental data reported in the literature. reacting species. It takes into account the reactions in both the aqueous and organic phases and the mass transfer between them. Predicted conversions, average molecular weights, polydispersity indexes and MWDs for different experimental conditions agree well with experimental data reported in the literature. Fil: Zurman, Ayelen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina Fil: Sarmoria, Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina Fil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina Fil: Asteasuain, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina |
description |
In this work, we study the reverse atom transfer radical polymerization in miniemulsion using a water-soluble initiator. This study is motivated by the technological advantages of performing polymerizations in dispersed systems, and the attractive possibilities of controlled radical polymerization techniques to produce tailor made polymers. A mathematical model for this system is presented. The model predicts average molecular properties as well as the full molecular weight distribution (MWD) for different experimental conditions. The method of moments is applied for calculating average properties and the probability generating function (pgf) technique is used to model the MWD. The model is based on the mass balance equations of In this work, we study the reverse atom transfer radical polymerization in miniemulsion using a water-soluble initiator. This study is motivated by the technological advantages of performing polymerizations in dispersed systems, and the attractive possibilities of controlled radical polymerization techniques to produce tailor made polymers. A mathematical model for this system is presented. The model predicts average molecular properties as well as the full molecular weight distribution (MWD) for different experimental conditions. The method of moments is applied for calculating average properties and the probability generating function (pgf) technique is used to model the MWD. The model is based on the mass balance equations of the reacting species. It takes into account the reactions in both the aqueous and organic phases and the mass transfer between them. Predicted conversions, average molecular weights, polydispersity indexes and MWDs for different experimental conditions agree well with experimental data reported in the literature. reacting species. It takes into account the reactions in both the aqueous and organic phases and the mass transfer between them. Predicted conversions, average molecular weights, polydispersity indexes and MWDs for different experimental conditions agree well with experimental data reported in the literature. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-04-01 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/90918 Zurman, Ayelen; Sarmoria, Claudia; Brandolin, Adriana; Asteasuain, Mariano; Mathematical modeling of reverse atom transfer radical polymerization in miniemulsion; Elsevier; Computational Materials Science; 145; 1-4-2018; 48-59 0927-0256 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/90918 |
identifier_str_mv |
Zurman, Ayelen; Sarmoria, Claudia; Brandolin, Adriana; Asteasuain, Mariano; Mathematical modeling of reverse atom transfer radical polymerization in miniemulsion; Elsevier; Computational Materials Science; 145; 1-4-2018; 48-59 0927-0256 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0927025617307267 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.commatsci.2017.12.038 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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13.070432 |