Toughened Polystyrene Nanoparticles through High-Solids Miniemulsion Polymerization

Autores
Ronco, Ludmila Irene; Minari, Roque Javier; Passeggi, Mario Cesar Guillermo; Meira, Gregorio Raul; Gugliotta, Luis Marcelino
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Polystyrene nanoparticles toughened with polybutadiene were synthesized by miniemulsion polymerization of 50% solids content. The effects of recipes and reaction conditions on the polymerization kinetics, polymer microstructure, particle morphology, and mechanical properties of the produced thermoplastic materials, are discussed. The final material characteristics are strongly dependant on the chemical nature of the employed initiator, and an interpretation for the observed effects is presented. The obtained nanostructured polystyrenes exhibit mechanical properties similar to those of the commercial HIPS, but with the typical advantages of polymerizations in disperse medium such as low environmental impact, high monomer conversion, and fast heat transfer.
Fil: Ronco, Ludmila Irene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina
Fil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina
Fil: Passeggi, Mario Cesar Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Física del Litoral; Argentina
Fil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina
Fil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina
Materia
Miniemulsion Polymerization
High-Solids Content
Toughened Polystyrene
Polybutadiene
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/4400
Acceder
id CONICETDig_b08fd02b0a472113a379d2e8dcf34f87
oai_identifier_str oai:ri.conicet.gov.ar:11336/4400
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Toughened Polystyrene Nanoparticles through High-Solids Miniemulsion PolymerizationRonco, Ludmila IreneMinari, Roque JavierPasseggi, Mario Cesar GuillermoMeira, Gregorio RaulGugliotta, Luis MarcelinoMiniemulsion PolymerizationHigh-Solids ContentToughened PolystyrenePolybutadienehttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Polystyrene nanoparticles toughened with polybutadiene were synthesized by miniemulsion polymerization of 50% solids content. The effects of recipes and reaction conditions on the polymerization kinetics, polymer microstructure, particle morphology, and mechanical properties of the produced thermoplastic materials, are discussed. The final material characteristics are strongly dependant on the chemical nature of the employed initiator, and an interpretation for the observed effects is presented. The obtained nanostructured polystyrenes exhibit mechanical properties similar to those of the commercial HIPS, but with the typical advantages of polymerizations in disperse medium such as low environmental impact, high monomer conversion, and fast heat transfer.Fil: Ronco, Ludmila Irene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); ArgentinaFil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); ArgentinaFil: Passeggi, Mario Cesar Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Física del Litoral; ArgentinaFil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); ArgentinaFil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); ArgentinaElsevier2015-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/4400Ronco, Ludmila Irene; Minari, Roque Javier; Passeggi, Mario Cesar Guillermo; Meira, Gregorio Raul; Gugliotta, Luis Marcelino; Toughened Polystyrene Nanoparticles through High-Solids Miniemulsion Polymerization; Elsevier; Chemical Engineering Journal; 263; 3-2015; 231-2381385-8947enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1385894714014880info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2014.11.033info:eu-repo/semantics/altIdentifier/issn/1385-8947info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:56:45Zoai:ri.conicet.gov.ar:11336/4400instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:56:46.122CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Toughened Polystyrene Nanoparticles through High-Solids Miniemulsion Polymerization
title Toughened Polystyrene Nanoparticles through High-Solids Miniemulsion Polymerization
spellingShingle Toughened Polystyrene Nanoparticles through High-Solids Miniemulsion Polymerization
Ronco, Ludmila Irene
Miniemulsion Polymerization
High-Solids Content
Toughened Polystyrene
Polybutadiene
title_short Toughened Polystyrene Nanoparticles through High-Solids Miniemulsion Polymerization
title_full Toughened Polystyrene Nanoparticles through High-Solids Miniemulsion Polymerization
title_fullStr Toughened Polystyrene Nanoparticles through High-Solids Miniemulsion Polymerization
title_full_unstemmed Toughened Polystyrene Nanoparticles through High-Solids Miniemulsion Polymerization
title_sort Toughened Polystyrene Nanoparticles through High-Solids Miniemulsion Polymerization
dc.creator.none.fl_str_mv Ronco, Ludmila Irene
Minari, Roque Javier
Passeggi, Mario Cesar Guillermo
Meira, Gregorio Raul
Gugliotta, Luis Marcelino
author Ronco, Ludmila Irene
author_facet Ronco, Ludmila Irene
Minari, Roque Javier
Passeggi, Mario Cesar Guillermo
Meira, Gregorio Raul
Gugliotta, Luis Marcelino
author_role author
author2 Minari, Roque Javier
Passeggi, Mario Cesar Guillermo
Meira, Gregorio Raul
Gugliotta, Luis Marcelino
author2_role author
author
author
author
dc.subject.none.fl_str_mv Miniemulsion Polymerization
High-Solids Content
Toughened Polystyrene
Polybutadiene
topic Miniemulsion Polymerization
High-Solids Content
Toughened Polystyrene
Polybutadiene
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Polystyrene nanoparticles toughened with polybutadiene were synthesized by miniemulsion polymerization of 50% solids content. The effects of recipes and reaction conditions on the polymerization kinetics, polymer microstructure, particle morphology, and mechanical properties of the produced thermoplastic materials, are discussed. The final material characteristics are strongly dependant on the chemical nature of the employed initiator, and an interpretation for the observed effects is presented. The obtained nanostructured polystyrenes exhibit mechanical properties similar to those of the commercial HIPS, but with the typical advantages of polymerizations in disperse medium such as low environmental impact, high monomer conversion, and fast heat transfer.
Fil: Ronco, Ludmila Irene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina
Fil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina
Fil: Passeggi, Mario Cesar Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Física del Litoral; Argentina
Fil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina
Fil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina
description Polystyrene nanoparticles toughened with polybutadiene were synthesized by miniemulsion polymerization of 50% solids content. The effects of recipes and reaction conditions on the polymerization kinetics, polymer microstructure, particle morphology, and mechanical properties of the produced thermoplastic materials, are discussed. The final material characteristics are strongly dependant on the chemical nature of the employed initiator, and an interpretation for the observed effects is presented. The obtained nanostructured polystyrenes exhibit mechanical properties similar to those of the commercial HIPS, but with the typical advantages of polymerizations in disperse medium such as low environmental impact, high monomer conversion, and fast heat transfer.
publishDate 2015
dc.date.none.fl_str_mv 2015-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/4400
Ronco, Ludmila Irene; Minari, Roque Javier; Passeggi, Mario Cesar Guillermo; Meira, Gregorio Raul; Gugliotta, Luis Marcelino; Toughened Polystyrene Nanoparticles through High-Solids Miniemulsion Polymerization; Elsevier; Chemical Engineering Journal; 263; 3-2015; 231-238
1385-8947
url http://hdl.handle.net/11336/4400
identifier_str_mv Ronco, Ludmila Irene; Minari, Roque Javier; Passeggi, Mario Cesar Guillermo; Meira, Gregorio Raul; Gugliotta, Luis Marcelino; Toughened Polystyrene Nanoparticles through High-Solids Miniemulsion Polymerization; Elsevier; Chemical Engineering Journal; 263; 3-2015; 231-238
1385-8947
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1385894714014880
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2014.11.033
info:eu-repo/semantics/altIdentifier/issn/1385-8947
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613703288225792
score 13.070432

Publicaciones similares