Determination of mercury in airborne particulate matter collected on glass fiber filters using high-resolution continuum source graphite furnace atomic absorption spectrometry and...

Autores
Araujo, Rennan G. O.; Vignola, Fabíola; Castilho, Ivan N. B.; Borges, Daniel L. G.; Welz, Bernhard; Vale, Maria Goreti R.; Smichowski, Patricia Nora; Ferreira, Sérgio L. C.; Becker Ross, Helmut
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A study has been undertaken to assess the capability of high-resolution continuum source graphite furnace atomic absorption spectrometry for the determination of mercury in airborne particulate matter (APM) collected on glass fiber filters using direct solid sampling. The main Hg absorption line at 253.652 nm was used for all determinations. The certified reference material NIST SRM 1648 (Urban Particulate Matter) was used to check the accuracy of the method, and good agreement was obtained between published and determined values. The characteristic mass was 22 pg Hg. The limit of detection (3σ), based on ten atomizations of an unexposed filter, was 40 ng g- 1, corresponding to 0.12 ng m- 3 in the air for a typical air volume of 1440 m3 collected within 24 h. The limit of quantification was 150 ng g-1, equivalent to 0.41 ng m-3 in the air. The repeatability of measurements was better than 17% RSD (n = 5). Mercury concentrations found in filter samples loaded with APM collected in Buenos Aires, Argentina, were between < 40 ng g-1 and 381 ± 24 ng g-1. These values correspond to a mercury concentration in the air between < 0.12 ng m-3 and 1.47 ± 0.09 ng m-3. The proposed procedure was found to be simple, fast and reliable, and suitable as a screening procedure for the determination of mercury in APM samples.
Fil: Araujo, Rennan G. O.. Universidade Federal de Santa Catarina; Brasil
Fil: Vignola, Fabíola. Universidade Federal de Santa Catarina; Brasil
Fil: Castilho, Ivan N. B.. Universidade Federal de Santa Catarina; Brasil
Fil: Borges, Daniel L. G.. Universidade Federal de Santa Catarina; Brasil. Universidade Federal da Bahia; Brasil
Fil: Welz, Bernhard. Universidade Federal de Santa Catarina; Brasil. Universidade Federal da Bahia; Brasil
Fil: Vale, Maria Goreti R.. Universidade Federal do Rio Grande do Sul; Brasil. Universidade Federal da Bahia; Brasil
Fil: Smichowski, Patricia Nora. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Ferreira, Sérgio L. C.. Universidade Federal da Bahia; Brasil
Fil: Becker Ross, Helmut. Leibniz-Institut für Analytische Wissenschaften; Alemania
Materia
AIRBORNE PARTICULATE MATTER
DIRECT SOLID SAMPLING ANALYSIS
GLASS FIBER FILTER
HR-CS GF AAS
MERCURY DETERMINATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/188909
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/188909
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Determination of mercury in airborne particulate matter collected on glass fiber filters using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid samplingAraujo, Rennan G. O.Vignola, FabíolaCastilho, Ivan N. B.Borges, Daniel L. G.Welz, BernhardVale, Maria Goreti R.Smichowski, Patricia NoraFerreira, Sérgio L. C.Becker Ross, HelmutAIRBORNE PARTICULATE MATTERDIRECT SOLID SAMPLING ANALYSISGLASS FIBER FILTERHR-CS GF AASMERCURY DETERMINATIONhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A study has been undertaken to assess the capability of high-resolution continuum source graphite furnace atomic absorption spectrometry for the determination of mercury in airborne particulate matter (APM) collected on glass fiber filters using direct solid sampling. The main Hg absorption line at 253.652 nm was used for all determinations. The certified reference material NIST SRM 1648 (Urban Particulate Matter) was used to check the accuracy of the method, and good agreement was obtained between published and determined values. The characteristic mass was 22 pg Hg. The limit of detection (3σ), based on ten atomizations of an unexposed filter, was 40 ng g- 1, corresponding to 0.12 ng m- 3 in the air for a typical air volume of 1440 m3 collected within 24 h. The limit of quantification was 150 ng g-1, equivalent to 0.41 ng m-3 in the air. The repeatability of measurements was better than 17% RSD (n = 5). Mercury concentrations found in filter samples loaded with APM collected in Buenos Aires, Argentina, were between < 40 ng g-1 and 381 ± 24 ng g-1. These values correspond to a mercury concentration in the air between < 0.12 ng m-3 and 1.47 ± 0.09 ng m-3. The proposed procedure was found to be simple, fast and reliable, and suitable as a screening procedure for the determination of mercury in APM samples.Fil: Araujo, Rennan G. O.. Universidade Federal de Santa Catarina; BrasilFil: Vignola, Fabíola. Universidade Federal de Santa Catarina; BrasilFil: Castilho, Ivan N. B.. Universidade Federal de Santa Catarina; BrasilFil: Borges, Daniel L. G.. Universidade Federal de Santa Catarina; Brasil. Universidade Federal da Bahia; BrasilFil: Welz, Bernhard. Universidade Federal de Santa Catarina; Brasil. Universidade Federal da Bahia; BrasilFil: Vale, Maria Goreti R.. Universidade Federal do Rio Grande do Sul; Brasil. Universidade Federal da Bahia; BrasilFil: Smichowski, Patricia Nora. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Ferreira, Sérgio L. C.. Universidade Federal da Bahia; BrasilFil: Becker Ross, Helmut. Leibniz-Institut für Analytische Wissenschaften; AlemaniaPergamon-Elsevier Science Ltd2011-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/188909Araujo, Rennan G. O.; Vignola, Fabíola; Castilho, Ivan N. B.; Borges, Daniel L. G.; Welz, Bernhard; et al.; Determination of mercury in airborne particulate matter collected on glass fiber filters using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sampling; Pergamon-Elsevier Science Ltd; Spectrochimica Acta Part B: Atomic Spectroscopy; 66; 5; 5-2011; 378-3820584-8547CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0584854711000978info:eu-repo/semantics/altIdentifier/doi/10.1016/j.sab.2011.05.004info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:47:28Zoai:ri.conicet.gov.ar:11336/188909instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:47:28.905CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Determination of mercury in airborne particulate matter collected on glass fiber filters using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sampling
title Determination of mercury in airborne particulate matter collected on glass fiber filters using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sampling
spellingShingle Determination of mercury in airborne particulate matter collected on glass fiber filters using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sampling
Araujo, Rennan G. O.
AIRBORNE PARTICULATE MATTER
DIRECT SOLID SAMPLING ANALYSIS
GLASS FIBER FILTER
HR-CS GF AAS
MERCURY DETERMINATION
title_short Determination of mercury in airborne particulate matter collected on glass fiber filters using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sampling
title_full Determination of mercury in airborne particulate matter collected on glass fiber filters using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sampling
title_fullStr Determination of mercury in airborne particulate matter collected on glass fiber filters using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sampling
title_full_unstemmed Determination of mercury in airborne particulate matter collected on glass fiber filters using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sampling
title_sort Determination of mercury in airborne particulate matter collected on glass fiber filters using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sampling
dc.creator.none.fl_str_mv Araujo, Rennan G. O.
Vignola, Fabíola
Castilho, Ivan N. B.
Borges, Daniel L. G.
Welz, Bernhard
Vale, Maria Goreti R.
Smichowski, Patricia Nora
Ferreira, Sérgio L. C.
Becker Ross, Helmut
author Araujo, Rennan G. O.
author_facet Araujo, Rennan G. O.
Vignola, Fabíola
Castilho, Ivan N. B.
Borges, Daniel L. G.
Welz, Bernhard
Vale, Maria Goreti R.
Smichowski, Patricia Nora
Ferreira, Sérgio L. C.
Becker Ross, Helmut
author_role author
author2 Vignola, Fabíola
Castilho, Ivan N. B.
Borges, Daniel L. G.
Welz, Bernhard
Vale, Maria Goreti R.
Smichowski, Patricia Nora
Ferreira, Sérgio L. C.
Becker Ross, Helmut
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv AIRBORNE PARTICULATE MATTER
DIRECT SOLID SAMPLING ANALYSIS
GLASS FIBER FILTER
HR-CS GF AAS
MERCURY DETERMINATION
topic AIRBORNE PARTICULATE MATTER
DIRECT SOLID SAMPLING ANALYSIS
GLASS FIBER FILTER
HR-CS GF AAS
MERCURY DETERMINATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A study has been undertaken to assess the capability of high-resolution continuum source graphite furnace atomic absorption spectrometry for the determination of mercury in airborne particulate matter (APM) collected on glass fiber filters using direct solid sampling. The main Hg absorption line at 253.652 nm was used for all determinations. The certified reference material NIST SRM 1648 (Urban Particulate Matter) was used to check the accuracy of the method, and good agreement was obtained between published and determined values. The characteristic mass was 22 pg Hg. The limit of detection (3σ), based on ten atomizations of an unexposed filter, was 40 ng g- 1, corresponding to 0.12 ng m- 3 in the air for a typical air volume of 1440 m3 collected within 24 h. The limit of quantification was 150 ng g-1, equivalent to 0.41 ng m-3 in the air. The repeatability of measurements was better than 17% RSD (n = 5). Mercury concentrations found in filter samples loaded with APM collected in Buenos Aires, Argentina, were between < 40 ng g-1 and 381 ± 24 ng g-1. These values correspond to a mercury concentration in the air between < 0.12 ng m-3 and 1.47 ± 0.09 ng m-3. The proposed procedure was found to be simple, fast and reliable, and suitable as a screening procedure for the determination of mercury in APM samples.
Fil: Araujo, Rennan G. O.. Universidade Federal de Santa Catarina; Brasil
Fil: Vignola, Fabíola. Universidade Federal de Santa Catarina; Brasil
Fil: Castilho, Ivan N. B.. Universidade Federal de Santa Catarina; Brasil
Fil: Borges, Daniel L. G.. Universidade Federal de Santa Catarina; Brasil. Universidade Federal da Bahia; Brasil
Fil: Welz, Bernhard. Universidade Federal de Santa Catarina; Brasil. Universidade Federal da Bahia; Brasil
Fil: Vale, Maria Goreti R.. Universidade Federal do Rio Grande do Sul; Brasil. Universidade Federal da Bahia; Brasil
Fil: Smichowski, Patricia Nora. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Ferreira, Sérgio L. C.. Universidade Federal da Bahia; Brasil
Fil: Becker Ross, Helmut. Leibniz-Institut für Analytische Wissenschaften; Alemania
description A study has been undertaken to assess the capability of high-resolution continuum source graphite furnace atomic absorption spectrometry for the determination of mercury in airborne particulate matter (APM) collected on glass fiber filters using direct solid sampling. The main Hg absorption line at 253.652 nm was used for all determinations. The certified reference material NIST SRM 1648 (Urban Particulate Matter) was used to check the accuracy of the method, and good agreement was obtained between published and determined values. The characteristic mass was 22 pg Hg. The limit of detection (3σ), based on ten atomizations of an unexposed filter, was 40 ng g- 1, corresponding to 0.12 ng m- 3 in the air for a typical air volume of 1440 m3 collected within 24 h. The limit of quantification was 150 ng g-1, equivalent to 0.41 ng m-3 in the air. The repeatability of measurements was better than 17% RSD (n = 5). Mercury concentrations found in filter samples loaded with APM collected in Buenos Aires, Argentina, were between < 40 ng g-1 and 381 ± 24 ng g-1. These values correspond to a mercury concentration in the air between < 0.12 ng m-3 and 1.47 ± 0.09 ng m-3. The proposed procedure was found to be simple, fast and reliable, and suitable as a screening procedure for the determination of mercury in APM samples.
publishDate 2011
dc.date.none.fl_str_mv 2011-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/188909
Araujo, Rennan G. O.; Vignola, Fabíola; Castilho, Ivan N. B.; Borges, Daniel L. G.; Welz, Bernhard; et al.; Determination of mercury in airborne particulate matter collected on glass fiber filters using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sampling; Pergamon-Elsevier Science Ltd; Spectrochimica Acta Part B: Atomic Spectroscopy; 66; 5; 5-2011; 378-382
0584-8547
CONICET Digital
CONICET
url http://hdl.handle.net/11336/188909
identifier_str_mv Araujo, Rennan G. O.; Vignola, Fabíola; Castilho, Ivan N. B.; Borges, Daniel L. G.; Welz, Bernhard; et al.; Determination of mercury in airborne particulate matter collected on glass fiber filters using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sampling; Pergamon-Elsevier Science Ltd; Spectrochimica Acta Part B: Atomic Spectroscopy; 66; 5; 5-2011; 378-382
0584-8547
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0584854711000978
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.sab.2011.05.004
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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