Investigation of spectral interference in the determination of Pb in road dust using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct sol...
- Autores
- Fick, Susane Schossler; Nakadi, Flávio Venâncio; Fujiwara, Fabian; Smichowski, Patricia Nora; Vale, Maria Goreti R.; Welz, Bernhard; de Andrade, Jailson B.
- Año de publicación
- 2018
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Direct solid sample analysis using graphite furnace atomic absorption spectrometry (GF AAS) is an attractive alternative because no sample pretreatment is necessary. However, the major obstacles of this technique are spectral interference and the limited background correction capability of conventional line source AAS instruments. The introduction of high-resolution continuum source atomic absorption spectrometry (HR-CS AAS) has brought about a significant change in this direction due to its superior background correction capabilities. In this study, a method has been developed for the determination of Pb in road dust using HR-CS GF AAS and direct solid sample analysis. The analytical lines at 261.418 nm (2.1% relative sensitivity), with detection of 1 pixel, and at 283.306 nm (42% relative sensitivity), with side pixel evaluation, were used for Pb determination. Pyrolysis and atomization temperatures were 900 °C and 2300 °C, respectively, using a mixture of Pd and Mg as the chemical modifier. Twelve samples and three certified reference materials (CRMs) have been analyzed. A significant structured background has been observed at the optimum atomization temperature, which overlapped with the analyte atomic absorption wavelength. The background has been identified as AlCl, SiO and SiS molecules at 261.418 nm, and SiS at 283.306 nm. Least-squares background correction (LSBC) has been applied after the identification of the diatomic molecules and the results obtained for the CRMs were in agreement with the certified ones. The use of this correction technique allowed the elimination of spectral interference in the determination of Pb in road dust.
Fil: Fick, Susane Schossler. Universidade Federal do Rio Grande do Sul; Brasil
Fil: Nakadi, Flávio Venâncio. Universidade Federal do Rio Grande do Sul; Brasil
Fil: Fujiwara, Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; Argentina
Fil: Smichowski, Patricia Nora. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; Argentina
Fil: Vale, Maria Goreti R.. Universidade Federal do Rio Grande do Sul; Brasil. Universidade Federal da Bahia; Brasil
Fil: Welz, Bernhard. Universidade Federal da Bahia; Brasil. Universidade Federal de Santa Catarina; Brasil
Fil: de Andrade, Jailson B.. Universidade Federal da Bahia; Brasil - Materia
-
High-resolution continuum source atomic absorption spectrometry (HR-CS AAS)
Lead
Road dust - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/98864
Ver los metadatos del registro completo
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CONICET Digital (CONICET) |
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Investigation of spectral interference in the determination of Pb in road dust using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sample analysisFick, Susane SchosslerNakadi, Flávio VenâncioFujiwara, FabianSmichowski, Patricia NoraVale, Maria Goreti R.Welz, Bernhardde Andrade, Jailson B.High-resolution continuum source atomic absorption spectrometry (HR-CS AAS)LeadRoad dusthttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Direct solid sample analysis using graphite furnace atomic absorption spectrometry (GF AAS) is an attractive alternative because no sample pretreatment is necessary. However, the major obstacles of this technique are spectral interference and the limited background correction capability of conventional line source AAS instruments. The introduction of high-resolution continuum source atomic absorption spectrometry (HR-CS AAS) has brought about a significant change in this direction due to its superior background correction capabilities. In this study, a method has been developed for the determination of Pb in road dust using HR-CS GF AAS and direct solid sample analysis. The analytical lines at 261.418 nm (2.1% relative sensitivity), with detection of 1 pixel, and at 283.306 nm (42% relative sensitivity), with side pixel evaluation, were used for Pb determination. Pyrolysis and atomization temperatures were 900 °C and 2300 °C, respectively, using a mixture of Pd and Mg as the chemical modifier. Twelve samples and three certified reference materials (CRMs) have been analyzed. A significant structured background has been observed at the optimum atomization temperature, which overlapped with the analyte atomic absorption wavelength. The background has been identified as AlCl, SiO and SiS molecules at 261.418 nm, and SiS at 283.306 nm. Least-squares background correction (LSBC) has been applied after the identification of the diatomic molecules and the results obtained for the CRMs were in agreement with the certified ones. The use of this correction technique allowed the elimination of spectral interference in the determination of Pb in road dust.Fil: Fick, Susane Schossler. Universidade Federal do Rio Grande do Sul; BrasilFil: Nakadi, Flávio Venâncio. Universidade Federal do Rio Grande do Sul; BrasilFil: Fujiwara, Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; ArgentinaFil: Smichowski, Patricia Nora. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; ArgentinaFil: Vale, Maria Goreti R.. Universidade Federal do Rio Grande do Sul; Brasil. Universidade Federal da Bahia; BrasilFil: Welz, Bernhard. Universidade Federal da Bahia; Brasil. Universidade Federal de Santa Catarina; BrasilFil: de Andrade, Jailson B.. Universidade Federal da Bahia; BrasilRoyal Society of Chemistry2018-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/98864Fick, Susane Schossler; Nakadi, Flávio Venâncio; Fujiwara, Fabian; Smichowski, Patricia Nora; Vale, Maria Goreti R.; et al.; Investigation of spectral interference in the determination of Pb in road dust using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sample analysis; Royal Society of Chemistry; Journal of Analytical Atomic Spectrometry; 33; 4; 4-2018; 593-6020267-9477CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2018/JA/C7JA00405Binfo:eu-repo/semantics/altIdentifier/doi/10.1039/c7ja00405binfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:47:53Zoai:ri.conicet.gov.ar:11336/98864instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:47:53.842CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Investigation of spectral interference in the determination of Pb in road dust using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sample analysis |
title |
Investigation of spectral interference in the determination of Pb in road dust using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sample analysis |
spellingShingle |
Investigation of spectral interference in the determination of Pb in road dust using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sample analysis Fick, Susane Schossler High-resolution continuum source atomic absorption spectrometry (HR-CS AAS) Lead Road dust |
title_short |
Investigation of spectral interference in the determination of Pb in road dust using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sample analysis |
title_full |
Investigation of spectral interference in the determination of Pb in road dust using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sample analysis |
title_fullStr |
Investigation of spectral interference in the determination of Pb in road dust using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sample analysis |
title_full_unstemmed |
Investigation of spectral interference in the determination of Pb in road dust using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sample analysis |
title_sort |
Investigation of spectral interference in the determination of Pb in road dust using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sample analysis |
dc.creator.none.fl_str_mv |
Fick, Susane Schossler Nakadi, Flávio Venâncio Fujiwara, Fabian Smichowski, Patricia Nora Vale, Maria Goreti R. Welz, Bernhard de Andrade, Jailson B. |
author |
Fick, Susane Schossler |
author_facet |
Fick, Susane Schossler Nakadi, Flávio Venâncio Fujiwara, Fabian Smichowski, Patricia Nora Vale, Maria Goreti R. Welz, Bernhard de Andrade, Jailson B. |
author_role |
author |
author2 |
Nakadi, Flávio Venâncio Fujiwara, Fabian Smichowski, Patricia Nora Vale, Maria Goreti R. Welz, Bernhard de Andrade, Jailson B. |
author2_role |
author author author author author author |
dc.subject.none.fl_str_mv |
High-resolution continuum source atomic absorption spectrometry (HR-CS AAS) Lead Road dust |
topic |
High-resolution continuum source atomic absorption spectrometry (HR-CS AAS) Lead Road dust |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Direct solid sample analysis using graphite furnace atomic absorption spectrometry (GF AAS) is an attractive alternative because no sample pretreatment is necessary. However, the major obstacles of this technique are spectral interference and the limited background correction capability of conventional line source AAS instruments. The introduction of high-resolution continuum source atomic absorption spectrometry (HR-CS AAS) has brought about a significant change in this direction due to its superior background correction capabilities. In this study, a method has been developed for the determination of Pb in road dust using HR-CS GF AAS and direct solid sample analysis. The analytical lines at 261.418 nm (2.1% relative sensitivity), with detection of 1 pixel, and at 283.306 nm (42% relative sensitivity), with side pixel evaluation, were used for Pb determination. Pyrolysis and atomization temperatures were 900 °C and 2300 °C, respectively, using a mixture of Pd and Mg as the chemical modifier. Twelve samples and three certified reference materials (CRMs) have been analyzed. A significant structured background has been observed at the optimum atomization temperature, which overlapped with the analyte atomic absorption wavelength. The background has been identified as AlCl, SiO and SiS molecules at 261.418 nm, and SiS at 283.306 nm. Least-squares background correction (LSBC) has been applied after the identification of the diatomic molecules and the results obtained for the CRMs were in agreement with the certified ones. The use of this correction technique allowed the elimination of spectral interference in the determination of Pb in road dust. Fil: Fick, Susane Schossler. Universidade Federal do Rio Grande do Sul; Brasil Fil: Nakadi, Flávio Venâncio. Universidade Federal do Rio Grande do Sul; Brasil Fil: Fujiwara, Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; Argentina Fil: Smichowski, Patricia Nora. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; Argentina Fil: Vale, Maria Goreti R.. Universidade Federal do Rio Grande do Sul; Brasil. Universidade Federal da Bahia; Brasil Fil: Welz, Bernhard. Universidade Federal da Bahia; Brasil. Universidade Federal de Santa Catarina; Brasil Fil: de Andrade, Jailson B.. Universidade Federal da Bahia; Brasil |
description |
Direct solid sample analysis using graphite furnace atomic absorption spectrometry (GF AAS) is an attractive alternative because no sample pretreatment is necessary. However, the major obstacles of this technique are spectral interference and the limited background correction capability of conventional line source AAS instruments. The introduction of high-resolution continuum source atomic absorption spectrometry (HR-CS AAS) has brought about a significant change in this direction due to its superior background correction capabilities. In this study, a method has been developed for the determination of Pb in road dust using HR-CS GF AAS and direct solid sample analysis. The analytical lines at 261.418 nm (2.1% relative sensitivity), with detection of 1 pixel, and at 283.306 nm (42% relative sensitivity), with side pixel evaluation, were used for Pb determination. Pyrolysis and atomization temperatures were 900 °C and 2300 °C, respectively, using a mixture of Pd and Mg as the chemical modifier. Twelve samples and three certified reference materials (CRMs) have been analyzed. A significant structured background has been observed at the optimum atomization temperature, which overlapped with the analyte atomic absorption wavelength. The background has been identified as AlCl, SiO and SiS molecules at 261.418 nm, and SiS at 283.306 nm. Least-squares background correction (LSBC) has been applied after the identification of the diatomic molecules and the results obtained for the CRMs were in agreement with the certified ones. The use of this correction technique allowed the elimination of spectral interference in the determination of Pb in road dust. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-04 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/98864 Fick, Susane Schossler; Nakadi, Flávio Venâncio; Fujiwara, Fabian; Smichowski, Patricia Nora; Vale, Maria Goreti R.; et al.; Investigation of spectral interference in the determination of Pb in road dust using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sample analysis; Royal Society of Chemistry; Journal of Analytical Atomic Spectrometry; 33; 4; 4-2018; 593-602 0267-9477 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/98864 |
identifier_str_mv |
Fick, Susane Schossler; Nakadi, Flávio Venâncio; Fujiwara, Fabian; Smichowski, Patricia Nora; Vale, Maria Goreti R.; et al.; Investigation of spectral interference in the determination of Pb in road dust using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sample analysis; Royal Society of Chemistry; Journal of Analytical Atomic Spectrometry; 33; 4; 4-2018; 593-602 0267-9477 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2018/JA/C7JA00405B info:eu-repo/semantics/altIdentifier/doi/10.1039/c7ja00405b |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Royal Society of Chemistry |
publisher.none.fl_str_mv |
Royal Society of Chemistry |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613490793250816 |
score |
13.070432 |