Direct Lithium Recovery from Aqueous Electrolytes with Electrochemical Ion Pumping and Lithium Intercalation

Autores
Calvo, Ernesto Julio
Año de publicación
2021
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this mini-review, we provide an account of recent developments on electrochemical methods for the direct extraction of lithium (DEL) from natural brines, geothermal fluids, seawater, and battery recycling electrolytes by ion-pumping entropy cells. A critical discussion of selected examples with the LiMn2O4 lithium intercalation battery cathode material is presented, with emphasis on the operation parameters, some experimental results and multiscale simulations, some limitations and challenges, and conditions for industrial scaleup.
Fil: Calvo, Ernesto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Materia
Litio
Salares
Extracción
Electrooquímica
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/181819
Acceder
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spelling Direct Lithium Recovery from Aqueous Electrolytes with Electrochemical Ion Pumping and Lithium IntercalationCalvo, Ernesto JulioLitioSalaresExtracciónElectrooquímicahttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In this mini-review, we provide an account of recent developments on electrochemical methods for the direct extraction of lithium (DEL) from natural brines, geothermal fluids, seawater, and battery recycling electrolytes by ion-pumping entropy cells. A critical discussion of selected examples with the LiMn2O4 lithium intercalation battery cathode material is presented, with emphasis on the operation parameters, some experimental results and multiscale simulations, some limitations and challenges, and conditions for industrial scaleup.Fil: Calvo, Ernesto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaAmerican Chemical Society2021-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/181819Calvo, Ernesto Julio; Direct Lithium Recovery from Aqueous Electrolytes with Electrochemical Ion Pumping and Lithium Intercalation; American Chemical Society; ACS Omega; 6; 51; 12-2021; 35213-352202470-1343CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acsomega.1c05516info:eu-repo/semantics/altIdentifier/doi/10.1021/acsomega.1c05516info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:13:35Zoai:ri.conicet.gov.ar:11336/181819instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:13:36.042CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Direct Lithium Recovery from Aqueous Electrolytes with Electrochemical Ion Pumping and Lithium Intercalation
title Direct Lithium Recovery from Aqueous Electrolytes with Electrochemical Ion Pumping and Lithium Intercalation
spellingShingle Direct Lithium Recovery from Aqueous Electrolytes with Electrochemical Ion Pumping and Lithium Intercalation
Calvo, Ernesto Julio
Litio
Salares
Extracción
Electrooquímica
title_short Direct Lithium Recovery from Aqueous Electrolytes with Electrochemical Ion Pumping and Lithium Intercalation
title_full Direct Lithium Recovery from Aqueous Electrolytes with Electrochemical Ion Pumping and Lithium Intercalation
title_fullStr Direct Lithium Recovery from Aqueous Electrolytes with Electrochemical Ion Pumping and Lithium Intercalation
title_full_unstemmed Direct Lithium Recovery from Aqueous Electrolytes with Electrochemical Ion Pumping and Lithium Intercalation
title_sort Direct Lithium Recovery from Aqueous Electrolytes with Electrochemical Ion Pumping and Lithium Intercalation
dc.creator.none.fl_str_mv Calvo, Ernesto Julio
author Calvo, Ernesto Julio
author_facet Calvo, Ernesto Julio
author_role author
dc.subject.none.fl_str_mv Litio
Salares
Extracción
Electrooquímica
topic Litio
Salares
Extracción
Electrooquímica
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this mini-review, we provide an account of recent developments on electrochemical methods for the direct extraction of lithium (DEL) from natural brines, geothermal fluids, seawater, and battery recycling electrolytes by ion-pumping entropy cells. A critical discussion of selected examples with the LiMn2O4 lithium intercalation battery cathode material is presented, with emphasis on the operation parameters, some experimental results and multiscale simulations, some limitations and challenges, and conditions for industrial scaleup.
Fil: Calvo, Ernesto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
description In this mini-review, we provide an account of recent developments on electrochemical methods for the direct extraction of lithium (DEL) from natural brines, geothermal fluids, seawater, and battery recycling electrolytes by ion-pumping entropy cells. A critical discussion of selected examples with the LiMn2O4 lithium intercalation battery cathode material is presented, with emphasis on the operation parameters, some experimental results and multiscale simulations, some limitations and challenges, and conditions for industrial scaleup.
publishDate 2021
dc.date.none.fl_str_mv 2021-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/181819
Calvo, Ernesto Julio; Direct Lithium Recovery from Aqueous Electrolytes with Electrochemical Ion Pumping and Lithium Intercalation; American Chemical Society; ACS Omega; 6; 51; 12-2021; 35213-35220
2470-1343
CONICET Digital
CONICET
url http://hdl.handle.net/11336/181819
identifier_str_mv Calvo, Ernesto Julio; Direct Lithium Recovery from Aqueous Electrolytes with Electrochemical Ion Pumping and Lithium Intercalation; American Chemical Society; ACS Omega; 6; 51; 12-2021; 35213-35220
2470-1343
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acsomega.1c05516
info:eu-repo/semantics/altIdentifier/doi/10.1021/acsomega.1c05516
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.993085

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