Incorporation of Polybutadiene into Waterborne Polystyrene Nanoparticles via Miniemulsion Polymerization
- Autores
- Ronco, Ludmila Irene; Minari, Roque Javier; Vega, Jorge Ruben; Meira, Gregorio Raul; Gugliotta, Luis Marcelino
- Año de publicación
- 2013
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The incorporation of polybutadiene in waterborne polystyrene nanoparticles by miniemulsion polymerization is expected to positively combine the properties of both materials,improving the impact resistance and toughness. The kinetics of the miniemulsion polymerization used to synthesize these hybrid nanomaterials and the effect of the reaction variables on the polymer microstructure and particle morphology were investigated. Both molecular microstructure and final particle morphology (core?shell, ??salami?? or threephase type) depended on the nature of the employed polybutadiene based rubbers and initiators. The mechanisms responsible for these effects were discussed.
Fil: Ronco, Ludmila Irene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); Argentina
Fil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); Argentina
Fil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); Argentina. Universidad Tecnologica Nacional; Argentina
Fil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); Argentina
Fil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); Argentina - Materia
-
Miniemulsion
Polystyrene
Polybutadiene
Nanocomposites - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/8796
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Incorporation of Polybutadiene into Waterborne Polystyrene Nanoparticles via Miniemulsion PolymerizationRonco, Ludmila IreneMinari, Roque JavierVega, Jorge RubenMeira, Gregorio RaulGugliotta, Luis MarcelinoMiniemulsionPolystyrenePolybutadieneNanocompositeshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The incorporation of polybutadiene in waterborne polystyrene nanoparticles by miniemulsion polymerization is expected to positively combine the properties of both materials,improving the impact resistance and toughness. The kinetics of the miniemulsion polymerization used to synthesize these hybrid nanomaterials and the effect of the reaction variables on the polymer microstructure and particle morphology were investigated. Both molecular microstructure and final particle morphology (core?shell, ??salami?? or threephase type) depended on the nature of the employed polybutadiene based rubbers and initiators. The mechanisms responsible for these effects were discussed.Fil: Ronco, Ludmila Irene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); ArgentinaFil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); ArgentinaFil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); Argentina. Universidad Tecnologica Nacional; ArgentinaFil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); ArgentinaFil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); ArgentinaElsevier2013-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/8796Ronco, Ludmila Irene; Minari, Roque Javier; Vega, Jorge Ruben; Meira, Gregorio Raul; Gugliotta, Luis Marcelino; Incorporation of Polybutadiene into Waterborne Polystyrene Nanoparticles via Miniemulsion Polymerization; Elsevier; European Polymer Journal; 49; 9; 3-2013; 2635-26440014-3057enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.eurpolymj.2013.06.011info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0014305713002814info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:29:44Zoai:ri.conicet.gov.ar:11336/8796instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:29:44.941CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Incorporation of Polybutadiene into Waterborne Polystyrene Nanoparticles via Miniemulsion Polymerization |
title |
Incorporation of Polybutadiene into Waterborne Polystyrene Nanoparticles via Miniemulsion Polymerization |
spellingShingle |
Incorporation of Polybutadiene into Waterborne Polystyrene Nanoparticles via Miniemulsion Polymerization Ronco, Ludmila Irene Miniemulsion Polystyrene Polybutadiene Nanocomposites |
title_short |
Incorporation of Polybutadiene into Waterborne Polystyrene Nanoparticles via Miniemulsion Polymerization |
title_full |
Incorporation of Polybutadiene into Waterborne Polystyrene Nanoparticles via Miniemulsion Polymerization |
title_fullStr |
Incorporation of Polybutadiene into Waterborne Polystyrene Nanoparticles via Miniemulsion Polymerization |
title_full_unstemmed |
Incorporation of Polybutadiene into Waterborne Polystyrene Nanoparticles via Miniemulsion Polymerization |
title_sort |
Incorporation of Polybutadiene into Waterborne Polystyrene Nanoparticles via Miniemulsion Polymerization |
dc.creator.none.fl_str_mv |
Ronco, Ludmila Irene Minari, Roque Javier Vega, Jorge Ruben Meira, Gregorio Raul Gugliotta, Luis Marcelino |
author |
Ronco, Ludmila Irene |
author_facet |
Ronco, Ludmila Irene Minari, Roque Javier Vega, Jorge Ruben Meira, Gregorio Raul Gugliotta, Luis Marcelino |
author_role |
author |
author2 |
Minari, Roque Javier Vega, Jorge Ruben Meira, Gregorio Raul Gugliotta, Luis Marcelino |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
Miniemulsion Polystyrene Polybutadiene Nanocomposites |
topic |
Miniemulsion Polystyrene Polybutadiene Nanocomposites |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The incorporation of polybutadiene in waterborne polystyrene nanoparticles by miniemulsion polymerization is expected to positively combine the properties of both materials,improving the impact resistance and toughness. The kinetics of the miniemulsion polymerization used to synthesize these hybrid nanomaterials and the effect of the reaction variables on the polymer microstructure and particle morphology were investigated. Both molecular microstructure and final particle morphology (core?shell, ??salami?? or threephase type) depended on the nature of the employed polybutadiene based rubbers and initiators. The mechanisms responsible for these effects were discussed. Fil: Ronco, Ludmila Irene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); Argentina Fil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); Argentina Fil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); Argentina. Universidad Tecnologica Nacional; Argentina Fil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); Argentina Fil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); Argentina |
description |
The incorporation of polybutadiene in waterborne polystyrene nanoparticles by miniemulsion polymerization is expected to positively combine the properties of both materials,improving the impact resistance and toughness. The kinetics of the miniemulsion polymerization used to synthesize these hybrid nanomaterials and the effect of the reaction variables on the polymer microstructure and particle morphology were investigated. Both molecular microstructure and final particle morphology (core?shell, ??salami?? or threephase type) depended on the nature of the employed polybutadiene based rubbers and initiators. The mechanisms responsible for these effects were discussed. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-03 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/8796 Ronco, Ludmila Irene; Minari, Roque Javier; Vega, Jorge Ruben; Meira, Gregorio Raul; Gugliotta, Luis Marcelino; Incorporation of Polybutadiene into Waterborne Polystyrene Nanoparticles via Miniemulsion Polymerization; Elsevier; European Polymer Journal; 49; 9; 3-2013; 2635-2644 0014-3057 |
url |
http://hdl.handle.net/11336/8796 |
identifier_str_mv |
Ronco, Ludmila Irene; Minari, Roque Javier; Vega, Jorge Ruben; Meira, Gregorio Raul; Gugliotta, Luis Marcelino; Incorporation of Polybutadiene into Waterborne Polystyrene Nanoparticles via Miniemulsion Polymerization; Elsevier; European Polymer Journal; 49; 9; 3-2013; 2635-2644 0014-3057 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.eurpolymj.2013.06.011 info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0014305713002814 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614304529121280 |
score |
13.070432 |