Polymerization kinetics and microstructure of waterborne acrylic/alkyd nanocomposites synthesized by miniemulsion

Autores
Goikoetxea, Monika; Minari, Roque Javier; Beristain, Itxaso; Paulis, María; Barandiaran, María J.; Asua, José M.
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Waterborne acrylic-alkyd nanocomposites are expected to combine the positive properties of alkyd resins and acrylic polymers. In this work the kinetics of the miniemulsion polymerization used to synthesize these nanocomposites and the effect of the process variables on the polymer architecture and particle morphology was investigated. It was found that resin hydrophobicity and the type of initiator strongly affected the microstructure of these materials. The mechanisms responsible for these effects were discussed.
Fil: Goikoetxea, Monika. Universidad del País Vasco; España
Fil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Beristain, Itxaso. Universidad del País Vasco; España
Fil: Paulis, María. Universidad del País Vasco; España
Fil: Barandiaran, María J.. Universidad del País Vasco; España
Fil: Asua, José M.. Universidad del País Vasco; España
Materia
Coatings
Composites
Miniemulsion Polymerization
Alkyds
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/17111
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/17111
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Polymerization kinetics and microstructure of waterborne acrylic/alkyd nanocomposites synthesized by miniemulsionGoikoetxea, MonikaMinari, Roque JavierBeristain, ItxasoPaulis, MaríaBarandiaran, María J.Asua, José M.CoatingsCompositesMiniemulsion PolymerizationAlkydshttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Waterborne acrylic-alkyd nanocomposites are expected to combine the positive properties of alkyd resins and acrylic polymers. In this work the kinetics of the miniemulsion polymerization used to synthesize these nanocomposites and the effect of the process variables on the polymer architecture and particle morphology was investigated. It was found that resin hydrophobicity and the type of initiator strongly affected the microstructure of these materials. The mechanisms responsible for these effects were discussed.Fil: Goikoetxea, Monika. Universidad del País Vasco; EspañaFil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Beristain, Itxaso. Universidad del País Vasco; EspañaFil: Paulis, María. Universidad del País Vasco; EspañaFil: Barandiaran, María J.. Universidad del País Vasco; EspañaFil: Asua, José M.. Universidad del País Vasco; EspañaJohn Wiley & Sons Inc2009-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/17111Goikoetxea, Monika; Minari, Roque Javier; Beristain, Itxaso; Paulis, María; Barandiaran, María J.; et al.; Polymerization kinetics and microstructure of waterborne acrylic/alkyd nanocomposites synthesized by miniemulsion; John Wiley & Sons Inc; Journal Of Polymer Science Part A: Polymer Chemistry; 47; 19; 8-2009; 4871-48850887-624Xenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/pola.23535info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/pola.23535/abstractinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:49:57Zoai:ri.conicet.gov.ar:11336/17111instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:49:57.505CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Polymerization kinetics and microstructure of waterborne acrylic/alkyd nanocomposites synthesized by miniemulsion
title Polymerization kinetics and microstructure of waterborne acrylic/alkyd nanocomposites synthesized by miniemulsion
spellingShingle Polymerization kinetics and microstructure of waterborne acrylic/alkyd nanocomposites synthesized by miniemulsion
Goikoetxea, Monika
Coatings
Composites
Miniemulsion Polymerization
Alkyds
title_short Polymerization kinetics and microstructure of waterborne acrylic/alkyd nanocomposites synthesized by miniemulsion
title_full Polymerization kinetics and microstructure of waterborne acrylic/alkyd nanocomposites synthesized by miniemulsion
title_fullStr Polymerization kinetics and microstructure of waterborne acrylic/alkyd nanocomposites synthesized by miniemulsion
title_full_unstemmed Polymerization kinetics and microstructure of waterborne acrylic/alkyd nanocomposites synthesized by miniemulsion
title_sort Polymerization kinetics and microstructure of waterborne acrylic/alkyd nanocomposites synthesized by miniemulsion
dc.creator.none.fl_str_mv Goikoetxea, Monika
Minari, Roque Javier
Beristain, Itxaso
Paulis, María
Barandiaran, María J.
Asua, José M.
author Goikoetxea, Monika
author_facet Goikoetxea, Monika
Minari, Roque Javier
Beristain, Itxaso
Paulis, María
Barandiaran, María J.
Asua, José M.
author_role author
author2 Minari, Roque Javier
Beristain, Itxaso
Paulis, María
Barandiaran, María J.
Asua, José M.
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Coatings
Composites
Miniemulsion Polymerization
Alkyds
topic Coatings
Composites
Miniemulsion Polymerization
Alkyds
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Waterborne acrylic-alkyd nanocomposites are expected to combine the positive properties of alkyd resins and acrylic polymers. In this work the kinetics of the miniemulsion polymerization used to synthesize these nanocomposites and the effect of the process variables on the polymer architecture and particle morphology was investigated. It was found that resin hydrophobicity and the type of initiator strongly affected the microstructure of these materials. The mechanisms responsible for these effects were discussed.
Fil: Goikoetxea, Monika. Universidad del País Vasco; España
Fil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Beristain, Itxaso. Universidad del País Vasco; España
Fil: Paulis, María. Universidad del País Vasco; España
Fil: Barandiaran, María J.. Universidad del País Vasco; España
Fil: Asua, José M.. Universidad del País Vasco; España
description Waterborne acrylic-alkyd nanocomposites are expected to combine the positive properties of alkyd resins and acrylic polymers. In this work the kinetics of the miniemulsion polymerization used to synthesize these nanocomposites and the effect of the process variables on the polymer architecture and particle morphology was investigated. It was found that resin hydrophobicity and the type of initiator strongly affected the microstructure of these materials. The mechanisms responsible for these effects were discussed.
publishDate 2009
dc.date.none.fl_str_mv 2009-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/17111
Goikoetxea, Monika; Minari, Roque Javier; Beristain, Itxaso; Paulis, María; Barandiaran, María J.; et al.; Polymerization kinetics and microstructure of waterborne acrylic/alkyd nanocomposites synthesized by miniemulsion; John Wiley & Sons Inc; Journal Of Polymer Science Part A: Polymer Chemistry; 47; 19; 8-2009; 4871-4885
0887-624X
url http://hdl.handle.net/11336/17111
identifier_str_mv Goikoetxea, Monika; Minari, Roque Javier; Beristain, Itxaso; Paulis, María; Barandiaran, María J.; et al.; Polymerization kinetics and microstructure of waterborne acrylic/alkyd nanocomposites synthesized by miniemulsion; John Wiley & Sons Inc; Journal Of Polymer Science Part A: Polymer Chemistry; 47; 19; 8-2009; 4871-4885
0887-624X
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/pola.23535
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/pola.23535/abstract
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Inc
publisher.none.fl_str_mv John Wiley & Sons Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613542854000640
score 13.070432

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