Determination of antimony in airborne particulate matter collected on filters using direct solid sampling and high-resolution continuum source graphite furnace atomic absorption sp...
- Autores
- Araujo, Rennan G. O.; Welz, Bernhard; Castilho, Ivan N. B.; Vale, Maria Goreti R.; Smichowski, Patricia Nora; Ferreira, Sérgio L. C.; Becker Ross, Helmut
- Año de publicación
- 2010
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- A method has been developed for the determination of antimony in airborne particulate matter collected on glass fiber filters using direct solid sampling and high-resolution continuum source graphite furnace atomic absorption spectrometry. The certified reference material, BCR 176 (City Waste Incineration Ash) has been analyzed for validation purposes; no statistically significant difference has been found between the certified and the determined value for antimony based on a Student t-test at a 95% confidence level. The secondary antimony absorption line at 212.739 nm, which is about a factor of 20 less sensitive than the primary resonance line, has been used in order to adapt the sensitivity of the method to the antimony concentration in the samples. 400 μg of ruthenium, thermally deposited on the solid sampling platform has been used as permanent modifier. The characteristic mass at this line was found to be m0 = 0.7 ng Sb. The limit of detection (3σ), based on ten atomizations of an unused filter was found to be 15 μg g-1, corresponding to 40 ng m-3 for a typical air volume of 1440 m 3. The limits of quantification, based on the same measurements were 50 μg g-1 and 128 ng m-3, respectively. The repeatability of the measurements has been between 4% and 9% (n = 5). The antimony concentration found in filter samples varied between <15 μg g-1and 342 ± 16 μg g-1, corresponding to <40 ng m-3 and 1820 ± 90 ng m-3, respectively. Direct solid sample analysis and detection by high-resolution continuum source graphite furnace atomic absorption spectrometry proved to be a simple, fast and reliable alternative for the determination of Sb in airborne particulate matter. An attempt to transfer the method to conventional line source equipment has been without success because of spectral interference and the weak emission of the secondary line from a hollow cathode lamp.
Fil: Araujo, Rennan G. O.. Universidade Federal de Santa Catarina; Brasil. Universidade Federal de Sergipe; Brasil
Fil: Welz, Bernhard. Universidade Federal de Santa Catarina; Brasil. Universidade Federal da Bahia; Brasil
Fil: Castilho, Ivan N. B.. Universidade Federal de Santa Catarina; Brasil
Fil: Vale, Maria Goreti R.. Universidade Federal de Santa Catarina; Brasil
Fil: Smichowski, Patricia Nora. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Ferreira, Sérgio L. C.. Universidade Federal de Santa Catarina; Brasil
Fil: Becker Ross, Helmut. Leibniz Institute for Analytical Sciences; Alemania - Materia
-
Antimony Determination
Glass Fiber Filters
Airborne Particulate Matter
Direct Solid Sampling Analysis
Hr-Cs Gf Aas - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/54614
Ver los metadatos del registro completo
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oai:ri.conicet.gov.ar:11336/54614 |
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3498 |
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CONICET Digital (CONICET) |
spelling |
Determination of antimony in airborne particulate matter collected on filters using direct solid sampling and high-resolution continuum source graphite furnace atomic absorption spectrometryAraujo, Rennan G. O.Welz, BernhardCastilho, Ivan N. B.Vale, Maria Goreti R.Smichowski, Patricia NoraFerreira, Sérgio L. C.Becker Ross, HelmutAntimony DeterminationGlass Fiber FiltersAirborne Particulate MatterDirect Solid Sampling AnalysisHr-Cs Gf Aashttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A method has been developed for the determination of antimony in airborne particulate matter collected on glass fiber filters using direct solid sampling and high-resolution continuum source graphite furnace atomic absorption spectrometry. The certified reference material, BCR 176 (City Waste Incineration Ash) has been analyzed for validation purposes; no statistically significant difference has been found between the certified and the determined value for antimony based on a Student t-test at a 95% confidence level. The secondary antimony absorption line at 212.739 nm, which is about a factor of 20 less sensitive than the primary resonance line, has been used in order to adapt the sensitivity of the method to the antimony concentration in the samples. 400 μg of ruthenium, thermally deposited on the solid sampling platform has been used as permanent modifier. The characteristic mass at this line was found to be m0 = 0.7 ng Sb. The limit of detection (3σ), based on ten atomizations of an unused filter was found to be 15 μg g-1, corresponding to 40 ng m-3 for a typical air volume of 1440 m 3. The limits of quantification, based on the same measurements were 50 μg g-1 and 128 ng m-3, respectively. The repeatability of the measurements has been between 4% and 9% (n = 5). The antimony concentration found in filter samples varied between <15 μg g-1and 342 ± 16 μg g-1, corresponding to <40 ng m-3 and 1820 ± 90 ng m-3, respectively. Direct solid sample analysis and detection by high-resolution continuum source graphite furnace atomic absorption spectrometry proved to be a simple, fast and reliable alternative for the determination of Sb in airborne particulate matter. An attempt to transfer the method to conventional line source equipment has been without success because of spectral interference and the weak emission of the secondary line from a hollow cathode lamp.Fil: Araujo, Rennan G. O.. Universidade Federal de Santa Catarina; Brasil. Universidade Federal de Sergipe; BrasilFil: Welz, Bernhard. Universidade Federal de Santa Catarina; Brasil. Universidade Federal da Bahia; BrasilFil: Castilho, Ivan N. B.. Universidade Federal de Santa Catarina; BrasilFil: Vale, Maria Goreti R.. Universidade Federal de Santa Catarina; BrasilFil: Smichowski, Patricia Nora. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Ferreira, Sérgio L. C.. Universidade Federal de Santa Catarina; BrasilFil: Becker Ross, Helmut. Leibniz Institute for Analytical Sciences; AlemaniaRoyal Society of Chemistry2010-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/54614Araujo, Rennan G. O.; Welz, Bernhard; Castilho, Ivan N. B.; Vale, Maria Goreti R.; Smichowski, Patricia Nora; et al.; Determination of antimony in airborne particulate matter collected on filters using direct solid sampling and high-resolution continuum source graphite furnace atomic absorption spectrometry; Royal Society of Chemistry; Journal of Analytical Atomic Spectrometry; 25; 4; 2-2010; 580-5840267-9477CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/content/articlelanding/2010/ja/b914868jinfo:eu-repo/semantics/altIdentifier/doi/10.1039/B914868Jinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:34:38Zoai:ri.conicet.gov.ar:11336/54614instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:34:38.396CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Determination of antimony in airborne particulate matter collected on filters using direct solid sampling and high-resolution continuum source graphite furnace atomic absorption spectrometry |
title |
Determination of antimony in airborne particulate matter collected on filters using direct solid sampling and high-resolution continuum source graphite furnace atomic absorption spectrometry |
spellingShingle |
Determination of antimony in airborne particulate matter collected on filters using direct solid sampling and high-resolution continuum source graphite furnace atomic absorption spectrometry Araujo, Rennan G. O. Antimony Determination Glass Fiber Filters Airborne Particulate Matter Direct Solid Sampling Analysis Hr-Cs Gf Aas |
title_short |
Determination of antimony in airborne particulate matter collected on filters using direct solid sampling and high-resolution continuum source graphite furnace atomic absorption spectrometry |
title_full |
Determination of antimony in airborne particulate matter collected on filters using direct solid sampling and high-resolution continuum source graphite furnace atomic absorption spectrometry |
title_fullStr |
Determination of antimony in airborne particulate matter collected on filters using direct solid sampling and high-resolution continuum source graphite furnace atomic absorption spectrometry |
title_full_unstemmed |
Determination of antimony in airborne particulate matter collected on filters using direct solid sampling and high-resolution continuum source graphite furnace atomic absorption spectrometry |
title_sort |
Determination of antimony in airborne particulate matter collected on filters using direct solid sampling and high-resolution continuum source graphite furnace atomic absorption spectrometry |
dc.creator.none.fl_str_mv |
Araujo, Rennan G. O. Welz, Bernhard Castilho, Ivan N. B. Vale, Maria Goreti R. Smichowski, Patricia Nora Ferreira, Sérgio L. C. Becker Ross, Helmut |
author |
Araujo, Rennan G. O. |
author_facet |
Araujo, Rennan G. O. Welz, Bernhard Castilho, Ivan N. B. Vale, Maria Goreti R. Smichowski, Patricia Nora Ferreira, Sérgio L. C. Becker Ross, Helmut |
author_role |
author |
author2 |
Welz, Bernhard Castilho, Ivan N. B. Vale, Maria Goreti R. Smichowski, Patricia Nora Ferreira, Sérgio L. C. Becker Ross, Helmut |
author2_role |
author author author author author author |
dc.subject.none.fl_str_mv |
Antimony Determination Glass Fiber Filters Airborne Particulate Matter Direct Solid Sampling Analysis Hr-Cs Gf Aas |
topic |
Antimony Determination Glass Fiber Filters Airborne Particulate Matter Direct Solid Sampling Analysis Hr-Cs Gf Aas |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
A method has been developed for the determination of antimony in airborne particulate matter collected on glass fiber filters using direct solid sampling and high-resolution continuum source graphite furnace atomic absorption spectrometry. The certified reference material, BCR 176 (City Waste Incineration Ash) has been analyzed for validation purposes; no statistically significant difference has been found between the certified and the determined value for antimony based on a Student t-test at a 95% confidence level. The secondary antimony absorption line at 212.739 nm, which is about a factor of 20 less sensitive than the primary resonance line, has been used in order to adapt the sensitivity of the method to the antimony concentration in the samples. 400 μg of ruthenium, thermally deposited on the solid sampling platform has been used as permanent modifier. The characteristic mass at this line was found to be m0 = 0.7 ng Sb. The limit of detection (3σ), based on ten atomizations of an unused filter was found to be 15 μg g-1, corresponding to 40 ng m-3 for a typical air volume of 1440 m 3. The limits of quantification, based on the same measurements were 50 μg g-1 and 128 ng m-3, respectively. The repeatability of the measurements has been between 4% and 9% (n = 5). The antimony concentration found in filter samples varied between <15 μg g-1and 342 ± 16 μg g-1, corresponding to <40 ng m-3 and 1820 ± 90 ng m-3, respectively. Direct solid sample analysis and detection by high-resolution continuum source graphite furnace atomic absorption spectrometry proved to be a simple, fast and reliable alternative for the determination of Sb in airborne particulate matter. An attempt to transfer the method to conventional line source equipment has been without success because of spectral interference and the weak emission of the secondary line from a hollow cathode lamp. Fil: Araujo, Rennan G. O.. Universidade Federal de Santa Catarina; Brasil. Universidade Federal de Sergipe; Brasil Fil: Welz, Bernhard. Universidade Federal de Santa Catarina; Brasil. Universidade Federal da Bahia; Brasil Fil: Castilho, Ivan N. B.. Universidade Federal de Santa Catarina; Brasil Fil: Vale, Maria Goreti R.. Universidade Federal de Santa Catarina; Brasil Fil: Smichowski, Patricia Nora. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Ferreira, Sérgio L. C.. Universidade Federal de Santa Catarina; Brasil Fil: Becker Ross, Helmut. Leibniz Institute for Analytical Sciences; Alemania |
description |
A method has been developed for the determination of antimony in airborne particulate matter collected on glass fiber filters using direct solid sampling and high-resolution continuum source graphite furnace atomic absorption spectrometry. The certified reference material, BCR 176 (City Waste Incineration Ash) has been analyzed for validation purposes; no statistically significant difference has been found between the certified and the determined value for antimony based on a Student t-test at a 95% confidence level. The secondary antimony absorption line at 212.739 nm, which is about a factor of 20 less sensitive than the primary resonance line, has been used in order to adapt the sensitivity of the method to the antimony concentration in the samples. 400 μg of ruthenium, thermally deposited on the solid sampling platform has been used as permanent modifier. The characteristic mass at this line was found to be m0 = 0.7 ng Sb. The limit of detection (3σ), based on ten atomizations of an unused filter was found to be 15 μg g-1, corresponding to 40 ng m-3 for a typical air volume of 1440 m 3. The limits of quantification, based on the same measurements were 50 μg g-1 and 128 ng m-3, respectively. The repeatability of the measurements has been between 4% and 9% (n = 5). The antimony concentration found in filter samples varied between <15 μg g-1and 342 ± 16 μg g-1, corresponding to <40 ng m-3 and 1820 ± 90 ng m-3, respectively. Direct solid sample analysis and detection by high-resolution continuum source graphite furnace atomic absorption spectrometry proved to be a simple, fast and reliable alternative for the determination of Sb in airborne particulate matter. An attempt to transfer the method to conventional line source equipment has been without success because of spectral interference and the weak emission of the secondary line from a hollow cathode lamp. |
publishDate |
2010 |
dc.date.none.fl_str_mv |
2010-02 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/54614 Araujo, Rennan G. O.; Welz, Bernhard; Castilho, Ivan N. B.; Vale, Maria Goreti R.; Smichowski, Patricia Nora; et al.; Determination of antimony in airborne particulate matter collected on filters using direct solid sampling and high-resolution continuum source graphite furnace atomic absorption spectrometry; Royal Society of Chemistry; Journal of Analytical Atomic Spectrometry; 25; 4; 2-2010; 580-584 0267-9477 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/54614 |
identifier_str_mv |
Araujo, Rennan G. O.; Welz, Bernhard; Castilho, Ivan N. B.; Vale, Maria Goreti R.; Smichowski, Patricia Nora; et al.; Determination of antimony in airborne particulate matter collected on filters using direct solid sampling and high-resolution continuum source graphite furnace atomic absorption spectrometry; Royal Society of Chemistry; Journal of Analytical Atomic Spectrometry; 25; 4; 2-2010; 580-584 0267-9477 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/content/articlelanding/2010/ja/b914868j info:eu-repo/semantics/altIdentifier/doi/10.1039/B914868J |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Royal Society of Chemistry |
publisher.none.fl_str_mv |
Royal Society of Chemistry |
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reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) |
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CONICET Digital (CONICET) |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613072462807040 |
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13.070432 |